• Composites Research
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• 제37권3호
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• pp.215-218
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• 2024

Diglycidyl ether of 4,4'-dihydroxy-α-methylstilbene (DGE-DHMS)에 aniline을 2:1의 비율로 첨가한 액정에폭시올리고머인 DD-A를 합성하고 촉매성 경화제인 1-Methyl Imidazole을 이용하여 경화시키며 겔화 및 유리화 시간을 측정하여 액정 변화가 포함된 Time-Temperature-Transition Diagram을 작성하였다. 경화제의 농도가 높아질수록 겔화 및 유리화 시간이 감소함을 확인할 수 있었고 유리화 곡선은 전형적인 S-형태를 보였다.

• Fibers and Polymers
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• 제1권2호
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• pp.83-91
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• 2000

Thermotropic liquid crystalline polymer made up of poly(p-hydroxybenzoate) (PHB)-poly(ethylene terephthalate)(PET) 8/2 copolyester, poly(ethylene 2,6-naphthalate) (PEN) and PET were mechanically blended to pursue the liquid crystalline phase of ternary blends. Complex viscosities of blends decreased with increasing temperature and PHB content. DSC thermal analysis indicated that glass transition temperature (Tg) and melting temperature (Tm) of blends increased with increasing PHB content. Both tensile strength and initial modulus increased with raising PHB content and take-up speed of monofilaments. In the WAXS diagram, only PEN crystal reflection at 2Θ=$15.5^{\circ}C$ appeared but PET crystal reflection was not shown in all compositions. The degree of transesterification and randomness of blends increased with blending time but sequential length of both PEN and PET segment decreased.

• 한국주조공학회지
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• 제23권5호
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• pp.276-285
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• 2003

In the undercooled melt of $Pd_{40}Cu_{30}Ni_{10}P_{20}$ alloy, the solidification behavior including nucleation and growth of crystals at the micrometer level has been observed in-situ by use of a confocal scanning laser microscope combined with an infrared image furnace. The $Pd_{40}Cu_{30}Ni_{10}P_{20}$ alloy specimens were cooled from the liquid state to glass transition temperature. 575 K, at various cooling late under a helium gas flow. According to the cooling rate, the morphologies of the solidification front are changed among various types, irregular jog like front, columnar dendritic front, cellular grain, star like shape jog and fine grain, etc. The velocities of the solid-liquid interface are measured to be $10^{-5}{\sim}10^{-8}$ m/s which are at least two orders higher than the theoretical crystal growth rates. Combining the morphologies observed in terms of cooling rates and their solidification behaviors, we conclude that phase separation takes place in the undercooled molten $Pd_{40}Cu_{30}Ni_{10}P_{20}$ alloy. The continuous cooling transformation (CCT) diagram was constructed from solidification onset time at various linear cooling conditions with different rate. The CCT diagram suggests that the critical cooling rate for glassy solidification is about 1.5 K/s, which is in agreement with the previous calorimetric findings.

• Progress in Superconductivity
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• 제4권2호
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• pp.153-156
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• 2003

We have studied fabrication of $MgB_2$ thin film on $SrTiO_3$ (001) and r-cut $A1_2$$O_3$ substrates by rf magnetron sputtering method using and $ MgB_2$ single target and two targets of Mg and B, respectively. Based on P -T phase diagram of $MgB_2$ and vapor pressure curves of Mg and B, a three-step process was employed. B layer was deposited at the bottom to enhance the film adhesion to the substrate. Secondly, co-sputtering of Mg and B was done. Finally, Mg was sputtered on top to compensate fur the loss of Mg during annealing. Subsequently, $MgB_2$ films were in-situ annealed in various conditions. The sample fabricated using the three-step process showed $T_{c}$ of 24 K and formation of superconducting $MgB_2$ phase was confirmed by XRD spectra. In case of co-sputtering deposition, $T_{c}$ depended on annealing time and argon pressure. However, those made by single-target sputtering showed non-superconducting behavior or low transition temperature, at best.est.

• 대한전기학회논문지:전기기기및에너지변환시스템부문B
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• 제49권11호
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• pp.729-736
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• 2000

This paper deals with the characteristic analysis of magnetizer for convergence purity magnet by the finite element method. The analysis utilizes combined method of the time-stepped finite element analysis and the Preisach model with hysteresis phenomena. In the finite element analysis, the non-linearity and the eddy current of the magnetizing fixure and permanent-magnet are taken account. The magnetization distribution in the permanent magnet is determined by using Preisach model which are composed of Everett function table and the first order transition curves is obtained by the Vibrating Sample Magnetometer. The calculated flux density values on the surface of the permanent magnet are led to the approximated gauss density values measured by the gauss meter. As a result, winding current, copper loss, eddy current loss of the magnetizing yoke, flux plot, surface gauss plot, temperature rise of the coil and resistor variation, vector diagram of magnetization distribution are shown.