• Title/Summary/Keyword: Time of Gas Emission

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A Study of Nitrous Oxide Thermal Decomposition and Reaction Rate in High Temperature Inert Gas (고온 불활성 기체 분위기에서 아산화질소 열분해 및 반응속도에 관한 연구)

  • Lee, Han Min;Yun, Jae Geun;Hong, Jung Goo
    • Journal of ILASS-Korea
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    • v.25 no.3
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    • pp.132-138
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    • 2020
  • N2O is hazardous atmosphere pollution matter which can damage the ozone layer and cause green house effect. There are many other nitrogen oxide emission control but N2O has no its particular method. Preventing further environmental pollution and global warming, it is essential to control N2O emission from industrial machines. In this study, the thermal decomposition experiment of N2O gas mixture is conducted by using cylindrical reactor to figure out N2O reduction and NO formation. And CHEMKIN calculation is conducted to figure out reaction rate and mechanism. Residence time of the N2O gas in the reactor is set as experimental variable to imitate real SNCR system. As a result, most of the nitrogen components are converted into N2. Reaction rate of the N2O gas decreases with N2O emitted concentration. At 800℃ and 900℃, N2O reduction variance and NO concentration are increased with residence time and temperature. However, at 1000℃, N2O reduction variance and NO concentration are deceased in 40s due to forward reaction rate diminished and reverse reaction rate appeared.

A Study on the Emission Characteristics of Greenhouse Gas by Cumulative Mileage of Gasoline Vehicle (가솔린 차량의 누적주행거리에 따른 온실가스 배출특성 연구)

  • Park, Jin-sung;Lim, Jae-Hyuk;Kim, Ki-Ho;Lee, Jung-Min
    • Journal of ILASS-Korea
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    • v.23 no.4
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    • pp.227-233
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    • 2018
  • An automobile is composed of a combination of a lot of parts, and it is difficult to maintain the same performance from a new car until it's scrapped. Greenhouse gases included in automobile emissions are typically carbon dioxide and methane. It is expected that this greenhouse gas will change depending on the aging (cumulative mileage) of the automobile However, the greenhouse gas characteristics by cumulative mileage lack of actual data due to time and economic difficulties. Therefore, in this paper, we selected automobile with high sales by displacement in korea and carbon dioxide and methane were measured by using method of the related law. The cumulative mileage is as follows; within 160 km (Statutory mileage by 2010), 6500 km (current statutory mileage), 15000 km (approximately 1-year average mileage of Non-business passenger vehicle). As a result of the test, the emission of carbon dioxide and methane was the smallest at 6,500 km, and increased in order of 15000 km, within 160 km. Also, it was confirmed that the $CO_2$ emission change of a large displacement automobile is more smaller at each mileage. Although the greenhouse gas tends to increase as the mileage of the vehicle, it is thought that additional confirmation is required of since 15,000 km as well, because it can occur deviations due to taming process or mechanical friction of the automobile.

NUMERICAL ANALYSIS OF A SAMPLING MODULE FOR A FAST RESPONSE EXHAUST GAS ANALYZER

  • Kim, W.S.;Lee, J.H.;Yoo, J.S.;Rhee, B.O.;Park, J.I.
    • International Journal of Automotive Technology
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    • v.8 no.2
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    • pp.149-154
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    • 2007
  • The engine behavior in a transient condition is important to not only emission regulations but also fuel economy. A fast response gas analyzer can be a useful tool to investigate exhaust gas in a transient operation. It should be designed to analyze gas concentration with a short time constant by a fast sampling module and an appropriate measuring method for each emission element. In this study, a new fast sampling module is introduced and flow analysis is performed by numerical simulation. The analysis has shown the proper operating condition and the sensitivity of the module for practical application. Calculated flow to the sampling module has $0.5{\sim}4%$ error, while backflow toward the expansion tube is expected when pressure in CP (Constant Pressure) chamber is over 0.6 bar. For a stable supply of flow to the optical cell, sample gas pressure should be in the range, $0.35{\sim}1.90$ bar, when the pressure in the CP camber and the optical cell are 0.2 bar and 0.158 bar, respectively.

