• Journal of the Korean Wood Science and Technology
• /
• v.39 no.5
• /
• pp.381-389
• /
• 2011

The effect of organoclays on the mechanical properties of cured phenol formaldehyde resin and oriented strand lumber made from Mountain Pine Beetle killed pine strands was analyzed. Three organoclays were used: a natural montmorillonite, hydrophobic organically modified 10 A, and hydrophilic organically modified 30 B. The oriented strand lumber samples were less creep deformation as well as improved internal bonding strength by adding organoclays in the order of 10 A 2% > MMT 2% > 30 B 2% > control. Furthermore, time-temperature superposition (TTS) analysis was proved to be able to predict the long-term creep behavior of MPB-OSL samples.

• Elastomers and Composites
• /
• v.53 no.4
• /
• pp.195-201
• /
• 2018

Three kinds of rubber compounds were prepared, and their underwater acoustical properties were investigated for anechoic coating. Dynamic mechanical properties of the rubber compounds were measured using a dynamic mechanical analyzer and extended to 100 kHz using time-temperature superposition. The sound speed, reflection coefficient, and attenuation constant were calculated. Silicone rubber showed the lowest reflection coefficient, and nitrile rubber showed the highest attenuation constant. The acoustic properties of nitrile rubber compounds with various compositions were investigated. The sound speed, reflection coefficient, and transmission coefficient of the nitrile rubber in the frequency range of 200-1000 kHz were measured in a water-filled tank.

• Food Science and Biotechnology
• /
• v.17 no.1
• /
• pp.90-94
• /
• 2008

Dynamic rheological properties of honey samples with 3 different moisture contents (17.2, 19.0, and 21.0%) were evaluated at various low temperatures (-15, -10, -5, and $0^{\circ}C$) using a controlled stress rheometer. The honey samples displayed a liquid-like behavior, with loss modulus (G") predominating over storage modulus (G') (G">>G'), showing the high dependence on frequency ($\omega$). The magnitudes of G' and G" decreased with an increase in temperature and water content while a predominant increase of G' was noticed at $-15^{\circ}C$. The time-temperature superposition (TTS) principle was applied to bring G" values for honeys at various temperatures together into a master curve. The G" over the temperature range of -15 to $0^{\circ}C$ obeyed the Arrhenius relationship with a high determination coefficient ($R^2=0.98-0.99$). Activation energy value (Ea=112.4 kJ/mol) of honey with a moisture content of 17.2% was higher than those (Ea=98.8-101.1 kJ/mol) of other honey samples with higher moisture contents.

• Food Science and Biotechnology
• /
• v.16 no.4
• /
• pp.610-614
• /
• 2007

Dynamic rheological properties of honeys with invert sugar at different mixing ratios of honey and invert sugar (10/0, 812, and 6/4 ratios) were evaluated at various low temperatures (-15, -10, -5, and $0^{\circ}C$) using a controlled stress rheometer for small-deformation oscillatory measurements. Honey-invert sugar mixtures displayed a liquid-like behavior, with loss modulus (G") predominating over storage modulus (G') (G">>G'), showing the high dependence on frequency (${\omega}$). The magnitudes of G' and G" increased with a decrease in temperature while their predominant increases were noticed at -10 and $-15^{\circ}C$. The greater tan ${\delta}$ values were found at higher temperature and ratio of honey to invert sugar, indicating that the honey samples at subzero temperatures become more viscous with increased ratio of honey to invert sugar and temperature. The time-temperature superposition (TTS) principle was used to bring G" values at various temperatures together into a single master curve. The TTS principle was suitable for the honey samples in the liquid-like state. The progress of viscous property (G") was also described well by the Arrhenius equation with high determination coefficients ($R^2=0.99$). Dynamic rheological properties of honey samples seem to be greatly influenced by the addition of invert sugar.

• Journal of the Korean Geosynthetics Society
• /
• v.4 no.1
• /
• pp.3-6
• /
• 2005

The failure of geogrids can be defined as an excessive creep strain which causes the collapse of slopes and embankments. In this study, the lifetime of knitted polyester geogrids was predicted by using SIM(Stepped Isothermal Methods using TTS principal) and statistical data analysis techniques. The results indicate that the creep strain was 8.74, 8.79, 8.80% with 2.16~2.20% of CV% at 75, 100, 114 years, respectively and the creep strain reaches 9.3% after 100 years of usage at $27^{\circ}C$ which meets the required lifetime(creep strain less than 10% after 100 years of usage) in the fields. The SIM method is shown to be effective in reduction of uncertainty associated with inherent variability of multi-specimen tests and shorter test times than conventional TTS(Time-Temperature Superposition).

