• 한국재료학회지
• /
• 제14권6호
• /
• pp.394-398
• /
• 2004

A Ti47Al1.7W-3.7Zr alloy was oxidized between $900^{\circ}C$ and $1050^{\circ}C$, and the oxide scales formed were studied. The oxide scales consisted primarily of an outer$TiO_2$ layer, an intermediate $Al_2$$O_3$-rich layer, and an inner mixed ($TiO _2$ + $Al_2$$O_3$) layer. Besides $TiO_2$ and $Al_2$$O_3$, oxidation led to the formation of some $Ti_2$AlN and TiN. Both W and Zr were preferentially segregated below the intermediate $Al_2$$O_3$-rich layer. Tungsten in the oxide scale was present as $WO_3$ and ${Ti}_{x}$$W_{1-x}$, whereas zirconium as monoclic-$ZrO_2$ and tetragonal-$ZrO_2$.

• 한국표면공학회:학술대회논문집
• /
• 한국표면공학회 2017년도 춘계학술대회 논문집
• /
• pp.156-156
• /
• 2017

In this work, analysis of biocompatible TiO2 oxide multilayer by the XPS depth profiling was researched. the manufacture of the TiO2 barrier-type multilayer was accurately performed in a mixed electrolyte containing HAp, Pd, and Ag nanoparticles. The temperature of the solution was kept at approximatively $32^{\circ}C$ and was regularly rotated by a magnetic stirring rod in order to increase the ionic diffusion rate. The manufactured specimens were carefully analyzed by XPS depth profile to investigate the result of chemical bonding behaviors. From the analysis of chemical states of the TiO2 oxide multilayer using XPS, the peaks are showed with the typical signal of Ti oxide at 459.1 eV and 464.8 eV, due to Ti 2p(3/2) and Ti 2p(1/2), respectively. The Pd-3d peak was split into Pd-3d(5/2) and Pd-3d(3/2)peaks, and shows two bands at 334.7 and 339.9 eV for Pd-3d3 and Pd-3d5, respectively. Also, the peaks of Ag-3d have been investigated. The chemical states consisted of the O-1s, P-2p, and Ti-2p were identified in the forms of PO42- and PO43-. Based on the results of the chemical states, the chemical elements into the TiO2 oxide multilayer were also inferred to be penetrated from the electrolyte during anodic process.The structure characterization of the modified surface were performed by using FE-SEM, and from the result of biological evaluation in simulated body fluid(SBF), the biocompatibility of TiO2 oxide multilayer was effective for bioactive property.

• 한국수소및신에너지학회논문집
• /
• 제5권1호
• /
• pp.41-49
• /
• 1994

Ti-Bi alloy was prepared by arc melting of appropriate amounts of titanium and bismuth powder. The photocurrent($I_{ph}$) of Ti-Bi oxide electrode was increased with the increase of Bi content, up to 10wt%. The maximum $I_{ph}$ showed $7.6mA/cm^2$ at V=0.5V vs. SCE. The band gap energy of Ti-Bi oxide electrode was observed to 3.0~2.87eV. Surface barrier($V_s$) of Ti-10Bi oxide electrode showed maximum value(1.08V) but didn't exceed 1.23V, then it was impossible to run $H_2$ generation without any other energy sources other than the light. Ti-Bi oxide electrode was found to be quite stable under alkaline solution and showed no signs of photodecomposition.

• 한국분말재료학회지
• /
• 제25권4호
• /
• pp.327-330
• /
• 2018

This study is conducted as a preliminary research to verify the feasibility of Ti-based Oxide dispersion strengthened (ODS) alloy. Pure-Ti powder is mixed with $Y_2O_3$ powder and subsequently, mechanically alloyed at $-150^{\circ}C$. The Ti-based ODS powder is hot-isostatically pressed and subsequently hot-rolled for recrystallization. The microstructure consists of elongated grains and Y excess fine particles. The oxide particle size is larger than that of the typical Fe-based ODS steel. Tensile test shows that the tensile ductility is approximately 25%, while the strength is significantly higher than that of pure Ti. The high-temperature hardness of the Ti-ODS alloy is also significantly higher than that of pure Ti at all temperatures, while being lower than that of Ti-6Al-4V. The dimple structure is well developed, and no evidence of cleavage fracture surface is observed in the fracture surface of the tensile specimen.

• Bulletin of the Korean Chemical Society
• /
• 제35권9호
• /
• pp.2660-2664
• /
• 2014

A simple method of depositing titanium dioxide ($TiO_2$) nanoparticles onto graphene oxide (GO) as a catalytic support was devised for photocatalytic degradation of methylene blue (MB). Thiol groups were utilized as linkers to secure the $TiO_2$ nanoparticles. The resultant GO-supported $TiO_2$ (GO-$TiO_2$) sample was characterized by transmission electron microscopy (TEM), near-edge X-ray absorption fine structure (NEXAFS), and X-ray photoelectron spectroscopy (XPS) measurements, revealing that the anatase $TiO_2$ nanoparticles had effectively anchored to the GO surface. In the photodegradation of MB, GO-$TiO_2$ exhibited remarkably enhanced photocatalytic efficiency compared with thiolated GO and pure $TiO_2$ nanoparticles. Moreover, after five-cycle photodegradation experiment, no obvious deactivation was observed. The overall results showed that thiolated GO provides a good support substrate and, thereby, enhances the photodegradation effectiveness of the composite photocatalyst.

