• Title/Summary/Keyword: Tin-Water System

Search Result 24, Processing Time 0.019 seconds

Evaluation on the Rlationship between Wear Ratio and Polarization Characteristics of Anti-Fouling Paint (방오도료 도막의 마모율과 분극특성의 상관관계에 관한 평가)

  • Jeong, Jae-Hun;Moon, Kyung-Man;Won, Jong-Pil;Park, Dong-Hyun;Kim, Yun-Hae;Kim, Hyun-Myung;Lee, Myeong-Hoon;Baek, Tae-Sil
    • Corrosion Science and Technology
    • /
    • v.13 no.1
    • /
    • pp.15-19
    • /
    • 2014
  • Recently, anti-fouling paints which does not include the poison components such as tin(Sn), copper(Cu) have been increasingly developed in order to inhibit the environmental contamination of the sea water. Moreover, the wear ratios of these anti-fouling paints are very important problem to prolong their life time in economical point of view. In this study, five types of anti-fouling paints as self polishing type were investigated on the relationship between their polarization characteristics and wear ratios. It was verified that there was apparently a good relationship between the wear ratio and polarization characteristics, for example, the wear ratio increased with increasing the impedance ratio, and increased or decreased with the corrosion potential shifting in the negative or positive direction respectively. In addition, the wear ratio decreased with decreasing the corrosion current density. Consequently, it is suggested that we can qualitatively expect the wear ratio by only measuring the polarization characteristics. Therefore, before the examination of the wear ratio was actually carried out in the field, the evaluation of polarization property in the laboratory may give a available reference data for their developments.

Antifouling Effect of an Ultrasonic System Operating at Different Frequencies (주파수 변동에 따른 초음파방오장비의 파울링제거효과)

  • Bae, Jin-Woo;Park, Guan-Sik;Ru, Myung-Lok;Park, Goun-Ha
    • Journal of the Korean Society of Marine Environment & Safety
    • /
    • v.25 no.5
    • /
    • pp.609-616
    • /
    • 2019
  • When the fouling of a vessel occurs, its resistance at sea increases and there is a corresponding increase in fuel consumption. The maintenance cost of the vessel also increases because it is time-consuming to remove the fouling. To solve this problem and minimize environmental contamination of sea-water, there have been recent developments in anti-fouling paints as self-polishing copolymers that not include toxic elements such as tin. When these conventional techniques are applied to vessels, polishing is promoted during the operation whereby friction or vibration with seawater occurs. This leads to enhanced anti-fouling performance. However, when fouling is intensified such as during an anchorage, there is no flow of seawater and polishing is suppressed. This leads to a deterioration of the performance of anti-fouling. To solve these problems, we developed a system that induces vibration in a vessel during anchorage. As such, the deterioration of polishing due to insuf icient flow of seawater is inhibited. The reliability of the ultrasonic antifouling system was evaluated by calculating its repeatability. The removal efficiency of fouling of the proposed system was qualitatively evaluated using test specimens. The test revealed that the value of the coefficient of variation for the reproducibility of the frequency and amplitude was 0.2 % and 4.0 % on average. The degree of fouling of the specimens was the highest at 73.3 g in the No.5 sepcimen. Moreover, efficiency of fouling removal was 93.2 % on average compared to the specimens without the proposed system.

The Effect of Freshwater Inflow on the Spatio-temporal Variation of water Qualify of Yeongil Bay (영일만 수질의 시ㆍ공간 변동에 미치는 담수유입의 효과)

  • 김영숙;김영섭
    • Korean Journal of Environmental Biology
    • /
    • v.22 no.1
    • /
    • pp.57-65
    • /
    • 2004
  • In order to determine the effect of fresh water inflow from the Heongsan river on the changes of water quality in the Yeongil Bay (Korea), the seasonal changes of water temperature, salinity, chemical oxygen demand (COD), dissolved inorganic nitrogen(DIN) and phosphate phosphorus ($PO_4$-P) concentrations were examined using the data set obtained five fixed points of Yeongil Bay from 1998 to 2000. The distributions and changes of COD and concentrations of total inorganic phosphorous (TIP) and nitrogen (TIN) at three points Heongsan river, were also compared with those of Yeongil Bay. Based on the correlations of DIN and $PO_4$-P, it was found that the inflow of freshwater affected on the water quality of Yeongil Bay. Such a complicacy was confirmed by the prominent differences in n few water quality measures between Site 1(the innermost area) and Site 5 (the mouth of the bay). The negative correlations in $\Delta N/\Delta P $ at sites 1, 2 and 3 of the inner-part of the bay also indicated a large effect of freshwater inflow on the water quality of the bay. The extremely low atomic ratio of an average of 6.4 in $\Delta N/\Delta P $ compared to the Redfild ratio suggested that the DIN was depleted in the overall bay system. In contrast, it was inferred that the excessive PO$_4$-P concentration was due to the inflow of freshwater from the Heongsan river.

Study on Synthesis of 68GeO2 and Behavior of 68Ga3+ for Generator Column (Generator 컬럼용 68GeO2 합성 및 68Ga3+의 거동에 관한 연구)

  • Kim, Gun Gyun;Lee, Jun Young;Kim, Sang Wook;Hur, Min Gu;Yang, Seung Dae;Park, Jeong Hoon
    • Journal of Radiation Industry
    • /
    • v.10 no.4
    • /
    • pp.189-192
    • /
    • 2016
  • $^{68}Ga$ has emerged as a promising candidate for non-invasive diagnostic imaging within Positron Emission Tomography (PET) because of its advantageous radiochemical characteristics ($t_{1/2}=68min$, ${\beta}^+$ yield ~89%). $^{68}Ga$ forms a stable chelation with various ligands and it is possible to be quickly and easily study using a $^{68}Ge/^{68}Ga$ generator. Commercial $^{68}Ge/^{68}Ga$ generators are chromatographic system using the inorganic materials such as alumina and tin dioxide which are employed as column matrixes for $^{68}Ge$. In this study, we tried out to make $^{68}Ge/^{68}Ga$ generator system with the $^{68}GeO_2$ microstructures for column matrix. $^{68}Ge$ tends to have stable bond with oxide as $^{68}GeO_2$ microstructures. The $^{68}GeO_2$ has been synthesized by hydrolysis of $GeCl_4$ (sol-gel method) and characterized by X-ray diffraction and scanning electron microscope for geometrical analysis. The stability of $GeO_2$ was tested using eluents with diverse solvents(water, ethanol and 0.1 N HCl). The radioactivity of $^{68}Ga^{3+}$ in eluate through $GeO_2$ was measured to prove a function as column material for a generator.