• Title/Summary/Keyword: Thin membrane

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Crease Behavior of Thin Membrane (멤브레인의 접힘 거동 연구)

  • Woo, Kyeong-Sik
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.35 no.10
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    • pp.905-911
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    • 2007
  • In this paper, geometrically and materially non-linear finite element analyses were performed to study the crease behavior of thin membranes. The cross-section of the membrane was modeled with 2-dimensional plane strain elements. To simulate the creasing process, the membrane mesh was folded, compressed to prescribed crease gauge by activating two rigid contact surfaces, and then released to give the crease topology. Various crease gauges were considered to investigate the effect of crease intensity on the initial deployment angle. The crease geometry was also obtained by experiments and the results were compared.

Prediction of Cut Propagation Direction of Wrinkled Thin Membrane (얇은 막재에서 컷의 진전방향에 주름이 미치는 영향)

  • Kim, Young-Ah;Woo, Kyeong-Sik
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.40 no.5
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    • pp.423-430
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    • 2012
  • In this paper, the effect of wrinkling on the cut propagation direction of thin membrane was studied using geometrically nonlinear shell element post-buckling analysis. In the analysis, rectangular tensile membrane configuration with a slanted center cut was considered. The cut propagation direction was predicted by maximum energy release rate method, $K_{II}$-zero method, and maximum tangential stress method. The cut propagation angle and the $J$-integral values were calculated for the wrinkled and unwrinkled cases and the results were compared. Various initial cut orientation angles were considered and the effect on the propagation direction was studied. The cut propagation paths were also predicted by virtual cut extension approach.

Synthesis and characterization of polyamide membrane for the separation of acetic acid from water using RO process

  • Mirfarah, Hesam;Mousavi, Seyyed Abbas;Mortazavi, Seyyed Sajjad;Sadeghi, Masoud;Bastani, Dariush
    • Membrane and Water Treatment
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    • v.8 no.4
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    • pp.323-336
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    • 2017
  • The main challenge in many applications of acetic acid is acid dehydration and its recovery from wastewater streams. Therefore, the performance of polyamide thin film composite is evaluated to separate acetic acid from water. To reach this goal, the formation of polyamide layer on polysulfone support membrane was investigated via interfacial polymerization (IP) of meta-phenylenediamine (MPD) in water with trimesoyl chloride (TMC) in hexane. Also, the effect of synthesis conditions, such as concentration of monomers and curing temperature on separation of acetic acid from water were investigated by reverse osmosis process. Moreover, the separation mechanism was discussed. The solute permeation was carried out under applied pressure of 5 bar at $25^{\circ}C$. Surface properties of TFC membrane were characterized by ATR-FTIR, SEM and AFM. The performance test indicated that 3.5 wt% of MPD, 0.35 wt% of TMC and curing temperature of $75^{\circ}C$ are the optimum conditions. Moreover, the permeate flux was $4.3{\frac{L}{m^2\;h}}$ and acetic acid rejection was about 43% at these conditions.

Solvent Filtration Performance of Thin Film Composite Membranes based on Polyethersulfone Support (폴리이터설폰 지지체를 활용한 박막복합막의 용매투과특성 연구)

  • Kim, SeungHwan;Kim, YooShin;Kim, DoYong;Kim, SooMin;Kim, Jeong F.
    • Membrane Journal
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    • v.29 no.6
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    • pp.348-354
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    • 2019
  • Recently, the application range of organic solvent nanofiltration (OSN) technology has been expanding, requiring membranes with better performance. In this work, thin film composite (TFC) OSN membrane was fabricated. First, ultrafiltration support membrane was prepared via nonsolvent-induced phase separation (NIPS) technique using polysulfone (PSf) and polyethersulfone (PES). Then, the effect of pore forming additives such as polyvinylpyrrolidone (PVP) and pluronic F-127 were employed to improve the membrane permeance. The well-known interfacial polymerization technique was employed using MPD-TMC chemistry to form a thin film on top of the fabricated support, and its solvent permeance and nanofiltration performance was characterized. It was found that polyethersulfone support exhibited more reliable performance compared to polysulfone, and PVP additive was more effective compared to Pluronic F-127. As for the oSN performance, polar aprotic solvents like acetonitrile show significantly higher flux (986.5 L·m-2·h-1·bar-1) compared to water and EtOH (9.5 L·m-2·h-1·bar-1).

