• 제목/요약/키워드: TiC-Mo

검색결과 213건 처리시간 0.024초

시화호의 중금속 오염과 산화-환원 상태의 공간적 차이 (Heavy Metal Contamination and Spatial Differences in Redox Condition of the Artificial Shihwa lake, Korea)

  • 현상민;김은수;팽우현
    • 한국환경과학회지
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    • 제13권5호
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    • pp.479-488
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    • 2004
  • Five sediment cores from the tidal flat of artificial Lake Shihwa are analyzed in terms of sedimentology and geochemistry to evaluate the heavy metal contamination and redox condition of surficial sediment following the Shihwa seawall construction. The variability of concentrations of various elements depends on the depositional environment, and reflects the various redox conditions and sediment provenances. The amounts of Ti and Al and their ratio of Ti/ Al with respect to Li clearly indicate that there is an anthropogenic contribution to the surficial sediment. The high concentrations of heavy metals suggest an anthropogenic contribution at ST. 34 and ST. 22. Concentrations of most elements (Cr, Cu, Zn and Pb) are higher near the Shihwa-Banwol industrial complex than in the central part of Lake Shihwa. Concentrations of heavy metal in surficial sediment near the Shihwa-Banwol industrial complex are two to eight times higher than in the center of Lake Shihwa. Enrichment factors (EF), which are normalized by the unpolluted shale, suggests a significant metallic contamination near the Shihwa-Banwol industrial complex (SBIC). The redox condition is divided into two anoxic and mixed oxi $c_oxic zones based on the carbon:sulfur (C/S) ratios of organic matter and elemental relationships. Correlations among geochemical elements Mn, U and Mo are significantly different from site to site, and may therefore be an indicator of the spatial redox condition. Controlling factors for switching anoxic/oxic conditions are thought to be water depth and the differences in industrial effluent supply. The variations of the Cu/Mn ratio in the sediments confirms above mentioned spatial differences of a redox condition in part, and therefore shows a location-dependence redox condition in sediments at four other sites. The redox condition of the surficial sediment characteristics of the Shihwa Lake are controlled by its geographic location and water depth.th.

엘리베이터구동용 영구자석형 동기전동기의 속도 제어 (Speed Control of Permanent Magnet Synchronous Motor for Elevator)

  • 원충연;유재성;김진흥;전범수;황선모
    • 조명전기설비학회논문지
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    • 제18권5호
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    • pp.74-82
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    • 2004
  • 본 논문은 엘리베이터용 표면부착형 영구자석형 동기전동기의 속도제어를 기술하였다. 엘리베이터 전동기는 컴팩트하고 슬립형이 되어야 한다. 제안된 기법은 속도 및 토크제어를 위해 벡터제어 알고리즘을 사용하였으며, 속도제어기와 전류제어기에 windup 현상을 방지하기 위해 Anti-windup 기법을 적용하였다. 이 시스템은 컴팩트하고 저렴하게 설계하기 위하여 고속 32비트 DSP(TMS320C31-50), 고직접 논리소자 FPGA(EPF10K10TI144-3)로 수행되었다. 제안된 기법은 기계실 없는 엘리베이터용 3상 13.3[kW] 표면부착형 동기전동기로 시뮬레이션 및 실험을 통하여 결과를 확인하였다.

LED 기반 그린에너지 조명시스템을 위한 전력품질 측정 (Power Quality Measurement for LED-based Green Energy Lighting Systems)

