• Title/Summary/Keyword: Ti(CN) ceramic

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Preparation of Fe4[Fe(CN)6]3 Coated on Mica or TiO2/Mica for Infrared Reflective Blue Pigments and Isolation-heat Properties of These Paints (Fe4[Fe(CN)6]3가 코팅된 Mica 또는 TiO2/Mica 적외선 반사용 청색안료 제조 및 이 도료의 차열 특성 평가)

  • Jung, Ha-Young;Kim, Dae Sung;Lee, Hyun-Jin;Lee, Seung-Ho;Lim, Hyung Mi;Choi, Byung-Ki;Kang, Kwang-Jung;Choi, Jin-Sub
    • Korean Journal of Materials Research
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    • v.23 no.12
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    • pp.672-679
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    • 2013
  • $Fe_4[Fe(CN)_6]_3$ coated on a mica or $TiO_2$/mica surface as infrared reflective blue pigment was prepared by a hydrothermal method. $Fe_4[Fe(CN)_6]_3$, used as coloring agent, was uniformly coated on mica or $TiO_2$/mica under the optimized condition of a 1.2 : 1 weight ratio between iron(III) chloride hexahydrate and potassium ferrocyanidetrihydrate at the initial pH level of 4.5 at $70^{\circ}C$. The infrared (IR)-reflective pigments were characterized by SEM, Zeta-potenial, FT-IR, and UV-VIS NIR spectrophotometry. Especially the CIE color coordinate and total solar reflectance(TSR) properties of the pigments were investigated in relation to variation of the coating and coated substrate thicknesses. Isolation-heat paint was prepared with 20 wt% blue pigments fully dispersed in acryl-urethane resin and several additives to coat the film uniformly. The films were also measured with CIE color coordinate, TSR, and the surface temperature was recorded by an isolation-heat measuring system. The pigments and films of $Fe_4[Fe(CN)_6]_3$ coated on mica and $TiO_2$/mica showed high TSR values compared with the TSR value of $Fe_4[Fe(CN)_6]_3$ itself. According to the increase of TSR value, the property of isolation-heat is effective. To realize the optimal blue color, we applied the the pigment to $TiO_2$ coated mica(TM(b)) which has blueish interference color. The pigment of $Fe_4[Fe(CN)_6]_3$ coated on TM(b) shows a strong blue color compared with that of $Fe_4[Fe(CN)_6]_3$ coated on $TiO_2$/Mmca(TM(w)), which has a whitish interference color.

A Study on the Friction and Wear Characteristics of TiC, TiN and Ti(CN) with PECVD Process (PECVD 공정에 의한 TiC, TiN 및 Ti(CN)의 마찰 마모 특성 연구)

  • Rhee Bong Goo;Jeon Ghan Yeol;Kim Jung Ki;Kim Dong Hyun;Oh Seong Mo
    • Transactions of the Korean Society of Machine Tool Engineers
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    • v.14 no.2
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    • pp.1-7
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    • 2005
  • In order to determine the wear Properties of PECVD ceramic coatings, wear process was evaluated using the coated pin of Falex Tribosystem. Coating materials deposited wear the TiC, TiN and Ti(CN). An experimental process was established to determine the tribological characteristics of friction and wear behavior under the variation of applied load, temperature and sliding distance by the Falex test machine. The experimental results indicate that TiN coating compared with TiC coating on e materials have e excellent friction and wear characteristics. However TiC coating compared i친 TiN coatings have a low friction coefficient with steel and good thermal stability, and Ti(CN) has the excellent anti-wear properly as well as the superiority of extreme pressure property. Compound coating compared wi simple coatings show improved tribological characteristics.

Mechanical Properties and Cutting Performance of Ti(CN) Based Carbonitride Ceramics (Ti(CN)기 탄화물질 세라믹스의 기계적 특성과 절삭성능)

  • Park, Dong-Su;Lee, Yang-Du;Jeong, Tae-Ju;Gang, Sin-Hu
    • 연구논문집
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    • s.28
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    • pp.193-207
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    • 1998
  • Fully dense THCN) based carbonitride ceramics were fabricated by pressureless sintering. During sintering, solid solutions were formed from the ceramic ingredients. The ceramics exhibited microvickers hardness of 1560-2050kgf/mm2, fracture toughness of 3.0-5.4 MPa $m^(1/2)$, and three point flexural strength of 645-1072 MPa. Some of the ceramics were shaped in a cutting tool, and the cutting performance was evaluated. In case of cutting SCM440 alloy steel, the ceramics showed better performance than the commercially available alumina-titanium carbide ceramic cutting tool. Considering the excellent productivity of pressureless sintering compared with other densification methods and their cutting performance, this new class of ceramics are very promising for wear resistant applications.

