• Journal of Hydrogen and New Energy
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• v.2 no.1
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• pp.39-46
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• 1990

In order to improve the power of hydride heat pump, prototype heat pump was constructed using $Zr_{0.95}Ti_{0.05}Cr_{0.9}Fe_{1.1}$-$Zr_{0.9}Ti_{0.1}Cr_{0.6}Fe_{1.4}$ which had very good hydrogenation properties. The power changed with operating parameter such as cycle time, air flow rate, and temperature of hot air was investigated. The power shows maximum value with cycle time. The power increased with air flow rate and temperature of hot air. The power of the heat pump was $65-72 Kcal/Kg-alloy{\cdot}h$ under optimum operating condition, which was superior to that the system using $LaNi_{0.9}Al_{0.3}-MmNi_{4.15}Al_{0.66}Fe_{0.2}$ alloy pairs.

• Korean Journal of Materials Research
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• v.5 no.1
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• pp.112-122
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• 1995

Metal hydride alloys of TiFe based system have been produced by mechanical alloying(MA) method and their electrochemical characteristics have been evaluated for application for Ni/MH battery electrode. These alloys became amorphous after 36hrs ball milling and easily activated electrochemically. All MA amorphous alloys reached at the first charge/discharge cycle the maximum capacity which was 2-3 times higher than the crystalline state. But their cyclic lives were much inferior to the crystalline state. Alloying elements such as Ni, Co, Cr, Mo substituting Fe greatly improved the capacity and 180 mAh/g capacity was obtained in an alloy of TiFe_{0.6}Ni_{0.1}Co_{0.1}Cr_{0.1}Mo_{0.1}$.

• Proceedings of the Materials Research Society of Korea Conference
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• 2012.05a
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• pp.105.2-105.2
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• 2012

타이타늄합금기지 복합재료(Ti-MMC)는 일반 철합금 혹은 철합금기지 복합재료에 비하여 내식성과 내마모성, 내열성, 강도 등이 우수하여, 고성능 가솔린자동차 부품 외에도 하이브리드 자동차 엔진 부품, 고온 압축기 및 터빈 휠 등 고온에서 사용되는 고속 회전품으로 응용가능성이 매우 크다. 그러나 아직까지도 타이타늄 원소재 가격이 높고 제조 공정의 어려움으로 인하여 실용화에 장애가 되고 있다. 이를 극복하기 위하여 최근에는 타이타늄기지 복합재료의 제조단가를 낮추는 동시에 기계적 성질을 개선하기 위한 다양한 연구들이 진행되고 있다. 본 연구에서는 고가의 HDH(Hydride-Dehydride) 공정에 의하여 제조된 타이타늄 분말 대신에 저가의 titanium hydride를 사용하여 반응생성 공정으로 제조단가가 낮은 복합재료를 제조하고자 하였다. 당 연구실에서 저비용합금으로 개발된 Ti-Al-Fe 계 타이타늄합금을 기지로 한 TiB 강화 복합재료를 제조하기 위하여 반응분말로 $TiB_2$를 사용하여 제조하였다. 강화상 분율에 따른 밀도변화와 제조 공정변수에 따른 소결특성과 기계적 특성 변화에 대하여 조사하였다.

• Journal of Powder Materials
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• v.12 no.3
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• pp.174-178
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• 2005

This paper deals with the fabrication of titanium carbide using fine titanium hydride. The ratio of $TiH_2$ and C (Activated carbon) was 1:1 (mol) and milled in a planetary ball mill at a ball-to-powder weight ratio of 20:1. Thereafter, TGA was performed at $1400^{\circ}C$ to observe change of weight with milling time. Titanium carbide was obtained by using tempering the milled powders at $1100-1500^{\circ}C$. The microstructures of titanium carbide as well as the change of the lattice parameters and particle size have been studied by X-ray diffraction (XRD) and scanning electron microscopy (SEM).

