• 대한화학회지
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• 제43권5호
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• pp.505-510
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• 1999

n-butanol 용매 내에서 titanium n-butoxide의 가수분해 반응에 의하여 $TiO_2$ 분말을 합성하였고, 가수분해 반응 메카니즘은 UV-Vis 분광법에 의하여 조사하였다. 가수분해 반응시 물의 농도를 과량으로 하여 반응이 유사일차반응으로 진행하도록 하였다. 이러한 농도 조건에서 얻어진 분말의 상(phase)을 XRD에 의하여 확인하였으며 반응속도는 Guggenheim method를 이용하여 계산하였다. 합성 결과 얻어진 분말은 생성 초기 비결정 상태에서 열처리 과정을 거치면서 rutile 구조로 상전이 하였다. 속도상수로부터 얻어진 물분자수(n-value)와 열역학적 파라미터로부터 titanium n-butoxide의 가수분해 반응은 Interchange-Associative(Ia)메카니즘으로 진행하는 것으로 추정되었다.

• 한국결정성장학회지
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• 제19권3호
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• pp.144-151
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• 2009

Photocatalytic degradation of methylene blue (MB) in aqueous solution was investigated using $TiO_2$ coated on various acid modified activated carbon fiber (ACF). The ACFs/$TiO_2$ composites were prepared from titanium n-butoxide (TNB) as titanium precursor and various acid modified ACFs. The prepared samples are heat treated at 973 K. Then the ACF/$TiO_2$ composites were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), energy dispersive X-ray analysis (EDX). Moreover, photocatalytic degradation of MB by the ACF/$TiO_2$ composites was determined under UV irradiation. The results shows that the photocatalytic activity of ACF/$TiO_2$ composites ($AT1{\sim}AT4$) prepared with TNB and various acid modified ACF was much better than that of ACF/$TiO_2$ composite (AT) prepared with TNB and non-acid modified ACF, and the effects improved with order of sample AT3 > AT4 > AT1 > AT2.

• 한국세라믹학회지
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• 제53권2호
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• pp.227-233
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• 2016

In order to make a highly ordered three-dimensional porous structure of titania ceramics, porogen beads of PS [Polystyrene] and PMMA [poly(methylmetacrylate)] were prepared by emulsion polymerization using styrene monomer and methyl methacrylate monomer, respectively. The uniform beads of PS or PMMA latex were closely packed by centrifugation as a porogen template for the infiltration of titanium butoxide solution. The mixed compound of PS or PMMA with titanium butoxide was dried and the dry compacts were calcined at $450^{\circ}C-750^{\circ}C$ according to the firing schedule to prepare micro- and meso- structures of polycrystalline titania with monodispersed porosity. Inorganic frameworks composed of $TiO_2$ were formed and showed a three Dimensionally Ordered Microstructure [3DOM] of $TiO_2$ ceramics. The pulverized particles of the $TiO_2$ ceramic skeleton were characterized using XRD analysis. A monodispersed crystalline micro-structure with micro/meso porosity was observed by FE-SEM with EDX analysis. The 3DOM $TiO_2$ skeleton showed opalescent color tuning according to the direction of light.

• Environmental Engineering Research
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• 제13권2호
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• pp.85-92
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• 2008

In this present study, we have synthesized Fe-containing AC(activated carbon)/$TiO_2$ composites with titanium (VI) n-butoxide (TNB) as a titanium source to Fe treated AC through an impregnation method. The result of the textural surface properties demonstrates that there is a slight decrease in the BET surface area of composite samples with an increase of the amount of Fe treated. The surface properties of scanning electron microscope (SEM) presented a characterization of a porous texture on the Fe-containing AC/$TiO_2$ composites and homogenous compositions for Fe and titanium dioxide distributed on the sample surfaces. Fe compound peaks and a titanium dioxide structure were observed in the X-ray diffraction patterns for the Fe-containing AC/$TiO_2$ composites. The results of chemical elemental composition for the Fe-containing AC/$TiO_2$ composites showed that most of the spectra for these samples gave stronger peaks for C, O, treated Fe components and Ti metal than that of any other elements. From the photo degradation results for the piggery waste, the Fe-containing AC/$TiO_2$ composites showed an excellent degradation activity for the chemical oxygen demand (COD) due to a photocatalysis of the supported $TiO_2$, radical reaction by Fe species and the adsorptivity and absorptivity of porous carbon.

