• Journal of The Korean Society of Agricultural Engineers
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• v.53 no.5
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• pp.9-16
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• 2011

Curve Numbers (CN) for the combination of land use and hydrologic soil group were regionalized at Imha Watershed using Long-term Hydrologic Impact Assessment (L-THIA) coupled with SCE-UA. The L-THIA was calibrated during 1991-2000 and validated during 2001-2007 using monthly observed direct runoff data. The Nash-Sutcliffe (NS) coefficients for calibration and validation were 0.91 and 0.93, respectively, and showed high model efficiency. Based on the criteria of model calibration, both calibration and validation represented 'very good' fit with observe data. The spatial distribution of direct surface runoff by L-THIA represented runoff from Thiessen pologen at Subi and Sukbo rain gage station much higher than other area due to the combination of poor hydrologic condition (hydrologic soil C and D group) and locality heavy rainfall. As a results of hydrologic condition and treatment for land use type based on calibrated CNs, forest is recommended to be hydrologically modelled dived into deciduous, coniferous, and mixed forest due to the hydrological difference. The CNs for forest and upland showed the poor hydrologic condition. The steep slope of forest and alpine agricultural field make high runoff rate which is the poor hydrologic condition because CN method can not consider field slope. L-THIA linded with SCE-UA could generated a regionalized CNs for land use type with minimized time and effort, and maximized model's accuracy.

• Bulletin of the Korean Chemical Society
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• v.30 no.2
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• pp.287-288
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• 2009

• Journal of The Korean Society of Agricultural Engineers
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• v.52 no.1
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• pp.1-11
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• 2010

Generation and transportation of runoff and pollutant loads within watershed generated eutrophication at Daecheong reservoir. To improve water quality at Daecheong reservoir, the best management practices should be developed and applied at upper watersheds for water quality improvement at downstream areas. In this study, two small watersheds of upper Daecheong reservoir were selected. The Long-Term Hydrologic Impact Assessment (L-THIA) model has been widely used for the estimation of the direct runoff worldwide. To apply the L-THIA ArcView GIS model was evaluated for direct runoff and water quality estimation at small watershed. And the Web-based Hydrograph Analysis Tool (WHAT) was used for direct runoff separating from total flow. As a result, the $R^2$ (Coefficient of determination) value and Nash-Sutcliffe coefficient value for direct runoff comparison at An-nae watershed were 0.81 and 0.71, respectively. And the $R^2$ value and Nash-Sutcliffe coefficient value at Wol-oe were 0.95 and 0.93. The $R^2$ value of BOD, TOC, T-N and T-P at An-nae watershed were BOD 0.94, TOC 0.81, T-N 0.94 and T-P 0.89. And the $R^2$ value of BOD, TOC, T-N and T-P at Wol-oe watershed were BOD 0.80, TOC 0.93, T-N 0.86 and T-P 0.65. The result that estimated pollutant loadings using the L-THIA ArcView GIS model reflected well the measured pollutant loadings except for T-P in Wol-oe watershed. With L-THIA ArcView GIS model, the direct runoff and non-point pollutant (NPS) loadings in the watershed could be analyzed through simple input data such as daily rainfall, land uses, and hydrologic soil group.

• Journal of Korean Society on Water Environment
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• v.27 no.4
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• pp.405-412
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• 2011

Increased Non-permeable areas which have resulted from civilization reduce the volume of groundwater infiltration that is one of the important factors causing water shortage during a dry season. Thus, seeking the efficient method to analyze the volume of groundwater in accurate should be needed to solve water shortage problems. In this study, two different watersheds were selected and precipitation, soil group, and land use were surveyed in a particular year in order to figure out the accuracy of estimated infiltration recharge ratio compared to Web-based Hydrograph Analysis Tool (WHAT). The volume of groundwater was estimated considering Antecedent soil Moisture Condition (AMC) and Curve Number (CN) using Long Term Hydrologic Impact Assessment (L-THIA) model. The results of this study showed that in the case of Kyoung-an watershed, the volume of both infiltration and baseflow seperated from WHAT was 46.99% in 2006 and 33.68% in 2007 each and in Do-am watershed the volume of both infiltration and baseflow was 33.48% in 2004 and 23.65% in 2005 respectively. L-THIA requires only simple data (i.e., land uses, soils, and precipitation) to simulate the accurate volume of groundwater. Therefore, with convenient way of L-THIA, researchers can manage watershed more effectively than doing it with other models. L-THIA has limitations that it neglects the contributions of snowfall to precipitation. So, to estimate more accurate assessment of the long term hydrological impacts including groundwater with L-THIA, further researches about snowfall data in winter should be considered.