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Dissolution and Reprecipitation Behavior of TiC-TiN-Ni Cermets During Liquid-Phase Sintering

  • Yoon, Choul-Soo;Shinhoo Kang;Kim, Doh-Yeon
    • The Korean Journal of Ceramics
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    • v.3 no.2
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    • pp.124-128
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    • 1997
  • An attempt was made to understand the dissolution and reprecipitation behavior of the constituent phases such as TiC, TiN, and Ti(CN) in TiC-TiN-Ni system. During the liquid-phase sintering the TiC phase was found to dissolve preferentially in Ni binder. The solid-solution phase, Ti(CN), formed around the TiN phase, resulting in a core/rim structure. This result was reproduced when large TiC particles were used with fine TiN particles. The path for the microstructural change in TiC-TiN-Ni system was largely controlled by the difference in the interfacial energy of each phase with the liquid binder phase. The results were discussed with thermodynamic principles.

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Tool Geometry for Improving Tool-Life in Turning of STS 304 (STS 304의 선삭에서 공구수명 향상을 위한 공구형상)

  • 이재우
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2003.06a
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    • pp.581-584
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    • 2003
  • The austenitic STS 304 stainless steel was turned to clarify the effects of tool geometry on the tool wear. The wear of TiN-TiCN-TiC-TiAlN coated tungsten carbide tool was the smallest, exhibiting larger wear in the order of Si-Al-O-N ceramic, TiN coated tungsten carbide, TiN-TiCN-TiN coated tungsten carbide, TiC-TiN cermet and M20 tungsten carbide tools at the same cutting conditions. The S-type tool of M20 with large approach angle showed the longest tool life of all tools used in this tests due to preventing the groove wear of the side cutting edge. The wear of the S-type tool with the rake angle of 15$^{\circ}$became smaller than with that of -5$^{\circ}$, but the tool with the nose radius of 0.8mm did not perform much better with increasing the rake angle.

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Tool-Wear Characteristics in Turning of STS 304 (STS 304 선삭시의 공구마멸 특성)

  • 이재우
    • Journal of the Korean Society for Precision Engineering
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    • v.20 no.10
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    • pp.56-64
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    • 2003
  • The effect of tool geometry on the tool wear in turning the austenitic stainless steel, STS 304 was investigated. The wear of TiN-TiCN-TiC-TiAlN coated tungsten carbide tool was the smallest, showing larger wear in the order of Si-Al-O-N ceramic, TiN coated tungsten carbide, TiN- TiCN- TiN coated tungsten carbide, TiC-TiN cermet and M20 tungsten carbide tools at the same cutting conditions. The S-type tool of M20 with the larger side cutting edge angle showed the smallest tool wear in all tests due to preventing the groove wear of the side cutting edge. The wear of the S-type tool with the rake angle of $15^{\circ}$ became smaller than with that of $-5^{\circ}$, but the tool with the nose radius of 0.8mm did not perform much better with increasing the rake angle.

Study of TiCN Aditions to an 2xxx Series Aluminium Alloy

  • Ruiz-Navas, E.M.;Delgado, Tienda M.L.;Benito, Gonzalez S.;Gordo, E.
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.1037-1038
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    • 2006
  • The increasing demand of PM parts for automobile and aerospace applications has caused a strong development of the aluminium based metal matrix composites (MMCs).Aluminium alloys are one of most widely used materials as matrix in MMCs, both in research and development as well as in industrial applications. In the present work, the influence of the ceramic reinforcement addition to a 2xxx series aluminium alloy is studied. Several percentages of TiCN have been added to the Al-Cu alloy using PM techniques, in order to analyze its influence on the liquid phase sintering process and on the final properties of the material.

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