• Title/Summary/Keyword: Thin membrane

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Corrosion Properties of Carbon-Coated Metallic Bipolar Plate for PEMFC (고분자 전해질 연료전지 금속 분리판 적용을 위한 탄소 박막의 증착과 내식성 평가)

  • Jang, Dong-Su;Lee, Jung-Joong
    • Journal of Surface Science and Engineering
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    • v.48 no.3
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    • pp.87-92
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    • 2015
  • Carbon thin films were deposited on STS 316L sheets by inductively coupled plasma enhanced magnetron sputtering with or without substrate bias voltage. Typical Raman spectrum for amorphous diamond-like carbon (DLC) was obtained, and the interfacial contact resistance (ICR) was measured to show its conductive nature. The electrochemical impedance spectroscopy (EIS) was used to investigate the corrosion mechanism of the carbon coating under the polymer electrolyte membrane fuel cell (PEMFC) condition. According to the pore-corrosion mechanism, the electrolyte penetrates the carbon coating through the pores and reacts with the substrate. As the substrate corrosion proceeds, the pore enlargement occurs and the surface area of the substrate exposed to the electrolyte. Applicability of the carbon coating for the PEMFC bipolar plate was evaluated by potentiodynamic polarization experiments. Finally, an adhesion problem was briefly considered.

A 2-Node Strain Based Curved Beam Element (변형률에 근거한 2-절점 곡선보 요소)

  • Ryu, Ha-Sang;Sin, Hyo-Chol
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.20 no.8
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    • pp.2540-2545
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    • 1996
  • It is well known that in typical displacement-based curved beam elements, the stiffness matrix is overestimated and as a result displacement predictions show gross error for the thin beam case. In this paper, a stain based curved beam element with 2 nodes is formulated based on shallow beam geometry. At the element level, the curvature and membrane strain fields are approximated independently and the displacement fields are obtained by integrating the strain fields. Three test problems are given to demonstrate the numerical performance of the element. Analysis results obtained reveal that the element is free for locking and very effectively applicable to deeply as well as shallowly curved beams.

A co-rotational 8-node assumed strain element for large displacement elasto-plastic analysis of plates and shells

  • Kim, K.D.
    • Structural Engineering and Mechanics
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    • v.15 no.2
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    • pp.199-223
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    • 2003
  • The formulation of a non-linear shear deformable shell element is presented for the solution of stability problems of stiffened plates and shells. The formulation of the geometrical stiffness presented here is exactly defined on the midsurface and is efficient for analyzing stability problems of thick plates and shells by incorporating bending moment and transverse shear resultant force. As a result of the explicit integration of the tangent stiffness matrix, this formulation is computationally very efficient in incremental nonlinear analysis. The element is free of both membrane and shear locking behaviour by using the assumed strain method such that the element performs very well in the thin shells. By using six degrees of freedom per node, the present element can model stiffened plate and shell structures. The formulation includes large displacement effects and elasto-plastic material behaviour. The material is assumed to be isotropic and elasto-plastic obeying Von Mises's yield condition and its associated flow rules. The results showed good agreement with references and computational efficiency.

Progress in the modification of reverse osmosis (RO) membranes for enhanced performance

  • Otitoju, T.A.;Saari, R.A.;Ahmada, A.L.
    • Journal of Industrial and Engineering Chemistry
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    • v.67
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    • pp.52-71
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    • 2018
  • RO membranes, the core elements for RO process formed using polyamide, have found prominent space in membrane technology. RO membranes with better application perspective could be achieved by precise controlling the kinetics of IP reaction and surface modification strategy. Despite huge progresses, great challenges still exist in trade-off between flux, rejections and fouling. More works are necessary to enhance the performance and stability of RO membranes via surface modification. Further insights into the use of natural monomers are necessary. It is anticipated that this article can provide clues for further in-depth evaluation and research in exploring more advanced RO membranes.

