• Applied Chemistry for Engineering
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• v.9 no.3
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• pp.342-347
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• 1998

Light-weight conductive polymer composites were prepared by incorporating polyheterocycles such as polypyrrole and polythiophene into pores of a highly porous cross-linked polystyrene, host polymer, to form a conductive network. The highly hydrophobic and porous host polymer was synthesized by concentrated emulsion polymerization method. Polypyrrole-based composites, prepared by employing ferric chloride-methanol system, showed a conductivity as high as 0.82 S/cm. Conductivity of polythiophene-based composites, prepared from ferric chloride-acetonitrile system, was 6.05 S/cm. Conductivity of compositivity was influenced by the initial molar ratio of oxidant to monomer as well. SEM micrographs of the composites showed that conducting polymer coated uniformly the inside wall of the porous host polymer. Shielding effectiveness of the polypyrrole-based composites and of the polythiophene-based composites were 15.2 dB and 22.5 dB at 2.0 GHz, respectively. In the temperature range from 20 to 300K, a polypyrrole impregnated composite exhibited seimiconducting behavior and followed the variable range hopping(VRH) model for charge transport.

• Imaging Science in Dentistry
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• v.43 no.3
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• pp.145-151
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• 2013

Purpose: This study was performed to evaluate and compare the radiopacity of dentin, enamel, and 8 restorative composites on conventional radiograph and digital images with different resolutions. Materials and Methods: Specimens were fabricated from 8 materials and human molars were longitudinally sectioned 1.0 mm thick to include both enamel and dentin. The specimens and tooth sections were imaged by conventional radiograph using #4 sized intraoral film and digital images were taken in high speed and high resolution modes using a phosphor storage plate. Densitometric evaluation of the enamel, dentin, restorative materials, a lead sheet, and an aluminum step wedge was performed on the radiographic images. For the evaluation, the Al equivalent (mm) for each material was calculated. The data were analyzed using one-way ANOVA and Tukey's test (p<0.05), considering the material factor and then the radiographic method factor, individually. Results: The high speed mode allowed the highest radiopacity, while the high resolution mode generated the lowest values. Furthermore, the high resolution mode was the most efficient method for radiographic differentiation between restorative composites and dentin. The conventional radiograph was the most effective in enabling differentiation between enamel and composites. The high speed mode was the least effective in enabling radiographic differentiation between the dental tissues and restorative composites. Conclusion: The high speed mode of digital imaging was not effective for differentiation between enamel and composites. This made it less effective than the high resolution mode and conventional radiographs. All of the composites evaluated showed radiopacity values that fit the ISO 4049 recommendations.

• Composites Research
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• v.31 no.1
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• pp.23-29
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• 2018

The RFI process can be applied to very thick structures without limiting the resin viscosity. When the proper thickness of the resin film cannot be set, the resin film creates either the non-impregnated section or the excessive resin contents and this leads to the deterioration of mechanical properties. Therefore, this study proposed a method for setting the resin film thickness in the RFI process. The fiber compaction behavior test was proposed by setting the proper resin film thickness and the properties of composites were evaluated through short beam shear strength test, compression test and porosity measurement to verify the proposed method. The evaluation of physical properties of composites was conducted and an appropriate level of resin film thickness was found based on the results of fiber compaction behavior test.

• Restorative Dentistry and Endodontics
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• v.40 no.2
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• pp.128-135
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• 2015

Objectives: This study evaluated the effects of the resin thickness on the microhardness and optical properties of bulk-fill resin composites. Materials and Methods: Four bulk-fill (Venus Bulk Fill, Heraeus Kulzer; SDR, Dentsply Caulk; Tetric N-Ceram Bulk Fill, Ivoclar vivadent; SonicFill, Kerr) and two regular resin composites (Charisma flow, Heraeus Kulzer; Tetric N-Ceram, Ivoclar vivadent) were used. Sixty acrylic cylindrical molds were prepared for each thickness (2, 3 and 4 mm). The molds were divided into six groups for resin composites. The microhardness was measured on the top and bottom surfaces, and the colors were measured using Commission Internationale d'Eclairage (CIE) $L^*a^*b^*$ system. Color differences according to the thickness and translucency parameters and the correlations between the microhardness and translucency parameter were analyzed. The microhardness and color differences were analyzed by ANOVA and Scheffe's post hoc test, and a student t-test, respectively. The level of significance was set to ${\alpha}=0.05$. Results: The microhardness decreased with increasing resin thickness. The bulk-fill resin composites showed a bottom/top hardness ratio of almost 80% or more in 4 mm thick specimens. The highest translucency parameter was observed in Venus Bulk Fill. All resin composites used in this study except for Venus Bulk Fill showed linear correlations between the microhardness and translucency parameter according to the thickness. Conclusions: Within the limitations of this study, the bulk-fill resin composites used in this study can be placed and cured properly in the 4 mm bulk.