• Journal of Korean Society of Rural Planning
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• v.8 no.2 s.16
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• pp.3-16
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• 2002

의사결장지원시스템은 다양한 분야에 적용되어 왔으며, 그 중 수자원 및 수질 관련 분야에도 다각적으로 적용되어 왔다. 본 연구에서는 미 농무성의 자연자원보전국(NRCS, Natural Resources Conservation Service)에서 개발한 유출곡선법(Curve Number Method)과 EMC(Event Mean Concentration)을 사용한 L-THIA(Long-Term Hydrologic Impact Assessment) 수문/수질 모형을 강우자료 데이터베이스, 웹기반 지리정보시스템, 웹 사용자 편의 시스템과 통합한 수문/수질 L-THIA web 의사결정지원시스템을 개발하였다. L-THIA web은 도시계획가나 지방자치단체, 또는 지방의 공동체가 사용할 수 있도록 쉽고 단순한 사용자 편의 시스템을 제공하고 있으며, 미국의 50개 본토의 주와 카운티(County) 이름으로 기상자료와 수문토양분류(Hydrologic Soil Group)을 인터넷 지리정보시스템을 이용하여 제공하고 있다. 본 연구는 지방자치단체 및 지역공동체의 실무자를 사용자로 수문/수질 평가 및 관리를 위한 시스템으로 유용하게 활용될 수 있을 것으로 사료된다.

• Applied Chemistry for Engineering
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• v.19 no.1
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• pp.51-58
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• 2008

A series of oleic acid esters containing mercaptobenzothiazole and dialkylenedithiocarbamate, which are potential environmentally friendly lubricating grease additives, were synthesized as 90% yield through several method such as nucleophilic substitution of dialkyl amine and carbon disulfide, reduction reaction, and condensation reaction. The structures of the additives were confirmed by $^1H$-NMR, FT-IR and EA analysis. The additives (1 wt%) were soluble in 100 N BO except C4-DTC-OE and soluble in soybean oil. The tribological properties as lubricating additives in 100 N BO were evaluated using 4-ball tester and the results showed as follows: Bz-thia-OE < C4-DTC-OE < Pyrro-DTC-OE < C8-DTC-OE. Whereas, the 4-ball anti-wear properties were not shown in soybean oil.

• Journal of Korean Society on Water Environment
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• v.25 no.2
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• pp.245-255
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• 2009

CN values are changed by various surface condition, which is cover type or treatment, hydrologic condition, or percent impervious area, even the same combination of land use and hydrologic soil group. In this study, CN parameters were regionalized for Nakdong River Basin by Long-Term Hydrologic Impact Assessment (L-THIA) coupled with SCE-UA, which is one of the global optimization technique. Six watersheds were selected for calibration (optimization) and periodic validation and two watersheds for spatical validation as ungauged watershed within Nakdong River Basin. Nash-Sutcliffe (NS) values were 0.66~0.86 for calibration, 0.68~0.91 for validation, and 0.60 and 0.85 for ungauged watersheds, respectively. Urban area for the selected watersheds covered high impervious area with 85% for residential area and 92% for commercial/industrial/transportation area. Hydrologic characteristics for crop area was similar to row crop with contoured treatment and poor hydrologic condition. For the forested area, hydrologic characteristics could be clearly distinguished from the leaf types of plant. Deciduous, coniferous, and mixed forest showed low, moderate, and high runoff rates by representing wood with fair and poor hydrologic condition, and wood-grass combination with fair hydrologic condition, respectively. CN parameters from this study could be strongly recommended to be used to simulate runoff for ungauged watershed.

• Bulletin of the Korean Chemical Society
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• v.14 no.6
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• pp.713-717
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• 1993

The crystal structure of the potassium salt of penicillin V has been studied by the X-ray crystallographic methods. Crystal data are as follows; potassium 3,3-dimethyl-7-oxo-6-phenoxyacetoamido-4-thia-1- azabicyclo[3.2.0]-heptane-2${\alpha}$-carboxylate, $K^+{\cdot}C_{16}H_{18}N_2O_5S^-$, $M_r$= 388.5, triclinic, Pl, a= 9.371 (1), b= 12.497 (2), c= 15.313 (2) ${\AA},\;{\alpha}= 93.74\;(2),\;{\beta}=99.32\;(1),\;{\gamma}=90.17\;(1)^{\circ},\;V=1765.7\;(2)\;{\AA}^3$, Z=4, $D_m=1.461\;gcm^{-1},\;{\lambda}(Cu\;K{\alpha})=1.5418\;{\AA},\;{\mu}=40.1\;cm^{-1}$, F(000)=808, T=296 K. The structure was solved by the heavy atom and difference Fourier methods with intensity data measured on an automated four-circle diffractometer. The structure was refined by the full-matrix least-squares method to a final R= 0.081 for 3563 observed $[I_0{\geq}2{\sigam}(I_0)]$ reflections. The four independent molecules assume different overall conformations with systematically different orientations of the phenyl groups although the penam moieties have the same closed conformations. There are intramolecular hydrogen bonds between the exocyclic amide nitrogen and phenoxy oxygen atoms. The penam moiety is conformationally very restricted although the carboxyl and exocyclic amide groups apparently have certain rotational degrees of freedom but the phenyl group is flexible about the ether bond despite the presence of the intramolecular N-H${\cdots}$O hydrogen bond. There are complicated pseudo symmetric relationships in the crystal lattice. The penam moieties are related by pseudo 20.5 screw axes and the phenyl groups by pseudo centers of symmetry. The potassium ions, related by both pseudo symmetries, form an infinite zigzag planar chain parallel to the b axis. Each potassium ion is coordinated to seven oxygen atoms in a severely distorted pentagonal bipyramid configuration, forming the infinite hydrophilic channels which in turn form the molecular stacks. Between these stacks, there are only lipophilic interactions involving the phenyl groups.