• Applied Chemistry for Engineering
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• v.5 no.2
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• pp.263-273
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• 1994

Titanium powder prepared by dehydrogenating the titanium hydride which is synthesized by reacting Ti-sponge (99.67%) with hydrogen using the self-propagating high-temperature synthesis method. In the synthesis of titanium hydride, the particle size of the product was found dependent on the amount of hydrogen incorporated into the titanium such that the particle size of titanium hydride decreased with increasing hydrogen pressure and after-burn time. In the dehydrogenation process, as the dehydrogenation time increase, the particle size of titanium powder increased due to partial melting and sintering of titanium particles.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.7 no.2
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• pp.284-291
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• 1997

The electrode characteristics of two kinds of metal hydride electrodes using V-Ti (V-rich) based alloy were studied, in which one electrode was prepared by sintering the mixture of V-Ti alloy and Ni powders by a rapid thermal annealing technique and the other one was prepared using V-Ti-Ni ternary alloy, The discharge capacities of all electrodes during the charge-discharge cycling were completely deteriorated within 10 cycles. It appeared that the deterioration of the electrodes was caused by the dissolution of V in the near-surface region into the electrolyte and the formation of $TiO_2$ layer on the alloy particle surface. This degradation mechanism was supported by the facts that V is main hydride forming element and $TiO_2$ has very low electrical conductivity and hydrogen diffusivity.

• Journal of Powder Materials
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• v.23 no.4
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• pp.282-286
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• 2016

A sintered body of $TiB_2$-reinforced iron matrix composite ($Fe-TiB_2$) is fabricated by pressureless-sintering of a mixture of titanium hydride ($TiH_2$) and iron boride (FeB) powders. The powder mixture is prepared in a planetary ball-mill at 700 rpm for 3 h and then pressurelessly sintered at 1300, 1350 and $1400^{\circ}C$ for 0-2 h. The optimal sintering temperature for high densities (above 95% relative density) is between 1350 and $1400^{\circ}C$, where the holding time can be varied from 0.25 to 2 h. A maximum relative density of 96.0% is obtained from the ($FeB+TiH_2$) powder compacts sintered at $1400^{\circ}C$ for 2 h. Sintered compacts have two main phases of Fe and $TiB_2$ along with traces of TiB, which seems to be formed through the reaction of TiB2 formed at lower temperatures during the heating stage with the excess Ti that is intentionally added to complete the reaction for $TiB_2$ formation. Nearly fully densified sintered compacts show a homogeneous microstructure composed of fine $TiB_2$ particulates with submicron sizes and an Fe-matrix. A maximum hardness of 71.2 HRC is obtained from the specimen sintered at $1400^{\circ}C$ for 0.5 h, which is nearly equivalent to the HRC of conventional WC-Co hardmetals containing 20 wt% Co.

• Proceedings of the Korean Powder Metallurgy Institute Conference
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• 2005.11a
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• pp.58-58
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• 2005

• Journal of the Korean Ceramic Society
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• v.31 no.6
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• pp.637-642
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• 1994

Using SHS(Self-propagating High-temperature Synthesis) method, the optimum synthetic condition of titanium carbonitride was established by controlling the parameters such as relative density of mixture (Ti+C), nitrogen pressure, additive amounts of titanium hydride(TiH1.924) and protecting heat loss. Under 1 atm nitrogen pressure, nitridation ratio with changing relative density of the sample compacts has a maximum (87.2%) at about 55%, and in the case of enveloping the pellet with a quartz tube, the highest nitridation ratio of 90% was obtained at about 68%. At relative density of 55%, nitridation ratio with the nitrogen pressure has a miximum (87.3%) at 7 atm. As the amounts of additive titanium hydride increased, nitridation ratio decreased at below 7 atm nitrogen pressure and, increased at above this pressure until percent of addition percent reached 15 wt% and decreased abruptly upon futher increases in titanium hydride. In the synthesis of TiCxNy by combustion reaction, heat transfer from combustion zone to preheating zone and nitrogen gas penetration into the compact were found to be important factors affecting the TiCxNy formation. It was difficult to obtain high nitridation ratio when the conbustion temperature was either too high or too low, and it seems that the retention of high temperature after a combustion wave sweeped through the reactant mixture pellet is critical to obtain a satisfactory nitridation ratio.

• Journal of the Korean Society of Propulsion Engineers
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• v.25 no.3
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• pp.26-41
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• 2021

Titanium hydride potassium perchlorate (THPP) has played an important role as initiators of the propulsion system. However, the 'aging' may cause performance degradation and even give rise to a failure in the total system. In this study, various hygrothermal aging conditions were considered and the aging effects on thermodynamic and ignition characteristics of THPP are provided via thermal analysis and ignition measurements. Also, physical-chemical changes were identified by morphological analysis. In conclusion, thermal aging led to E_α decrease-high reactivity due to oxidizer decomposition whereas hygrothermal aging gave rise to an opposite tendency by fuel oxidation.