• 한국세라믹학회지
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• 제47권3호
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• pp.210-215
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• 2010

In this study, an expanded graphite-titanium oxide composite is developed from expanded graphite (EG) and titanium n-butoxide (TNB). EG is synthesized by chemical intercalation of natural graphite (NG) and rapid expansion at high temperature. TNB is used as the titanium source. The performances of the prepared EG-$TiO_2$ composite are characterized by BET surface area measurements, scan electron microscope (SEM), X-ray diffraction patterns (XRD) and energy dispersive X-ray analysis (EDX). The catalytic activities of the EG-$TiO_2$ composite are investigated by analysis of the degradation of methylene blue (MB) in aqueous solution under irradiation of UV light. Compared with the pristine $TiO_2$ and activity carbon-$TiO_2$ (AC-$TiO_2$) composite, the EG-$TiO_2$ composite shows very high efficiency against MB solution, and the EG could improve the photocatalytic effect of $TiO_2$ in the MB degradation reaction under the irradiation of UV light.

• Elastomers and Composites
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• 제45권1호
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• pp.25-31
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• 2010

우리는 탄소 전구체로 활성탄 (AC), 활성탄 섬유 (ACF)와 탄소나노튜브 (MWCNT)와 티타늄 전구체로써 TNB를 사용하여 탄소-$TiO_2$ 복합체를 제조하였으며, 이들의 특성을 SEM, TEM, BET, XRD와 EDX를 이용하여 분석하였다. 그리고 이들의 광촉매 활성은 UV 램프 조사에서 일정한 농도의 MB 용액을 이용하여 측정하였다. UV 조사한 후에 MB의 농도는 UV-vis 분광광도기를 이용하여 측정하였다.

• Environmental Engineering Research
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• 제12권5호
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• pp.218-223
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• 2007

The hybrid $C/TiO_2$ complexes were prepared by a method involving the penetration of titanium n-butoxide (TNB) solution with porous carbons. The photocatalysts were investigated for their surface textural properties and SEM morphology, structural crystallinity and elemental identification between porous carbon and $TiO_2$, and dye decomposition performance. For all the $C/TiO_2$ complexes prepared by TNB solution methods, the excellent photocatalytic effect for dye degradation should be attributed to the synergitic effects between photo-decomposition of the supported $TiO_2$ and adsorptivity of the porous carbons.

• 한국정보통신학회:학술대회논문집
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• 한국해양정보통신학회 2003년도 춘계종합학술대회
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• pp.374-377
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• 2003

Sol-gel processing of BaTiO$_3$ ceramics doped with La(0.01-1.00 at.%) were prepared from metal barium, titanium n-butoxide and lanthanum isopropoxide. Characterization of the sol-gel-derived powder using XRD, SEM is also reported. The obtained results suggested that insulator to semiconductor transition for highly donor-doped barium titanate was closely related to the incorporation of donor into the grains and to the resultant grain size, which were significantly affected by the sinterability of BaTiO$_3$ powders and sintering conditions used.

• Bulletin of the Korean Chemical Society
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• 제29권1호
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• pp.159-164
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• 2008

Two kinds of CNT/TiO2 composite photocatalysts were synthesized with multi-walled carbon nanotubes (MWCNTs) and titanium(IV) n-butoxide (TNB) by a MCPBA oxidation method. Since MWCNTs had charge transfer and semiconducting, the CNT/TiO2 composite shows a good photo-degradation activity. The XRD patterns reveal that only anatase phase can be identified for MCT composite, but the HMCT composite synthesized with HCl treatment was observed the mixed phase of anatase and rutile. The EDX spectra were shown the presence as major elements of Ti with strong peaks. From the SEM results, the sample MCT and HMCT synthesized by the thermal decomposition with TNB show a homogenous sample with only individual MWCNTs covered with TiO2 without any jam-like aggregates between CNTs and TiO2. From the photocatalytic results, we could be suggested that the excellent activity of the CNT/TiO2 composites for organic dye and UV irradiation time could be attributed to combination effects between TiO2 and MWCNTs with plausible photodegradation mechanism.

• Journal of information and communication convergence engineering
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• 제1권1호
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• pp.31-34
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• 2003

Sol-gel processing of $BaTiO_{3}$ ceramics doped with La (0.01∼1.00 at.%) were prepared from metal barium, titanium n-butoxide and lanthanum isopropoxide. Characterization of the sol-gel-derived powder using XRD, SEM is also reported. The obtained results suggested that insulator to semiconductor transition for highly donor-doped barium titanate was closely related to the incorporation of donor into the grains and to the resultant grain size, which were significantly affected by the sinterability of $BaTiO_{3}$ powders and sintering conditions used.