• 한국산학기술학회논문지
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• 제11권9호
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• pp.3277-3283
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• 2010

본 연구에서는 콜라겐의 처방이 퍼머넌트웨이브 시술시 미치는 영향을 알아보기 위하여 정상모에 콜라겐을 농도별 처방한 퍼머넌트웨이브제로 퍼머넌트웨이브를 시술한 후 모발에 컬의 형성력, 굵기 관찰, 인장 강도, 메틸렌블루 흡광도, 수분 감소량 등의 변화를 측정하여 비교분석하였다. 결론적으로 퍼머넌트웨이브제의 콜라겐 처방 여부에 따라 모발의 굵기, 모발의 인장강도, 모발의 수분 감소량, 흡광도가 처방하지 않은 환원제에 대비하여 감소하였으며, 처방된 콜라겐의 농도가 증가할수록 모발의 손상도가 줄어드는 결과를 보였다. 그러나 콜라겐의 농도의 크기가 커질수록 퍼머넌트웨이브 시술시 컬의 형성력이 떨어지는 결과가 나타났다. 그러므로 퍼머넌트웨이브 시술시 모발의 손상도를 줄이기 위한 콜라겐 처방 농도는 2%가 적당하였다.

• Bulletin of the Korean Chemical Society
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• 제32권7호
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• pp.2260-2266
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• 2011

4-Chlorotetrazolo[1,5-a]quinoxaline (III) was synthesized by azide (2+3) cycloaddition of 2,3-dichloroquinoxaline (II). Compound (III) on further refluxing with hydrazine hydrate furnished 4-hydrazinotetrazolo[1,5-a]quinoxaline (IV). Further refluxing of (IV) with different aromatic aldehydes in methanol yielded corresponding Schiff's bases V(a-j). Various 4-aminotetrazolo[1,5-a]quinoxaline based azetidinones VII(a-j) were synthesized by stirring the compounds V(a-j), at low temperature, with equimolar mixture of chloroacetylchloride & triethylamine in dry benzene, while 4-aminotetrazolo[1,5-a]quinoxaline based thiazolidinones VIII(a-j) were synthesized by refluxing Schiff's bases V(a-j) with thioglycolic acid in oil-bath. The structures of all the compounds were confirmed on the basis of $^1H$-NMR & FT-IR spectral data. All the newly synthesized compounds were screened for in-vitro antimicrobial activity against E. coli, S. aureus, K. pneumoniae & P. aeruginosa & antifungal activity against C. albicans. Few of them have exhibited the promising activity.

• 한국분말재료학회지
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• 제27권3호
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• pp.233-240
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• 2020

Nano-sized ZnSe particles are successfully synthesized in an aqueous solution at room temperature using sodium borohydride (NaBH₄) and thioglycolic acid (TGA) as the reducing agent and stabilizer, respectively. The effects of the mass ratio of the reducing agent to Se, stabilizer concentration, and stirring time on the synthesis of the ZnSe nanoparticles are evaluated. The light absorption/emission properties of the synthesized nanoparticles are characterized using ultraviolet-visible (UV-vis) spectroscopy, photoluminescence (PL) spectroscopy, and particle size analyzer (PSA) techniques. At least one mass ratio (NaBH4/Se) of the reducing agent should be added to produce ZnSe nanoparticles finer than 10 nm and to absorb UV-vis light shorter than the ZnSe bulk absorption wavelength of 460 nm. As the ratio of the reducing agent increases, the absorption wavelengths in the UV-vis curves are blue-shifted. Stirring in the atmosphere acts as a deterrent to the reduction reaction and formation of nanoparticles, but if not stirred in the atmosphere, the result is on par with synthesis in a nitrogen atmosphere. The stabilizer, TGA, has an impact on the Zn precursor synthesis. The fabricated nanoparticles exhibit excellent photo-absorption/discharge characteristics, suggesting that ZnSe nanoparticles can be alloyed without the need for organic solutions or high-temperature environments.