Experiment and simulation analysis on full scale double-layer concrete shell

  • Thanh Quang Khai Lam;Thi My Dung Do
    • Computers and Concrete
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    • v.31 no.1
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    • pp.9-21
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    • 2023
  • The published studies usually used analytical method, numerical methods or experimental method to determine the stress-strain state and displacement of the single-layer or multi-layer curved shell types, but with a small scale model. However, a full scale multi-layer doubly curved concrete shell roof model should be researched. This paper presents the results of the experiment and simulation analysis involving stress-strain state, sliding between layers, the formation and development of the full scale double-layer doubly curved concrete shell roof when this shell begins to crack. The results of the this study have constructed the load-sliding strain relationship; strain diagram; stress diagram in the shell layers; the Nx, Ny membrane force diagram and deflection of shell. Thisresults by experimental method on a full scale model of concrete have clarified the working of multi-layer doubly curved concrete shell roof. The experimental and simulation results are compared with each other and compared with the Sap2000 software.

Five new species of genus Hyattella (Dictyoceratida: Spongiidae) from Korea

  • Young A Kim;Kyung Jin Lee
    • Journal of Species Research
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    • v.13 no.1
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    • pp.32-40
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    • 2024
  • Five new species of the genus Hyattella (Dictyoceratida: Spongiidae) were collected from Jejudo and Gageodo, Korea: Hy. gukheulensis n. sp., Hy. regularis n. sp., Hy. lenis n. sp., Hy. membrana n. sp., and Hy. asper n. sp. Hyattella gukheulensis n. sp. is similar to Hy. munseomensis Sim et al., 2015 in shape, but differs in skeletal structure. Hyattella regularis n. sp. is close to Hy. bakusi Sim et al., 2015 but differs in regular secondary fibres at the surface membrane. Hyattella lenis n. sp. is unique by having numerous windings at the surface. Hyattella membrana n. sp. is similar to Hy. bakusi Sim et al., 2015 in shape, but differs in surface and skeletal fibres. Hyattella asper n. sp. is close to Hy. lendenfeldi Sim and Lee, 2014 in skeletal fibres, but differs in thin secondary fibres. This new species has numerous dense cored primary fibres.

Studies on the Fouling Reduction by Coating of Cationic Exchange Polymer onto Reverse Osmosis Membrane Surfaces (역삼투막 표면의 양이온 교환 고분자 코팅에 의한 파울링 감소 연구)

  • Park, Chan Jong;Kim, Sung Pyo;Cheong, Seong Ihl;Rhim, Ji Won
    • Polymer(Korea)
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    • v.36 no.6
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    • pp.810-815
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    • 2012
  • The cation exchange polymer, poly(styrene sulfonic acid) (PSSA), was coated onto polyamide (PA) thin film composite reverse osmosis (RO) membranes. Then these membranes were investigated for the model foulants, bovine serum albumin (BSA), humic acid (HA), and sodium alginate (SA) to check whether there are some improvement. The contact angle of PSSA coated PA RO membrane showed $58^{\circ}$ from $78^{\circ}$, the value of PA RO membrane, which confirmed successful hydrophilization. As the operating pressure increased (2, 4, 8 atm for BSA, HA and SA 100 ppm in feed solution), the fouling phenomena was worse for both none- and PSSA-coated membranes. The fouling increased in the order of BSA>SA>HA due to the interactions between sulfonic acid in PSSA and functional groups of foulants. On the other hand more significant fouling reduction was observed in the order of HA>SA>BSA. The photographs of scanning electron microscopy showed the same trend. As a result, there was the improvement of fouling phenomena for the PSSA coated RO membranes, distinctly in the case of HA.

Studies on the Fouling Reduction through the Coating of Poly (vinyl alcohol) on Polyamide Reverse Osmosis Membrane Surfaces (역삼투막 표면에 폴리비닐알코올 코팅을 통한 파울링 현상 감소연구)

  • Kim, Il Hyoung;Ji, Eun Hee;Rhim, Ji Won;Cheong, Seong Ihl
    • Membrane Journal
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    • v.22 no.4
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    • pp.272-279
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    • 2012
  • The neutral polymer, poly (vinyl alcohol) (PVA), was coated onto polyamide (PA) thin film composite reverse osmosis (RO) membranes. And then these membranes were investigated for the model foulants, bovine serum albumin (BSA), humic acid (HA), and sodium alginate (SA) whether there are aome improvement. As the operating pressure increased with 2, 4, 8 atm for BSA, HA and SA 100 ppm in feed solution, the fouling phenomena was worse for both none and PSSA coated membranes. The fouling occurred in the sequence of BSA > HA > SA due to the interactions between PVA snd functional groups of foulants, and on the other hand the fouling reduction was observed in the order of HA > BSA > SA. The observation of scanning electron microscopy photographs showed the same trend. As a result, there should be the improvement of fouling phenomena for the PVA coated RO membranes and the case of HA was shown distinct.

