• Title/Summary/Keyword: Thin membrane

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Optimal Operational Planning of 1 kW Household PEMFC System (가정용 PEMFC 운전 최적 설계)

  • Kim, Ki-Young;Seo, Seok-Ho;Oh, Si-Doek;Kwak, Ho-Young
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.06a
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    • pp.113-116
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    • 2007
  • The fuel cell which converts directly chemical energy of fuel into electric energy has higher efficiency than the conventional power generation which involves several additional processes. Especially, polymer electrolyte membrane fuel cell (PEMFC) of which the electrolyte is a thin proton conductive polymer membrane is affordable for portable power applications and small-scale distributed power generation including household and small building. It is very important to not only increase the efficiency of FC itself but determine the optimal operation mode. The optimal operational planning of lkW household PEMFC system based on the daily electricity and heat demand patterns was performed. The estimated economic gain was up to 20% by adoption of PEMFC system.

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Electron-Microscopic Studies on the Spermiogenesis and the Spermatozoa of the Drake and the Gander (오리와 거위의 정자완성과 정자에 관한 전자현미경적 연구)

  • 배대식;김종욱
    • Korean Journal of Animal Reproduction
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    • v.11 no.3
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    • pp.206-217
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    • 1987
  • Testes from the drake and the gander have been examined by the electron microscopy in thin sections in order to examine the spermiogenesis and the structure of spermatozoa. The spermiogenesis can be divided into three stages: early spermatid, nuclear elongation, and matured spermatid. In the early spermatid of the drake, there are thread-like material in the nucleus, a prominent nuclear envelope around the nucleus, and big lumens in the cytoplasm. The shape of the gander's mitochondria in the early spermatid is slender compared to that of the drake, and the inner membrane of the mitochondria is thicker than the outer membrane. The distal centriole of the drake and the gander in the early spermatid is a long hollow cylinder form. In the nuclear elongation stage, elongated nucleus forms two or three cross sections in one spermatid cell and it is surrounded by the amorphous sheath. The nucleus of the matured spermatid is compact and its apical end is covered with acrosome cap and acrosome spine. The axoneme is surrounded by the amorphous material.

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The Deposition Characterization of DLPC Lipid Membrane by Moving Wall Type LB Methode (Moving Wall형 LB법에 의해서 제작된 DLPC 지질막의 누적특성)

  • 정용호;이우선;김남오;이경섭
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1997.04a
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    • pp.342-345
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    • 1997
  • We fabricated the sample of u1tra thin lipid membrane(L-${\alpha}$-DLPC ) by LB methode. The $\pi$-A isotherm of the DLPC was measured at the air-water interface varying with the compressing speed and amounts of solutions for spreading. For good property of lipid monolayer film, it was necessary for the lower speed of compressing, and 40${\mu}\ell$ of solutions for spreading. The molecular arrangement of deposited films were evaluated by measuring the absorption, transmitance and intensity with the UV spectrophotometer. The Y-type multilayers prepared at 50mN/m showed weaker than Z-type. So we found building-up of structurally high quality LB films is essential to study properties of the films and to get reproducible data.

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A study of properties of DLC films for membrane structure (멤브레인 구조를 위한 DLC 박막의 특성에 관한 연구)

  • Lee, Tae-Yong;Kim, Eung-Kwon;Park, Yong-Seob;Hong, Byung-You;Song, Joon-Tae;Park, Young
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07b
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    • pp.748-752
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    • 2004
  • The Hydrogenated amorphous carbon (a-C:H) thin films are deposited to fabricate suppored layer on silicon substrate with a closed field unbalanced magnetron(CFUBM) sputtering system. This study focuses on the characteristic of Diamond like carbon (DLC) films and Pb(Zr,Ti)$O_3$ (PZT) films for membrane structure. The deposition rate and the surface roughness of DLC fims decrease with DC bias voltage. hardness is 26 GPa at -200 V. Interface of DLC/Si and Pt/DLC layers was excellent.