  • 유형모;최진원;최상호
    • 전자공학회논문지
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    • 제50권2호
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    • pp.174-184
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    • 2013
  • LED 기반 그린에너지 조명 시스템의 성공적인 연구 개발과 원만한 설치 운영을 위해서는 펄스 파, 스파이크 파를 비롯한 비선형신호와 고조파, sag, swell 등을 포함한 불요신호에 대한 실시간 전력품질측정이 요구된다. 본 논문에서는 그린에너지 조명시스템 응용을 타깃으로 기존 저주파수 대 (60Hz~수KHz)는 물론 수십 KHz 이상의 고주파수 대에 발생하는 각종 전원 신호 분석이 가능한 저가형 전력품질측정 (power quality measurement: PQM) 방안을 제안하고, 이를 TI 320F28335 MCU(micro-controller unit) 기반 PQM 테스트 베드로 구현한다. 제안된 알고리즘은 CCS (Code Composer Studio) 3.3 환경에서 C언어로 작성하였으며, 임의 신호 발생기(NF-WF1974)로부터 발생된 모의 신호를 활용하여 구현된 알고리즘을 검증한다. 테스트 베드를 이용하여 LED SMPS로부터 발생되는 각종 비선형 전류 신호 측정, FFT를 이용한 고조파 신호의 분석이 가능할 뿐 아니라 이산 웨이블렛 변환을 이용한 sag, swell, interruption 등의 고품질 전력신호 측정도 가능하다.

A$_2$O$_3$세라믹과 Ni-Cr-Mo鋼과의 인서트 合金을 이용한 擴散接合에 關한 硏究 (A study on the diffusion bonding of the $Al_2$O$_3$ ceramics to metal)

  • 김영식;박훈종;김정일
    • Journal of Welding and Joining
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    • 제10권3호
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    • pp.63-72
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    • 1992
  • The joining methods of ceramics to metals which can be expected to obtain high temperature strength are mainly classified into the solid-state diffusion bonding method and the active brazing method. Between these two, the solid-state diffusion bonding method is given attentions as substituting method for active brazing method due to being capable of obtaining higher bonding strength at high temperature and accurate bonding. In this paper, the solid-state diffusion bonding of $Al_{2}$O$_{3}$ ceramics to Ni-Cr-Mo alloy steel (SNCM21) using insert metal was carried out. The insert metal employed in this study was experimentally home-made, Ag-Cu-Ti alloy. Influence of several bonding parameters of $Al_{2}$O$_{3}$SNCM21 joint was quantitatively evaluated by bonding strength test, and microstructural analyses at the interlayer were performed by SEM/EDX. From above experiments, the optimum bonding condition of the solid-state diffusion bonding of $Al_{2}$O$_{3}$/SNCM21 using Ag-Cu-Ti insert metal was determined. Futhermore, high temperature strength and thermal-shock properties of $Al_{2}$O$_{3}$/SNCM21 joint were also examined. The results obtained are as follows. 1. The maximum bonding strength was obtained at the temperature of 95% melting point of insert metal. 2. The high temperature strength of $Al_{2}$O$_{3}$/SNCM21 joint appeared to bemaximum value at test temperature 500.deg.C and the bonding strength with increasingtemperature showed parabolic curve. 3. The strength of thermal-shocked specimens was far deteriorated than those of as-bonded specimens. Especially, water-quenched specimen after heated up to 600.deg. C was directly fractured in quenching.

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알루미늄 주조/단조 공정에서 주조조직 제어에 관한 연구 (A Study on the Control of Cast Microstructure in the Aluminum Casting/Forging Process)

  • 배원병;강정윤;이영석;이성모;홍창호
    • 한국정밀공학회지
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    • 제16권9호
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    • pp.41-47
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    • 1999
  • The scale of dendritic structure of a cast preform plays a key role in determining the mechanical properties of cast/forged products. In this study, casting experiments are carried out to reduce dendrite arm spacing (DAS) to smaller than 20 ${\mu}$m by increasing cooling rate of the mold and then to spheriodize dendritic structures by addition of alloying elements such as Zr and Ti-B. From the casting experiments, appropriate casting conditions for producing the cast preform of a motorcycle connecting rod are obtained. To obtain fine microstructures of the cast preform, mold temperature must set to be low whilst cooling rate being high. When cooling rate is 10 $^{\circ}C$/s, the size of DAS is 17.4 ${\mu}$m. And the degree of spheriodization of a grain in the cast preform is described by aspect ratio, which is defined as the ratio of major and minor radii of an elliptical grain. When 0.5% Zr and 0.24 % Ti+B are added to the molten aluminum alloy, the best aspect-ratio 0.75 is obtained. After forging the cast preform of a motorcycle connecting rod, the microstructure and mechanical properties of the cast preform are compared with those of the cast/forged product. Cast/forged products are superior in microstructure and in mechanical properties such as ultimate strength, elongation, and hardness.

