• Title/Summary/Keyword: Time Span

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Effects of HLB value on oil-in-water emulsions: Droplet size, rheological behavior, zeta-potential, and creaming index

  • Hong, In Kwon;Kim, Su In;Lee, Seung Bum
    • Journal of Industrial and Engineering Chemistry
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    • v.67
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    • pp.123-131
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    • 2018
  • Using mixed nonionic surfactants Span/Tween, we investigated the effects of HLB value on the O/W emulsion stability and rheological behaviors. In this study, MS-01 (Span 60 & Tween 60) and MS-02 (Span 80 & Tween 80) was used as mixed nonionic surfactants. We considered required HLB value 10.85 and selected corresponding HLB value range 8-13. The droplet size distributions, droplet morphology, rheological properties, zeta-potential and creaming index of the emulsion samples were obtained to understand the mechanism and interaction of droplets in O/W emulsion. The results indicated that optimal HLB number for O/W emulsions was 10.8 and 10.7, while using MS-01 surfactant and MS-02 surfactant respectively. MS-01 (HLB = 10.8) sample and MS-02 (HLB = 10.7) sample showed smallest droplet size and highest zeta-potential value. Rheological properties are measured to understand rheological behaviors of emulsion samples. All emulsion samples showed no phase separation until 30 days storage time at $25^{\circ}C$.

The Study on the Preparation of the Silica Particles by the Reactive Crystallization (반응 결정화에 의한 실리카 미립자 합성에 관한 연구)

  • Kim, Jun Ho;Lee, Chang Hwan;Lee, Choul Ho
    • Applied Chemistry for Engineering
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    • v.17 no.1
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    • pp.12-15
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    • 2006
  • The purpose of this study was to investigate the effect of reaction conditions, solvents, and surfactants on the average size and size distribution of silica particles in preparing silica fine powders by sodium silicate. Silica fine particles were synthesized by varying kinds of solvents and surfactants using the emulsion method. Span 20, Span 40, Span 60, and Span 80 were used as nonionic surfactants, Dispersing solvents were n-Hexane, n-Heptane, iso-Octane, and n-Decane of the alkane group. In these experiments, it was known that the optimum dispersion stirring time to form the emulsion of the constant size was around 6 min. The mean sizes of silica particles, at a variety of the dispersion stirring speeds, decreased as the dispersion stirring speed increased. Also, in the case of the solvents, the size of the formed silica particles decreased when the molecular weight of the solvent increased. Lastly, in the case of the surfactants, the mean size of silica particles increased as the hydrophobic lipophilic balance (HLB) value of the surfactant decreased.

Combined Effect of Lidocaine Hydrochloride with Some Surfactants ( I ) (유화제(乳化劑)와 Lidocaine.HCl의 병용효과에 관(關)한 연구(硏究)( I ))

  • Kim, Yong-Hyoun;Yeum, Chul-Ho;Choi, Jun-Shik
    • Journal of Pharmaceutical Investigation
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    • v.12 no.2
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    • pp.31-36
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    • 1982
  • The effect of some surfactants, such as tween 40, tween 80, span 80, and triethanolamine, on the absorption of lidocaine was studied using goldfish as a model of absorption kinetics. This model was believed that reciprocal overturn time and death time were the occurrence of biological effect versus drug absorption. The results were as follows; The threshold concentration of lidocaine was significantly reduced by the surfactants. Overturn time and death time of goldfish in the lidocaine solution were reduced by such surfactants as tween 40, tween 80, span 80 and triethanolamine, and more reduced with increasing concentration of surfactants except tween 40 and tween 80. The plots of reciprocal death time versus lidocaine concentration were linear relationship with a positive concentration intercept such as minimum effective concentration (0.2-0.8%). As results it is believed that these surfactants may form complexes with lidocaine or affect the goldfish membrane to make more permeable to lidocaine, which is adsorbed more rapidly.

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Effects of Salinity on Demographic Traits of the Rotifer (Brachionus rotundiformis)