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Disposable Microfluidic Infusion Pump using Elastomeric Blister Actuator (탄성 블리스터 액츄에이터를 이용한 일회용 미세유체 주입펌프)

  • Jang, Woong Ki;Kim, Hyung Jin;Kim, Byeong Hee;Seo, Young Ho
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.22 no.2
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    • pp.235-240
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    • 2013
  • This paper presents a disposable microfluidic infusion pump using the restoring force of elastomeric membrane of Polydimethylsiloxane. Microfluidic infusion pump consists of hydraulic resistance control part, elastomeric blister actuator part, drug inlet and outlet. Expanded elastomeric blister actuator continuously pushes liquid in the chamber to outlet. At same time, microchannel diameter near the outlet was controlled by thin elastomeric membrane in hydraulic resistance control part. Eventually flow rate of infused liquid is controlled by air pressure. In experimental study, the amount of the filled liquid in the blister is precisely controlled by the height of the blister. Flow rate of infused liquid could be controlled, that is, controlled release of the drug over time was possible by adjusting hydraulic resistance and restoring pressure with the blister actuator.

Fabrication of a CNT Filter for a Microdialysis Chip

  • An, Yun-Ho;Song, Si-Mon
    • Molecular & Cellular Toxicology
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    • v.2 no.4
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    • pp.279-284
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    • 2006
  • This paper describes the fabrication methods of a carbon nanotube (CNT) filter and a microdialysis chip. A CNT filter can help perform dialysis on a microfluidic chip. In this study, a membrane type of a CNT filter is fabricated and located in a microfluidic chip. The filter plays a role of a dialysis membrane in a microfluidic chip. In the fabrication process of a CNT filter, individual CNTs are entangled each other by amide bonding that is catalyzed by 1-Ethyl-3-(3-dimethylaminopropyl)carbodiimide (EDC) and N-hydroxysuccinimide (NHS). The chemically treated CNTs are shaped to form a CNT filter using a PDMS film-mold and vacuum filtering. Then, the CNT filter is sandwiched between PDMS substrates, and they are bonded together using a thin layer of PDMS prepolymer as adhesive. The PDMS substrates are fabricated to have a microchannel by standard photo-lithography technique.

The Uptake of Solvent in Polymeric Thin Membranes By a Relaxation-Sorption Coupled Mechanism

  • Song, Kyu-Min;Hong, Won-Hi
    • Proceedings of the Membrane Society of Korea Conference
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    • 1995.10a
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    • pp.43-44
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    • 1995
  • The diffusion behavior of liquid into polymer has been described by Fick's law, but the departure from Fickian diffusion is frequently found. In this study, 'noble' expressions for the rates of relaxation and sorption are introduced to eliminate these limitations. The ralaxation-sorption coupled mechanism model are based on the possibility of contacting liquid molecule and the active site which has the numerical concept of free volume. The concept has an analogy of reaction rate expressed by the possibility of collision with molecules and used in adsorption and reactive extraction etc. The new model simulated by Rungc-Kutta method for initial-value problem and Fickian diffusion is caompared with experimental data. The results show that the ralaxation-sorption coupled mechanism is able to account well for Fickian and non-Fickian sorption behavior including sigmoid and two-stage. In addition, this model has a chance of expansion to multi-component sorption with ease.

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Studies on the Separation Performances of Chlorophenol Compounds from Water by Thin Film Composite Membranes

  • Yogesh, K.M. Popat;Ganguly, B.;Brahmbhatt, H.;Bhattacharya, A.
    • Macromolecular Research
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    • v.16 no.7
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    • pp.590-595
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    • 2008
  • The pressure driven membrane process has been a breakthrough in the removal of pollutants from drinking water. These experiments examined the removal of chlorophenol compounds from water using low pressure membranes. The removal performance of the membranes was based primarily on size exclusion. Apart from size exclusion, the polarity and pKa of the compounds also influences the membrane performance. The molecular size and dipole moments of the respective molecules were calculated using a quantum chemical method. The rejection of pollutants also followed the same trend as salt rejection by the membranes.