Effect of Seed Coating Layer on the Microstructure of NaA Zeolite Separation Layer Grown on ${\alpha}$-alumina Support (종결정 코팅층이 다공성 ${\alpha}$-알루미나 지지체 표면에 성장되는 NaA 제올라이트 분리층의 미세구조에 미치는 영향)

  • Kim, Min-Ji;Sharma, Pankaj;Han, Moon-Hee;Cho, Churl-Hee
    • Membrane Journal
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    • v.24 no.5
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    • pp.375-385
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    • 2014
  • NaA zeolite/${\alpha}$-alumina composite membranes were hydrothermally synthesized at $100^{\circ}C$ for 24 hr by using nanosize seed of 100 nm in diameter and an ${\alpha}$-alumina support of $0.1{\mu}m$ in pore diameter, and then effect of seed coating layer on the microstructure of NaA zeolite separation layer was systematically investigated. In cases when nanosize seed was coated with a monolayer, increment in seed coverage induced small grained and thick NaA zeolite separation layer. On the other hand, in case when nanosize seed was coated with a multilayer, much small grained and thick separation layer was formed. It was clear that an uniform monolayer seed coating is required to grow hydrothermally a thin and defect-free NaA zeolite separation layer. In the present study, it was clearly announced that seed coating layer is a key factor to determine the microstructure of NaA zeolite layer, secondary grown on a porous support.

Ultrastructural Btudy on the Degranulation of Rat Peritoneal Mast Cells Induced by Horseradish Peroxidase (Horseradish Peroxidase에 의해 유도(誘導)된 백서(白鼠) 복강비만세포(腹腔肥滿細胞)의 탈과립(脫顆粒)에 관(關)한 미세구조적(微細構造的) 연구(硏究))

  • Cho, Byung-Pil;Kang, Ho-Suck;Kim, Woo-Kap
    • Applied Microscopy
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    • v.17 no.1
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    • pp.98-114
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    • 1987
  • Degranulation of the rat peritoneal mast cell induced by intraperitoneal injection of horseradish peroxidase(HRP) was studied using light and electron microscopes. 1. Rat peritoneal mast cells in the Tyrode's buffered salt solution injected control group did not show any particular morphological changes following the specified time course. 2. Under the light microscope, the majority of mast cells observed 10 minutes after HRP injection were nearly the same as those of the control group. However, after 30 minutes, granule densities or staining properties of certain cells began to decrease and these appearances increased gradually until 12 hours after injection, at which time small groups of granules being stained pale-red or pink with toluidine blue were easily identified in the cytoplasm of many cells, and numerous extruded granuleg were scattered around these cells. 3. In the mast cells representing the early stage of degranulation induced by HRP, the electron densities of certain granules decreased as the size enlarged, and perigranular cavities were formed by perigranular membrane expansion. As a result, a thin cytoplasmic septum was formed between the expanded perigranular membrane and the cytoplasmic membrane in the cell periphery, and fusion of the adjacent perigranular membranes was observed in the inner side of the cell. 4. In some mast cells, one or two changes in the peripheral cytoplasmic septum could be seen. One was a focal rupture of the peripheral septum and the other was the formation of a saccule containing one or more vesicles. This saccule was thought to be used for granule-extrusion site and/or material absorptive apparatus judging from the morphological characteristics. 5. As the degranulation proceeded, the granule was extruded from the cell after partial rupture of the peripheral cytoplasmic septum. This phenomenon proceeded to-ward the inner side of the cell through the fused perigranular cavities, and consequently several distinct cavities containing a few unextruded membrane-free granules were formed throughout the cytoplasm after 12 hours. As a rule, the granule-extrusion sites were relatively fewer while the cytoplasmic cavities resulting from degranulation were more numerously observed. Thus, it was thought that the granule-extrusion sites tended to be restricted in the HRP-induced degranulation.

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