Assessment of Landfill Gas Generation - A Case Study of Cheongju Megalo Landfill (매립지 가스 발생량 평가 - 청주권 광역생활폐기물 매립장 사례연구)

  • Hong, Sang-Pyo
    • Journal of Environmental Impact Assessment
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    • v.17 no.5
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    • pp.321-330
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    • 2008
  • Methane is a potent greenhouse gas and methane emissions from landfills have been linked to global warming. In this study, LandGEM (Landfill Gas Emission Model) was applied to predict landfill gas quantity over time, and then this result was compared with the data surveyed on the site, Cheongju Megalo Landfill. LandGEM allows the input of site-specific values for methane generation rate (k) and potential methane generation capacity $L_o$, but in this study, k value of 0.05/yr and $L_o$ value of $170m^3/Mg$ were considered to be most appropriate for reflecting non-arid temperate region conventional landfilling, Cheongju Megalo Landfill. High discrepancies between the surveyed data and the predicted data about landfill gas seems to be derived from insufficient compaction of daily soil-cover, inefficient recovery of landfill gas and banning of direct landfilling of food garbage waste in 2005. This study can be used for dissemination of information and increasing awareness about the benefits of recovering and utilizing LFG (landfill gas) and mitigating greenhouse gas emissions.

The Effect of Bacillus-based Feed Additive on Growth Performance, Nutrient Digestibility, Fecal Gas Emission, and Pen Cleanup Characteristics of Growing-finishing Pigs

  • Upadhaya, S.D.;Kim, S.C.;Valientes, R.A.;Kim, I.H.
    • Asian-Australasian Journal of Animal Sciences
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    • v.28 no.7
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    • pp.999-1005
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    • 2015
  • Bacillus-based feed additive was evaluated for its efficacy on growth performance, nutrient digestibility, fecal gas emission, and the consumption of time and amount of water for cleaning the pen of growing finishing pigs. A total of 120 growing pigs ($23.59{\pm}1.41kg$) were used in a 16-wk feeding trial. Pigs were randomly distributed into 1 of 2 treatments on the basis of body weight and sex. There were 12 replicate pens per treatment, with 5 pigs (3 barrows and 2 gilts) per pen. Dietary treatments were CON which was basal diet, and T1 which was CON+62.5 ppm microbial feed additive that provided $1.47{\times}10^8cfu$ of Bacillus organisms per gram of supplement. During the weeks 0 to 6, average daily gain (ADG) in T1 treatment was higher (p<0.05) than CON, but no improvement in average daily feed intake (ADFI) and feed efficiency (G:F) was noted. During 6 to 16 weeks, no difference (p>0.05) was noted in growth performance. However, ADG was improved (p<0.05) and overall ADFI tended (p = 0.06) to improve in T1 compared with CON. At week 6, the co-efficient of apparent total tract digestibility (CATTD) of dry matter (DM) nitrogen (N) was increased (p<0.05) in T1 compared with CON. Fecal $NH_3$ emission was decreased (p<0.05) in T1 compared with CON, at the end of 6th and 15th weeks. The time and water consumed for washing the pens were decreased (p<0.05) in T1 compared with CON. In conclusion, supplementation with Bacillus-based feed additive could improve the overall growth performances, increase the CATTD of DM and decrease the fecal $NH_3$ content and the time and water consumed in washing the pens for growing-finishing pigs.

Simulation Analysis of MILD Combustion and NOx Formation for Methane-Hydrogen Mixture Using 0D Model (0D 모델을 활용한 메탄-수소 혼소에 따른 MILD 연소 및 NOx 배출 특성 해석 연구)

  • AN, SOJEONG;PARK, JINJE;BAE, YOUN-SANG;LEE, YOUNGJAE
    • Transactions of the Korean hydrogen and new energy society
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    • v.33 no.4
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    • pp.400-412
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    • 2022
  • Hydrogen with high chemical reactivity and combustion efficiency, is expected to reduce greenhouse gas and CO emission. However, there is a problem of increase in NOx emission due to hydrogen combustion. MILD combustion technology has been proposed to resolve NOx emission. In this study, the characteristics of MILD combustion and NOx formation by flue gas recirculation (KV) in CH4-H2 mixture were analyzed and predicted using 0D premixed combustion model. The ignition delay time became shorter as the hydrogen co-firing rate increased, and longer as the recirculation rate increased. For NOx emission, EINO decreased as the KV increased, but EINO increased as the hydrogen co- firing rate increased. In particular, EINO was predicted to increase significiently above 80% hydrogen. Through the pathway analysis of NO formation, it was found that the influence of N2O intermediate route and NNH route was enhanced for hydrogen co-firing.