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12wt% Co 담지 촉매에서 합성오일 제조시 조촉매 효과 및 반응조건 영향 분석 (The Effect of Promotor and Reaction Condition for FT Oil Synthesis over 12wt% Co-based Catalyst)

  • 박연희;이지윤;정종태;이종열;조원준;백영순
    • 한국수소및신에너지학회논문집
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    • 제25권3호
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    • pp.247-254
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    • 2014
  • The synthesis of Fischer-Tropsch oil is the catalytic hydrogenation of CO to give a range of products, which can be used for the production of high-quality diesel fuel, gasoline and linear chemicals. Our cobalt based catalyst was prepared Co/alumina, silica and titania by the incipient wet impregnation of the nitrates of cobalt and promoter with supports. Cobalt catalysts was calcined at $350^{\circ}C$ before being loaded into the FT reactors. After the reduction of catalyst has been carried out under $450^{\circ}C$ for 24hrs, FT reaction of the catalyst has been carried out at GHSV of 4,000/hr under $200^{\circ}C$ and 20atm. From these test results, we have obtained the results as following ; in case of 12wt% Co-supported $Al_2O_3$, $SiO_2$ and $TiO_2$ catalysts, maximum activities of the catalysts were appeared at the promoters of Mn, Mo and Ce respectively. The activity of 12wt% $Co/Al_2O_3$ added a Mn promoter was about 3 times as high as that of 12wt% $Co/Al_2O_3$ catalyst without promoters. When it has been the experiment at the range of reaction temperature of $200{\sim}220^{\circ}C$ and GHSV of 1,546~5,000/hr, the results have shown generally increasing the activities with the increase of reaction temperature and GHSV.

녹차 추출물의 약리적 특성 및 분석 (A Study on the Pharmacetical Characteristics and Analysis of Green-tea Extract)

  • 성기천
    • 한국응용과학기술학회지
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    • 제23권2호
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    • pp.115-124
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    • 2006
  • From the result of pharmacetical characteristics and analysis of Green-tea extract, it could obtain some conclusions as follows. The extract experiment of Green-tea appeared about 10%-extraction ratio as semi-solid state, and after dried in freezing from Green-tea extract of semi-solid state, it obtained about 65% Green-tea extract as solid state. In the results on antimicrobial experiment of Green-tea extract, number of S-typhimurium and fungus in microbe decreased more and more according to the time passage. This phenomenon could show that Green-tea extract keeps antimicrobial effect. In the results on antioxidation experiment of Green-tea extract, DPPH scavenging activity of free radical showed that Green-tea extract appears more remarkable reduction ability than reference samples. This phenomenon means that antioxidation of Green-tea extract appears higher than Vitamin-C and BHA sample. In the results on intrument analysis, the fatty and aromatic components of aniline, acetaldehyde, acetic acid, trichloroethylene, caffeine etcs from Green-tea extract was detected with GC/MS analysis and inorganic components of Ca, Mg, Cu, Mo, Sb, Ti etcs from Green-tea extract was detected with ICP/OES analysis.