• 한국표면공학회지
• /
• 제35권6호
• /
• pp.383-390
• /
• 2002

To investigate behaviors of Ti and O elements and microstructures of anodic titanium oxide films, the films were prepared by anodizing pure titanium in $H_2$S $O_4$, $H_3$P $O_4$, and $H_2O$$_2$ mixed solution at 180V. The microstructures and chemical states of the elements were analyzed using SEM, X-ray mapping, AFM, XRD, XPS (depth profile). The films formed on a titanium substrate showed porous layers which were composed of pore and wall, And with increasing anodizing time a hexagonal shape of cell structures were dominant and solace roughness increased. From the XRD result the structure of the Ti $O_2$ layer was anatase type of crystal on the whole. In the XPS spectra it was found that Ti and O were chemically binded in forms of Ti $O_2$, TiOH, $Ti_2$ $O_3$ at Ti 2p, and Ti $O_2$, $Ti_2$ $O_3$, $P_2$ $O_{5}$, S $O_4^{2-}$ at O ls respectively. Concentration of Ti $O_2$ decreased as the depth increased from the surface of the oxide film towards the substrate, but to the contrary concentrations of TiOH and $Ti_2$ $O_3$ increased.d.

• 대한전자공학회:학술대회논문집
• /
• 대한전자공학회 2000년도 추계종합학술대회 논문집(2)
• /
• pp.41-44
• /
• 2000

Ultra large scale integrated circuit(ULSI) & complementary metal oxide semiconductor(CMOS) circuits require gate electrode materials such as meta] silicides, titanium-silicide for gate oxides. Many previous authors have researched the improvements sub-micron gate oxide quality. However, little has been done on the electrical quality and reliability of ultra thin gates. In this research, we recommend novel shallow trench isolation structure and two step TiSi$_{2}$ formation for sub 0.1${\mu}{\textrm}{m}$ gate oxide.

• 한국자기학회:학술대회 개요집
• /
• 한국자기학회 2004년도 하계학술연구발표회 논문개요집
• /
• pp.150-151
• /
• 2004

• 한국세라믹학회지
• /
• 제35권1호
• /
• pp.55-65
• /
• 1998

Ag-36.8a%Cu-7.4at%Ti 조성의 브레이징 합금을 Si3N4 기판위에 브레이징한 후 브레이징 합금의 산화거동을 대기중 400, 500, 600$^{\circ}C$에서 조사하였다. 브레이징 합금의 구성원소인 Ag는 산화되지 않고 Cu와 Ti가 산화되며, 산화거동은 포물선적 산화법칙을 따랐다. 브레이징 합금의 산화에 따른 활성화에너지는 80kj/ mol 으로서 소량 첨가된 활성원소인 Ti에 의하여 순수한 Cu의 산화시 활성화에너지보다 감소하였다. 산화 초기에 생성되는 외부산화물은 Cu이온의 외부확산에 의해 성장이 지배되는 Cu산화물로 구성되어 있었다. 산화기간이 경과함에 따라 외부산화물층 아래에서 Cu의 농도는 감소되고 Ag의 농도는 증가하는 농도구배가 발생하여, 브레이징 합금의 산화물은 Cu산화물층(CuO)/Ag잉여층/Cu산화물층(Cu2O)/Ag잉여층의 다층구조를 갖았다. 또한, 분위기중의 산소는 Cu산화물 및 Ag잉여층을 통해 브레이징 합금 내부로 확산되어 브레이징 합금내의 Ti와 반응하여 내부산화물 TiO2를 생성하였다.

• 한국재료학회지
• /
• 제10권4호
• /
• pp.282-289
• /
• 2000

전자싸이클로트론공명-플라즈마 화학기상증착법으로 $PbTiO_3$박막을 증착하였다. $RuO_2$ 기판과 Pt 기판 위에 금속유기화합물 원료기체 유량 및 증착온도에 따라서 $PbTiO_3$박막의 증착특성을 연구하였다. $RuO_2$ 기판 위에서 Pt 기판에 비하여 Pb-oxide 분자의 잔류시간이 상대적으로 크고, 페로브스카이트 핵생성 밀도는 상대적으로 작으며, 단일한 페로브스카이트 상의 $PbTiO_3$ 박막을 얻을 수 있는 공정범위가 Pt 기판보다 좁았다. $PbTiO_3$ 박막 증착 전 Ti-oxide 씨앗층을 도입함으로써 $RuO_2$ 기판에서도 페로브스카이트 핵생성 밀도를 증가시켜 단일한 페로브스카이트 박막을 얻을 수 있는 공정범위가 확장되었다. $PbTiO_3$에서 Ti 성분을 Zr으로 일부 대체시킨 $Pb(Zr,Ti)O_3\;(PZT)$ 박막의 경우에도 Ti-oxide 씨앗층을 도입함으로써 넓은 공정범위에서 단일한 페로브스카이트 PZT 박막을 $RuO_2$기판 위에서도 제조할 수 있었다.