• Journal of the Microelectronics and Packaging Society
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• v.22 no.4
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• pp.65-70
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• 2015

A study on thermal properties for a single-layer metal and two-layer composites was investigated for the heat-sink application. For the single-layer metal, an aluminum alloy (Al6061) was selected. A screen printed aluminum nitride (AlN) layer on the Al6061 substrate was chosen for the two-layer composites. The thermal conductivity of the sample was determined from the thermal diffusivity measured by the light flash analysis (LFA), specific heat and density. Measured thermal property values were compared to calculated values using the data from the references. The thermal conductivity of composites with screen printed AlN layer on the Al6061 substrate decreased linearly with increasing the thickness of AlN layer. Measured values of the thermal conductivity for composites with $53{\mu}m$ and $163{\mu}m$ thick AlN layers were $114.1W/m{\cdot}K$ and $72.3W/m{\cdot}K$, respectively. In particular, the thermal conductivity of the screen-printed AlN layer was demonstrated by appling the rule of mixture in view point of thermal resistivity. Measured values of the thermal conductivity for AlN layers with the thickness of $53{\mu}m$ and $163{\mu}m$ showed $9.35W/m{\cdot}K$ and $12.40W/m{\cdot}K$, respectively.

• Journal of the Korean Ceramic Society
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• v.34 no.8
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• pp.908-913
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• 1997

Multilayer NbCxC1-x/Y2O3/Ti were sputter-coated on the alumina substrate, starting with a 0.7 ㎛ thick NbCxC1-x layer grown on substrate, followed by 0.7 ㎛ thick Y2O3 layer and 1 ㎛ thick Ti layer. To find out the optimum conditions for thickness uniformity and adhesion, sputtering works have been done with the variation of sputtering power and Ar pressure. After vacuum annealing at 950℃ and 1000℃, the thermal stability of the NbCxC1-x/Y2O3/Ti coated alumina substrates has been investigated by peel off test. The coating scheme didn't cause any debonded layer after an annealing at 950℃ for 3hrs. However, it was peeled off after annealing at 1000℃ for 3hr. It was found that the thermal stability of Al2O3/NbCxC1-x/Y2O3/Ti coating scheme changed with the NbCxC1-x composition.

• Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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• 2004.11a
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• pp.225-227
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• 2004

The compressive characteristics of thick carbon/epoxy composite in a submarine environment was investigated in this study. The specimens made of thick carbon fiber/epoxy composite that were immersed into seawater Jar thirteen months. the seawater content at saturation was about $1.2\%$ of the specimen weight. Compressive tests have been performed in different hydrostatic pressures of 0.1 MPa, 100 MPa, 200 MPa, and 270 MPa. The results showed that the compressive elastic modulus increased about $12.3\%$ as the hydrostatic pressure increased from 0.1 MPa to 200 MPa. The results also showed that compressive fracture strength increased $28\%$ and compressive fracture strain increased $8.5\%$ as the hydrostatic pressure increased from 0.1 MPa to 270 MPa.

• Restorative Dentistry and Endodontics
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• v.41 no.3
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• pp.159-166
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• 2016

The purpose of this review was to suggest practical criteria for the clinical translucency evaluation of direct esthetic restorative materials, and to review the translucency with these criteria. For the evaluation of reported translucency values, measuring instrument and method, specimen thickness, background color, and illumination should be scrutinized. Translucency parameter (TP) of 15 to 19 could be regarded as the translucency of 1 mm thick human enamel. Visual perceptibility threshold for translucency difference in contrast ratio (${\Delta}CR$) of 0.07 could be transformed into ${\Delta}TP$ value of 2. Translucency differences between direct and indirect resin composites were perceivable (${\Delta}TP>2$). Universal and corresponding flowable resin composites did not show perceivable translucency differences in most products. Translucency differed significantly by the product within each shade group, and by the shade group within each product. Translucency of human enamel and perceptibility threshold for translucency difference may be used as criteria for the clinical evaluation of translucency of esthetic restorative materials.

• Proceedings of the Korean Society For Composite Materials Conference
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• 2002.10a
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• pp.280-283
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• 2002

In the manufacturing of large scale composite structures, the cost-effective processing and the enhancement of structural performance are critical. One of the most effective ways for this purpose is to use stitched multiaxial warp knitted (MWK) perform in the resin transfer molding process. This study reports the effect of stitching on the mechanical properties of MWK composites, and the feasibility processing of the thick U-beam structure utilizing the stitched preforms. Permeability of the preform, viscosity and cure property of the epoxy resin have been measured. The results of resin flow analysis has been used in determining the gate/vent locations of the RTM mold. Cross-sectional observation of the channel beam prototype demonstrated that the resin impregnation was almost complete, except for some surrounding area of stitched yarns.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2003.06a
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• pp.1390-1393
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• 2003

Work factor approach is conveniently used in metal fracture mechanics to determine fracture toughness from a single fracture test. In this work, we investigated the applicability of the work factor approach in order to determine fracture toughness of thick graphite/epoxy composites in the hydrostatic pressure environment from a single fracture test. The effect of hydrostatic pressure on the elastic work factor was studied, The stacking sequence used was multi-directional, [0$^{\circ}$/${\pm}$45$^{\circ}$/90$^{\circ}$]. The hydrostatic pressures applied were 0.1 MPa, 100 MPa, 200 MPa, and 300 MPa. The results showed that the elastic work factor was not affected by the hydrostatic pressure, The elastic work factor decreased in a linear fashion with crack length.