A Polysilicon Field Effect Transistor Pressure Sensor of Thin Nitride Membrane Choking Effect of Right After Turn-on for Stress Sensitivity Improvement (스트레스 감도 향상을 위한 턴 온 직후의 조름 효과를 이용한 얇은 질화막 폴리실리콘 전계 효과 트랜지스터 압력센서)

  • Jung, Hanyung;Lee, Junghoon
    • Journal of Sensor Science and Technology
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    • v.23 no.2
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    • pp.114-121
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    • 2014
  • We report a polysilicon active area membrane field effect transistor (PSAFET) pressure sensor for low stress deflection of membrane. The PSAFET was produced in conventional FET semiconductor fabrication and backside wet etching. The PSAFET located at the front side measured pressure change using 300 nm thin-nitride membrane when a membrane was slightly strained by the small deflection of membrane shape from backside with any physical force. The PSAFET showed high sensitivity around threshold voltage, because threshold voltage variation was composed of fractional function form in sensitivity equation of current variation. When gate voltage was biased close to threshold voltage, a fractional function form had infinite value at $V_{tn}$, which increased the current variation of sensitivity. Threshold voltage effect was dominant right after the PSAFET was turned on. Narrow transistor channel established by small current flow was choked because electron could barely cross drain-source electrodes. When gate voltage was far from threshold voltage, threshold voltage effect converged to zero in fractional form of threshold voltage variations and drain current change was mostly determined by mobility changes. As the PSAFET fabrication was compatible with a polysilicon FET in CMOS fabrication, it could be adapted in low pressure sensor and bio molecular sensor.

Hydrogen Perm-Selectivity Property of the Palladium Hydrogen Separation Membranes on Porous Stainless Steel Support Manufactured by Metal Injection Molding (금속 사출성형 방식의 다공성 스테인리스 강 지지체에 형성된 팔라듐 수소 분리막의 투과 선택도 특성)

  • Kim, Se-Hong;Yang, Ji-Hye;Lim, Da-Sol;Kim, Dong-Won
    • Journal of the Korean institute of surface engineering
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    • v.50 no.2
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    • pp.98-107
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    • 2017
  • Pd-based membranes have been widely used in hydrogen purification and separation due to their high hydrogen diffusivity and infinite selectivity. However, it has been difficult to fabricate thin and dense Pd-based membranes on a porous stainless steel(PSS) support. In case of a conventional PSS support having the large size of surface pores, it was required to use complex surface treatment and thick Pd coating more than $6{\mu}m$ on the PSS was required in order to form pore free surface. In this study, we could fabricate thin and dense Pd membrane with only $3{\mu}m$ Pd layer on a new PSS support manufactured by metal injection molding(MIM). The PSS support had low surface roughness and mean pore size of $5{\mu}m$. Pd membrane were prepared by advanced Pd sputter deposition on the modified PSS support using fine polishing and YSZ vacuum filling surface treatment. At temperature $400^{\circ}C$ and transmembrane pressure difference of 1 bar, hydrogen flux and selectivity of $H_2/N_2$ were $11.22ml\;cm^{-2}min^{-1}$ and infinity, respectively. Comparing with $6{\mu}m$ Pd membrane, $3{\mu}m$ Pd membrane showed 2.5 times higher hydrogen flux which could be due to the decreased Pd layer thickness from $6{\mu}m$ to $3{\mu}m$ and an increased porosity. It was also found that pressure exponent was changed from 0.5 on $6{\mu}m$ Pd membrane to 0.8 on $3{\mu}m$ Pd membrane.

Positron Annihilation Lifetime Spectroscopic Analysis to Demonstrate Flux-Enhancement Mechanism of Aromatic Polyamide Reverse Osmosis Membranes (양전자 소멸시간 분광분석을 통한 방향족 폴리아미드 역삼투 분리막의 수투과 향상 메커니즘 제시)

  • Kim, Sung-Ho;Kwak, Seung-Yeop
    • Proceedings of the Membrane Society of Korea Conference
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    • 2004.05b
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    • pp.82-85
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    • 2004
  • Flux-enhancement mechanism of thin-film-composite (TFC) membranes for the reverse comosis (RO) process was newly explained by positron annihilation lifetime spectroscopy (PALS) that has been found to be applied for detecting molecular vacancies or pores having sizes that are equivalent to salt or hydrate ions in RO membrane.(omitted)

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A Study on the Variance of Properties of Thin Film Composite Membrane according to change of International Polymerization Condition (계면중합조건에 따른 복합막의 물성 변화에 관한 연구)

  • 이동진;최영국;이수복;민병렬
    • Proceedings of the Membrane Society of Korea Conference
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    • 1998.04a
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    • pp.17-20
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    • 1998
  • 1. 서론 : 계면중합은 제조에 따른 박막의 성능 조절이 가능한 이유로 해서 역삼투용 복합막의 주요 제조 방법으로 제시되어 왔다. 계면중합을 응용하여 제조된 복합막의 성능은 반응 단량체의 종류, 용재의 종류, 단량체의 농도, 반응시간, 열처리 유무 및 온도와 시간 등에 의해 변한다. 한편 위의 변수에 절대적인 영향을 받고 아울러 단량체간의 몰 비가 성립하지 않음으로 해서 최적의 막 성능으로 제시되는 조건을 만족하기 위하여 주로 시행착오에 의한 방법을 동원하여 여러 변수에 다른 제조 막의 성능 고찰을 실시하여 왔다. (생략)

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