Estimation of Methane Generation Rate and Potential Methane Generation Capacity at Cheongju Megalo Landfill Site Based on LandGEM Model (LandGEM 모델을 이용한 청주권 생활폐기물 매립장의 매립지가스 발생상수 및 메탄 잠재발생량 산정)

  • Hong, Sang-Pyo
    • Journal of Environmental Health Sciences
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    • v.34 no.6
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    • pp.414-422
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    • 2008
  • Methane is a potent greenhouse gas and methane emissions from landfill sites have been linked to global warming. In this study, LandGEM (Landfill Gas Emission Model) was applied to predict landfill gas quantity over time, and then this result was compared with the data surveyed on the site, Cheongju Megalo Landfill. LandGEM allows the input of site-specific values for methane generation rate (k) and potential methane generation capacity $L_o$, but in this study, k value of 0.04/yr and $L_o$ value of $100\;m^3$/ton were considered to be most appropriate for reflecting non-arid temperate region conventional landfilling like Cheongju Megalo Landfill. Relatively high discrepancies between the surveyed data and the predicted data about landfill gas seems to be derived from insufficient compaction of daily soil-cover, inefficient recovery of landfill gas and banning of direct landfilling of food waste in 2005. This study can be used for dissemination of information and increasing awareness about the benefits of recovering and utilizing LFG (landfill gas) and mitigating greenhouse gas emissions.

Fatigue Characteristics and its Nondestructive Evaluation of Fire-resistance Steel for Construction with Low Yield Ratio and High Strength (저항복비·고강도 구조용 내화강의 피로특성 및 비파괴평가)

  • Kim, H.S.;Nam, K.W.;Kang, C.Y.
    • Journal of the Korean Society for Heat Treatment
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    • v.14 no.4
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    • pp.212-219
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    • 2001
  • The fatigue test was carried out to evaluate the fatigue characteristics of fire resistance steel for frame structure and heat affected zone (HAZ) by the one side Gas Metal Arc Welding (GMAW). In this paper, the fatigue crack growth behavior was investigated with the compact tension specimen of base metal and the HAZ according to chemical composition and rolling end temperature, respectively. And the acoustic emission signals obtained from the fatigue test were analyzed by the time-frequency analysis method as a nondestructive evaluation. Main results obtained are summarized as follows; The hardness was appeared softening phenomenon that weld metal and HAZ are lower than that of base metal. Fatigue life of welded specimen was longer than that of base metal. m was 3~4.5 in base metal and 3.8~5.8 in HAZ. The main frequency range of acoustic emission signal analyzed from time-frequency method is different with the range by noise and crack. Also, it could be classified that it was also generated by fracture mechanics of dimple, inclusion etc.

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IDLE PERFORMANCE OF AN SI ENGINE WITH VARIATIONS IN ENGINE CONTROL PARAMETERS

  • Kim, D.S.;Cho, Y.S.
    • International Journal of Automotive Technology
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    • v.7 no.7
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    • pp.763-768
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    • 2006
  • Emission reduction in the cold start period of SI engines is crucial to meet stringent emission regulations such as SULEV Emissoin reduction is the starting point of the study in the which the variable valve timing (VVT) technology may be one promising method to minimize cold start emissions while maintaining engine performance. This is because it is possible to change valve overlap and residual gas fraction during cold start and idle operations. Our previous study showed that spark timing is another important factor for reducing cold-start emissions since it affects warm-up time of close-coupled catalysts (CCC) by changing exhaust gas temperature. However, even though these factors may be favorable for reduction of emissions, they may deteriorate combustion stability in these operating conditions. This means that the two variables should be optimized for best exhaust emissions and engine stability. This study investigated the effects of valve and spark timings in idle performance such as combustion stability and exhaust emissions. Experiments showed that valve timings significantly affected engine stability and exhaust emissions, especially CO and $NO_x$, due to change in residual gas fraction within the combustion chamber. Spark timing also affects HC emissions and exhaust gas temperature. Yet it has no significant effects on combustion stability. A control strategy of proper valve timing and spark timing is suggested in order to achieve a reduction in exhaust emissions and a stable operation of the engine in a cold start and idle operation.

Source, Sinks and Distribution of Greenhouse Greenhouse Gas $Na_2O$ (지구온난화 기체 $Na_2O$의 거동에 관한 고찰)

  • 신찬기
    • Journal of environmental and Sanitary engineering
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    • v.9 no.1
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    • pp.62-66
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    • 1994
  • Nitrous Oxide( NaO), one of the green house gases, is not confirmed it's sources, sinl life time in the atmosphere clearly so far, In this paper, the emission sources physical characteristics, concentration in the air, monitoring method and distribution for the global warming gas were summarized.

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