  • Viayeh Reza Malekzadeh;Song Choon Bok
    • Fisheries and Aquatic Sciences
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    • v.7 no.1
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    • pp.39-45
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    • 2004
  • Six demographic parameters including life span (LS), maturation time (MT), net reproduction rate (Ro), mean generation length (G), innate capacity for increase $(r_m)$ and finite rate of increase $(\gamma)$ were estimated in the rotifer (Brachionus rotundiformis) cultured at three salinities of 5, 20 and 34 PSU and under a constant temperature of $28^{\circ}C$. The maximum life spans at salinities of 5, 20 and 34 PSU were 17, 12 and 13 days, respectively. The shortest maturation time (24 hr) was recorded at 5 PSU, and the rotifer at 20 PSU showed a most delayed maturation (192 hr). The maximum reproduction rate was 42 offspring per female in rotifer cultured at 5 PSU, while the longest generation length (8 days) was observed at 20 PSU. Maximum and minimum values of $r_m$ (1.56 and 0.46 individual per day) and $(\gamma)$ (6.67 and 1.70 individuals per day) were calculated at 5 and 34 PSU, respectively. Salinity also showed strong effect on correlation of the demographic traits examined. ANOVA revealed significant differences (P<0.05) between demographic parameters of the rotifer at the three salinity condition. Considering the higher values of life span, innate capacity and finite rate of increase, and shortest maturation time at 5 PSU, the rotifer we examined had a higher reproductive potential and longer life span at 5 PSU rather than at 20 or 34 PSU.

Field Investigation of Composite Behavior in High-speed Railway PSC Box Girder Bridge (고속전철 PSC 박스거더교 합성거동의 현장 계측에 관한 연구)

  • 김영진;김병석;강재윤
    • Proceedings of the Korea Concrete Institute Conference
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    • 2000.10b
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    • pp.995-1000
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    • 2000
  • Segmentally erected prestressed concrete box girder bridges have been widely used in Korean high speed railway. Segmental erection has been accomplished along the longitudinal direction and across the depth of cross section. The cross section is similar to a composite cross section, composed of old and new segments. Because these segments have different time-dependent creep and shrinkage properties, a stress redistribution takes place during the construction period. It is the main objective in this research to investigate this behavior. An actual bridge was instrumented with 96 vibrating wire embedded type strain gauges, 6 electronic type steel strain gauges, and 75 thermocouples. Two span continuous high speed railway bridge was selected. Two points of importance, such as the midpoint of the first span and the point of interior support, along the span of the girder were chosen to monitor the time dependent behaviors for an extended period of time. The data collection was starting just after concrete girder were cast and is still going on. According to the measured results, the strain distributions across the depth of the section at midspan and interior support were not continuous and the important redistribution of stresses takes place. Thus, rational design of prestressed concrete composite box girder bridges need.

An efficient method for universal equivalent static wind loads on long-span roof structures

  • Luo, Nan;Liao, Haili;Li, Mingshui
    • Wind and Structures
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    • v.25 no.5
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    • pp.493-506
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    • 2017
  • Wind-induced response behavior of long-span roof structures is very complicated, showing significant contributions of multiple vibration modes. The largest load effects in a huge number of members should be considered for the sake of the equivalent static wind loads (ESWLs). Studies on essential matters and necessary conditions of the universal ESWLs are discussed. An efficient method for universal ESWLs on long-span roof structures is proposed. The generalized resuming forces including both the external wind loads and inertial forces are defined. Then, the universal ESWLs are given by a combination of eigenmodes calculated by proper orthogonal decomposition (POD) analysis. Firstly, the least squares method is applied to a matrix of eigenmodes by using the influence function. Then, the universal ESWLs distribution is obtained which reproduces the largest load effects simultaneously. Secondly, by choosing the eigenmodes of generalized resuming forces as the basic loading distribution vectors, this method becomes efficient. Meanwhile, by using the constraint equations, the universal ESWLs becomes reasonable. Finally, reproduced largest load effects by load-response-correlation (LRC) ESWLs and universal ESWLs are compared with the actual largest load effects obtained by the time domain response analysis for a long-span roof structure. The results demonstrate the feasibility and usefulness of the proposed universal ESWLs method.

Multiple characteristic response damage analysis of large-span space structures based on equivalent damping ratio

  • Wei, Jun;Yang, Qingshun;Zhou, Lexiang;Chen, Fei
    • Earthquakes and Structures
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    • v.23 no.4
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    • pp.339-352
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    • 2022
  • Due to the large volume and generally as a public building, the damage of large-span space structures under various non-conventional loads will cause greater economic losses, casualties, and social impacts, etc. Therefore, it is particularly important to evaluate the seismic performance of large-span space structures. This paper taked a multipurpose sports center as an example and considered its synergistic deformation based on the method of equivalent damping ratio. Furthermore, The ABAQUS software was used to analyze the time-history and energy response of the multipurpose sports center under the action of rare earthquakes, and proposed a quantitative damage index to assess the overall damage of the structure. Finally, the research results indicated that the maximum inter-story drift ratio of the multipurpose sports center under the action of rare earthquakes was less than its limit value. The frame beams presented different degrees of damage, but the key members were basically in an elastic state. The bearing capacity did not reach the limit value, which satisfied the intended seismic performance target. This study taked an actual case as an example and proposed a relevant damage evaluation system, which provided some reference for the analysis of the seismic performance of large-span space structures.