High alloyed new stainless steel shielding material for gamma and fast neutron radiation

  • Aygun, Bunyamin
    • Nuclear Engineering and Technology
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    • 제52권3호
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    • pp.647-653
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    • 2020
  • Stainless steel is used commonly in nuclear applications for shielding radiation, so in this study, three different types of new stainless steel samples were designed and developed. New stainless steel compound ratios were determined by using Monte Carlo Simulation program Geant 4 code. In the sample production, iron (Fe), nickel (Ni), chromium (Cr), silicium (Si), sulphur (S), carbon (C), molybdenum (Mo), manganese (Mn), wolfram (W), rhenium (Re), titanium (Ti) and vanadium (V), powder materials were used with powder metallurgy method. Total macroscopic cross sections, mean free path and transmission number were calculated for the fast neutron radiation shielding by using (Geant 4) code. In addition to neutron shielding, the gamma absorption parameters such as mass attenuation coefficients (MACs) and half value layer (HVL) were calculated using Win-XCOM software. Sulfuric acid abrasion and compressive strength tests were carried out and all samples showed good resistance to acid wear and pressure force. The neutron equivalent dose was measured using an average 4.5 MeV energy fast neutron source. Results were compared to 316LN type stainless steel, which commonly used in shielding radiation. New stainless steel samples were found to absorb neutron better than 316LN stainless steel at both low and high temperatures.

회분식 전해조에서 PCB 식각폐수의 재생 및 구리의 회수 (Regeneration of PCB Etchants and Copper Recovery in a Batch-type Electrolytic Cell)

  • 남상철;남종우;탁용석;오승모
    • 공업화학
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    • 제8권2호
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    • pp.161-171
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    • 1997
  • 인쇄회로기판의 식각폐수를 전기화학적 방법을 이용하여 양극에서 이를 재생하고, 음극에서 구리를 석출하기 위한 실험을 행하였다. 양극에서의 Cu(I)의 산화에 따른 Cu(I)/Cu(II) 변화는 Pt와 Ag/AgCl/4M KCl 전극사이의 전위차를 이용하여 측정하였으며, 반응의 진행에 따른 양극에서의 염소기체 발생은 용액내에 Cu(I)의 농도를 일정치 이상으로 유지시키고, 비다공성 흑연전극을 이용하여 억제할 수 있었다. 그리고, 음극에서의 구리석출은 전류밀도 $360mA/cm^2$, 구리이온농도 12g/l 일때 가장 효율적이며 석출된 구리는 dendrite구조임을 알 수 있었다. 또한 석출효율과 회수방법을 고려할 때 음극으로서 Ti전극을 사용할 경우 가장 우수한 효율을 얻을 수 있었다. 전해온도가 증가함에 따라서 전류효율은 낮아졌으며, 전력효율은 $50^{\circ}C$에서 최대값을 나타내었다.

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도재소부용 Ni-Cr 보철합금 개발에 관한 연구 (A Study on the Development of Porcelain Bonded Ni-Cr Dental Alloy)

  • 이규환;신명철;최부병
    • 대한의용생체공학회:의공학회지
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    • 제6권1호
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    • pp.37-46
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    • 1985
  • Development of a dental Ni-Cr alloy system for porcelain veneering crown and bridge was studied in this research. The principles of alloy design were a) It should not contain toxic beryllium. b) It should have low melting Point. c) It should be easily ground and polished. d) It should possess an adequate strength to resist the deformational force In the mouth. e) It should be bondable Ivith porcelain by chemically. After investigating the effect of minor elements such as boron and rare earth metals on the mechanical properties of the Ni-Cr alloy system, the compromised ideal composition for dental use was determined. The composition was l9.6%, Cr, 5.6% Mo, 3.4% Si, 1, 0% Fe, 0.01% Ti, 0.5-1.0% B, 0.2-0.6% misch metal, balance Ni. To compare the performance of experimental alloy with commercially available alloys, the properties such as strength, melting point, and bond strength were measured. The results Ivere as follows: a) Boron increases the strength of the alloy but reduces the elongation. b) Misch metal increases the strength when the boron content is low, but does not increase the strength when boron content is high. And it reduces the elongation drastically, c) Mechanical strength of the experimental alloy was not superior to commercially available Be containing alloy, but handling performance such as castability, ease of granting and polishing, and cuttability were superior to the Be containing alloy.

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