• 소성∙가공
• /
• 제15권8호
• /
• pp.581-585
• /
• 2006

Effects of V on both the formation of Ti-Nb-V carbonitrides and mechanical properties of Ti-Nb bearing low carbon HSLA steels were investigated. Hot rolling process was simulated by using Gleeble 3500 system with the steels containing three different levels of V ($0{\sim}0.1wt.%$). Vanadium precipitated as Ti-Nb-V carbonitrides at austenite region but it did not precipitate as VC during austenite to acicular ferrite or bainitic ferrite phase transformation. As V content increased, the amount of Nb precipitates was decreased but the average size of Ti-Nb-V carbonitrides was increased due to larger diffusivity of V than that of Nb. Coarsened Ti-Nb-V carbonitrides could act as heterogeneous nucleation site during ${\gamma}{\rightarrow}{\alpha}$ phase transformation, thus, acicular ferrite transformation was promoted as V content increased, resulting in increase of upper shelf energy.

• 열처리공학회지
• /
• 제21권6호
• /
• pp.287-292
• /
• 2008

Dissolution behavior of complex carbonitrides in a Nb-Ti-V microalloyed steel was quantitatively examined by electrical resistivity, transmission electron microscopy (TEM), and optical microscopy. The electrical resistivity increased with solution treatment temperature up to $1250^{\circ}C$ for a holding time of 15 min. But, an increasing rate of electrical resistivity with temperature was obviously decreased above $1150^{\circ}C$. As the solution treatment temperature increases, irregular shaped Nb-rich carbonitrides disappear and cuboidal Ti-rich carbonitrides are observed. Abnormal grain growth occurs above $1250^{\circ}C$ for a holding time of 15 min. The optimal solution treatment temperature of a Nb-Ti-V microalloyed steel was determined as $1200^{\circ}C$ for a holding time of 15 min.

• 한국재료학회지
• /
• 제27권4호
• /
• pp.184-191
• /
• 2017

This present study deals with the effect of micro-alloying elements and transformation temperature on the correlation of microstructure and tensile properties of low-carbon steels with ferrite-pearlite microstructure. Six kinds of low-carbon steel specimens were fabricated by adding micro-alloying elements of Nb, Ti and V, and by varying isothermal transformation temperature. Ferrite grain size of the specimens containing mirco-alloying elements was smaller than that of the Base specimens because of pinning effect by the precipitates of carbonitrides at austenite grain boundaries. The pearlite interlamellar spacing and cementite thickness decreased with decreasing transformation temperature, while the pearlite volume fraction was hardly affected by micro-alloying elements and transformation temperature. The room-temperature tensile test results showed that the yield strength increased mostly with decreasing ferrite grain size and elongation was slightly improved as the ferrite grain size and pearlite interlamellar spacing decreased. All the specimens exhibited a discontinuous yielding behavior and the yield point elongation of the Nb4 and TiNbV specimens containing micro-alloying elements was larger than that of the Base specimens, presumably due to repetitive pinning and release of dislocation by the fine precipitates of carbonitrides.

• 대한용접접합학회:학술대회논문집
• /
• 대한용접접합학회 2004년도 추계학술발표대회 개요집
• /
• pp.141-143
• /
• 2004

The experimental simulation welds using 3kinds of 70ksi titania based flux-cored consumables were performed on 24 inches 24.6-thick API 5L Gr. B pipe with relatively high current, over 300A and four different Post Weld Heat Treaonent(PWHT) conditions at $625^{circ}C$ were applied to each consumable test coupon. It is well known that, in common welding processes such as Submerged Arc Welding(SAW) or Flux Cored A.c Welding(FCAW), the cooling rates in as-deposited weld bead are normally so ,apid that actual precipitation of microalloy carbonitrides, Nb(C,N) or V(C,N) is not likely to occur in the as-welded weld metal, however, during stress relief or PWHT the operation of precipitation can reduce the impact properties of the weld metal. As results of mechanical testing, it is concluded that PWHT at $625^{circ}C$ is detrimental to weld metal impact toughness of Ti-B type flux- cored (FC) welding consumables regardless of the amount of Nb and V, but two optima were exhibited, one at 800ppm Ti, 75ppm 5 and another 360ppm Ti, 54ppm 5.