Operational modal analysis of a long-span suspension bridge under different earthquake events

  • Ni, Yi-Qing;Zhang, Feng-Liang;Xia, Yun-Xia;Au, Siu-Kui
    • Earthquakes and Structures
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    • v.8 no.4
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    • pp.859-887
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    • 2015
  • Structural health monitoring (SHM) has gained in popularity in recent years since it can assess the performance and condition of instrumented structures in real time and provide valuable information to the asset's manager and owner. Operational modal analysis plays an important role in SHM and it involves the determination of natural frequencies, damping ratios and mode shapes of a constructed structure based on measured dynamic data. This paper presents the operational modal analysis and seismic response characterization of the Tsing Ma Suspension Bridge of 2,160 m long subjected to different earthquake events. Three kinds of events, i.e., short-distance, middle-distance and long-distance earthquakes are taken into account. A fast Bayesian modal identification method is used to carry out the operational modal analysis. The modal properties of the bridge are identified and compared by use of the field monitoring data acquired before and after the earthquake for each type of the events. Research emphasis is given on identifying the predominant modes of the seismic responses in the deck during short-distance, middle-distance and long-distance earthquakes, respectively, and characterizing the response pattern of various structural portions (deck, towers, main cables, etc.) under different types of earthquakes. Since the bridge is over 2,000 m long, the seismic wave would arrive at the tower/anchorage basements of the two side spans at different time instants. The behaviors of structural dynamic responses on the Tsing Yi side span and on the Ma Wan side span under each type of the earthquake events are compared. The results obtained from this study would be beneficial to the seismic design of future long-span bridges to be built around Hong Kong (e.g., the Hong Kong-Zhuhai-Macau Bridge).

Comparison between wind load by wind tunnel test and in-site measurement of long-span spatial structure

  • Liu, Hui;Qu, Wei-Lian;Li, Qiu-Sheng
    • Wind and Structures
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    • v.14 no.4
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    • pp.301-319
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    • 2011
  • The full-scale measurements are compared with the wind tunnel test results for the long-span roof latticed spatial structure of Shenzhen Citizen Center. A direct comparison of model testing results to full-scale measurements is always desirable, not only in validating the experimental data and methods but also in providing better understanding of the physics such as Reynolds numbers and scale effects. Since the quantity and location of full-scale measurements points are different from those of the wind tunnel tests taps, the weighted proper orthogonal decomposition technique is applied to the wind pressure data obtained from the wind tunnel tests to generate a time history of wind load vector, then loads acted on all the internal nodes are obtained by interpolation technique. The nodal mean wind pressure coefficients, root-mean-square of wind pressure coefficients and wind pressure power spectrum are also calculated. The time and frequency domain characteristics of full-scale measurements wind load are analyzed based on filtered data-acquisitions. In the analysis, special attention is paid to the distributions of the mean wind pressure coefficients of center part of Shenzhen Citizen Center long-span roof spatial latticed structure. Furthermore, a brief discussion about difference between the wind pressure power spectrum from the wind tunnel experiments and that from the full-scale in-site measurements is compared. The result is important fundament of wind-induced dynamic response of long-span spatial latticed structures.

Seismic Response on Thin Shell as Structural Foundation (기초구조물로서 얇은 쉘 구조물의 지진응답)

  • Yee Hooi Min;Azizah Abdul Nassir;Kim Jae Yeol
    • Journal of Korean Association for Spatial Structures
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    • v.24 no.2
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    • pp.31-41
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    • 2024
  • This study aims to investigate the seismic response of a large span thin shell structures and assess their displacement under seismic loads. The study employs finite element analysis to model a thin shell structure subjected to seismic excitation. The analysis includes eigenvalue analysis and time history analysis to evaluate the natural frequencies and displacement response of the structure under seismic loads. The findings show that the seismic response of the large span thin shell structure is highly dependent on the frequency content of the seismic excitation. The eigenvalue analysis reveals that the tenth mode of vibration of the structure corresponds to a large-span mode. The time history analysis further demonstrates, with 5% damping, that the displacement response of the structure at the critical node number 4920 increases with increasing seismic intensity, reaching a maximum displacement of 49.87mm at 3.615 seconds. Nevertheless, the maximum displacement is well below the allowable limit of the thin shell. The results of this study provide insight into the behaviour of complex large span thin shell structures as elevated foundations for buildings under seismic excitation, based on the displacement contours on different modes of eigenvalues. The findings suggest that the displacement response of the structure is significant for this new application of thin shell, and it is recommended to enhance the critical displacement area in the next design phase to align with the findings of this study to resist the seismic impact.