Synthesis of Graphene Using Thermal Chemical Vapor Deposition and Application as a Grid Membrane for Transmission Electron Microscope Observation (열화학증기증착법을 이용한 그래핀의 합성 및 투과전자현미경 관찰용 그리드 멤브레인으로의 응용)

  • Lee, Byeong-Joo;Jeong, Goo-Hwan
    • Korean Journal of Materials Research
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    • v.22 no.3
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    • pp.130-135
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    • 2012
  • We present a method of graphene synthesis with high thickness uniformity using the thermal chemical vapor deposition (TCVD) technique; we demonstrate its application to a grid supporting membrane using transmission electron microscope (TEM) observation, particularly for nanomaterials that have smaller dimensions than the pitch of commercial grid mesh. Graphene was synthesized on electron-beam-evaporated Ni catalytic thin films. Methane and hydrogen gases were used as carbon feedstock and dilution gas, respectively. The effects of synthesis temperature and flow rate of feedstock on graphene structures have been investigated. The most effective condition for large area growth synthesis and high thickness uniformity was found to be $1000^{\circ}C$ and 5 sccm of methane. Among the various applications of the synthesized graphenes, their use as a supporting membrane of a TEM grid has been demonstrated; such a grid is useful for high resolution TEM imaging of nanoscale materials because it preserves the same focal plane over the whole grid mesh. After the graphene synthesis, we were able successfully to transfer the graphenes from the Ni substrates to the TEM grid without a polymeric mediator, so that we were able to preserve the clean surface of the as-synthesized graphene. Then, a drop of carbon nanotube (CNT) suspension was deposited onto the graphene-covered TEM grid. Finally, we performed high resolution TEM observation and obtained clear image of the carbon nanotubes, which were deposited on the graphene supporting membrane.

Effects of Methyl-Beta-Cyclodextrin (MBCD) on Cold Shock and Membrane Cholesterol Quantity during the Freezing Process of Miniature Pig Spermatozoa (미니돼지 정액 동결 시 Methyl-Beta-Cyclodextrin (MBCD)이 냉각 충격과 막 콜레스테롤량에 미치는 영향)

  • Lee, Sung-Young;Lee, Yong-Seung;Cheong, Hee-Tae;Yang, Boo-Keun;Park, Choon-Keun
    • Reproductive and Developmental Biology
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    • v.35 no.3
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    • pp.265-271
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    • 2011
  • This study was undertaken to find out the effect of methyl-beta-cyclodextrin (MBCD) on cold shock and membrane cholesterol quantity of sperm during the freezing process in miniature pigs. For this study, semen ejaculated from PWG M-type miniature pig was diluted that freezing solution (with egg yolk group) and m-Modena B (without egg yolk group) treated with 0, 1, 5, 10 and 20 mM MBCD before freezing process. The diluted semen was monitored sperm ability at room temperature, after cooled until $5^{\circ}C$ and after forzen-thawed for cold shock test of spermatozoa. Also, membrane cholesterol of sperm was extracted by folch solution at the same time sperm ability was assessed for viability and acrosomal status. The membrane cholesterol quantity was measured by thin-layer chromatography (TLC) method. The result, viability and acrosome integrity in semen diluted without egg yolk groups were decreased at all temperature range by increasing of MBCD concentration. In particular, sperm of egg yolk group was showed that significantly higher viability and lower acrosome damage when treated with 5 mM MBCD (p<0.05). The results of TLC experiment, cholesterol amounts were increased with MBCD cocentration in egg yolk, and decreased with MBCD concentration in m-Modena B. In cryopreservation efficiency, there was no significant difference at viability, and acrosomal state of sperm in 5 mM MBCD concentration was significantly lower in acrosome damage than other groups (p<0.05). Therefore, the addition MBCD in egg yolk was protected spermatozoa from cold shock injury. This protective effect of MBCD may be due to addition of sperm membrane cholesterol.