• Journal of the Korean Geotechnical Society
• /
• v.19 no.5
• /
• pp.291-299
• /
• 2003

The effect of temperature and soil confining stress on geosyntheic creep behaviour was studied by performing the temperature dependent confined creep tests for HDPE geogrid and geomembrane specimen. The visco-elastic creep coefficients of the geosynthetics were evaluated by the test results and it was proposed that the simple expressions for the instantaneous and limit creep strain of geosynthetics was considered as a function of temperature and confining stress on geosynthetics. Based on the time-temperature superposition principle, a master curve has been drawn for extrapolating tensile creep strains to longer time intervals(1$\times$10 $^7$min.∼1$\times$10$^{10}$min.). By using this master curves, the shift factors which can be used in establishing master curve considering confining stress on geosynthetics were carried out. Each tests was performed during 8,000∼12,000 min., with temperature ranging between 5$^{\circ}C$ and 4$0^{\circ}C$ and with confining stress ranging between 0 t/$m^2$ and 9 t/$m^2$.

• Composites Research
• /
• v.32 no.1
• /
• pp.78-84
• /
• 2019

This study focused on the prediction of the long-term performance of carbon fiber/epoxy composites using Dynamic Mechanical Analysis (DMA) and Time-Temperature Superposition (TTS). Single-frequency test, multi-frequency test, and creep TTS test were performed. A sinusoidal load of $20{\mu}m$ amplitude was applied while increasing the temperature from $-30^{\circ}C$ to $240^{\circ}C$ at $2^{\circ}C/min$ for the single-frequency test and the multi-frequency test. The frequencies applied to the multi-frequency test were 0.316, 1, 3.16, 10 and 31.6 Hz. In the creep TTS test, a stress of 15 MPa was applied for 10 minutes at every $10^{\circ}C$ from $-30^{\circ}C$ to $230^{\circ}C$. The glass transition temperature was determined by single-frequency test. The activation energy and the storage modulus curve for each temperature were obtained from glass transition temperature for each frequency by the multi-frequency test. The master curve for the reference temperature was obtained by applying the shift factor using the Arrhenius equation. Also, TTS test was used to obtain the creep compliance curves for each temperature and the master curve for the reference temperature by applying the shift factors using the manual shift technique. The master curve obtained through this process can be applied to predict the long-term performance of carbon fiber/epoxy composites for a given environmental condition.

• Proceedings of the KSME Conference
• /
• 2000.04a
• /
• pp.751-754
• /
• 2000

Stress relaxation experiments were performed to obtain the material properties to be used in the linear viscoelastic study. Master curve of the modulus of polystyrene were obtained by using the time-temperature superposition principle. Because Shyu and Tobolsky's tensile relaxation modulus master curve or Polystyrene material showed very large difference, in-house data were required to calculate the residual stresses in injection-molded products more accurately. Our own experimental data showed that the master curve Shyu's data should be shifted about two orders in material time coordinate.

• Bulletin of the Korean Chemical Society
• /
• v.23 no.3
• /
• pp.413-416
• /
• 2002

The dielectric responses of 10 and 40 wt% siloxane-epoxy copolymers were investigated in temperature range near the glass transition of polydimethylsiloxane at which the dielectric transitions were also observed. On the other hand, the pure epoxy did not show any dielectric transition in measurement temperature range -90 to 150 $^{\circ}C.$ The experimental data showed that for the copolymer investigated, the temperature-frequency super-position principle could be applied to the dielectric response. From the Cole-Cole equation, the dielectric relaxation of the 10 wt% siloxane near the glass transition temperature resulted in a broad distribution with ${\beta}=$ 0.19 and the relaxation time at -70 $^{\circ}C$ was 5.3 ${\times}$ $10^{-2}$s. The glass transition temperature, 188 K, was estimated by using WLF relation, which was consistent with the data presented in experiment.

• Journal of the Korean Society of Propulsion Engineers
• /
• v.23 no.1
• /
• pp.46-51
• /
• 2019

Intermittent CSR testing was used to investigate the degradation of a NBR O-ring, and also the prediction of its life-time. An intermittent CSR jig was designed taking into consideration the O-ring's environment under use. Degradation of O-rings by thermal aging was observed between $40^{\circ}C$ and $120^{\circ}C$. O-rings showed non-linear degradation behavior under $80^{\circ}C$. At 20% of failure condition, predicted life-times were 32.5 years by Arrhenius plot and 22.6 years by WLF plot.