• Title/Summary/Keyword: Thermoplastic materials

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Radial displacement of clinical target volume in node negative head and neck cancer

  • Jeon, Wan;Wu, Hong-Gyun;Song, Sang-Hyuk;Kim, Jung-In
    • Radiation Oncology Journal
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    • v.30 no.1
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    • pp.36-42
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    • 2012
  • Purpose: To evaluate the radial displacement of clinical target volume in the patients with node negative head and neck (H&N) cancer and to quantify the relative positional changes compared to that of normal healthy volunteers. Materials and Methods: Three node-negative H&N cancer patients and five healthy volunteers were enrolled in this study. For setup accuracy, neck thermoplastic masks and laser alignment were used in each of the acquired computed tomography (CT) images. Both groups had total three sequential CT images in every two weeks. The lymph node (LN) level of the neck was delineated based on the Radiation Therapy Oncology Group (RTOG) consensus guideline by one physician. We use the second cervical vertebra body as a reference point to match each CT image set. Each of the sequential CT images and delineated neck LN levels were fused with the primary image, then maximal radial displacement was measured at 1.5 cm intervals from skull base (SB) to caudal margin of LN level V, and the volume differences at each node level were quantified. Results: The mean radial displacements were 2.26 (${\pm}1.03$) mm in the control group and 3.05 (${\pm}1.97$) in the H&N cancer patients. There was a statistically significant difference between the groups in terms of the mean radial displacement (p = 0.03). In addition, the mean radial displacement increased with the distance from SB. As for the mean volume differences, there was no statistical significance between the two groups. Conclusion: This study suggests that a more generous radial margin should be applied to the lower part of the neck LN for better clinical target coverage and dose delivery.

High Proton Conductivity Crosslinked Sulfonated Polyimide Membranes (높은 수소이온전도성을 가진 가교술폰화폴리이미드막)

  • Lee, Chang-Hyun;Park, Chi-Hoon;Park, Ho-Bum;Lee, Young-Moo
    • Proceedings of the Membrane Society of Korea Conference
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    • 2003.11a
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    • pp.61-63
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    • 2003
  • A major research objective related to proton exchange membrane(PEM) for DMFC is to achieve high proton conductivity over 10$^{-2}$ S/cm, high hydrolytic stability and low methanol permeability with low cost base materials. for the purpose, a lot of thermoplastic polymers such as polysulfones, polyethersulfone, polyetherketones, polyimides, polyoxadiazole, polyphosphazene and polybenzimidazol have been investigated. Amongst those polymers, polyimides have been suggested as a potential PEM due to their excellent thermal, chemical stability and good mechanical properties. Generally, polyimides are synthesized by polycondensation with numerious diamines and dianhydriedes. In our study, polyimide was prepared using non-sulfonated diamine, sulfonated diamine directly synthesized by fuming sulfuric acid, and naphthalenic dianhydride to improve the hydrolysis stability under acidic condition. Through monomer sulfonation-subsequent polymerization method, the high proton conducting capability and the desired sulfonation level were effectively controlled at the same time. To reduce severe methanol transport through the membrane, the chemical crosslinking among polymer chains was introduced using various crosslinking agents with different chain lengths. The crosslinked sulfonated polyimide membranes showed high proton conductivity up to 8.09$\times$10$^{-2}$ S/cm and from crosslinking effect methanol transport through the membranes was considerably reduced as compared with unmodified membranes. For increase of chain length of crosslinker, methanol permeability was adversely reduced to 10$^{-8}$ $\textrm{cm}^2$/s due to decrease of IEC and increase of crosslinking desity.

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Isocenter Reproducibility with Mask Fixation System in Stereotactic Radiosurgery (정위 마스크 시스템을 사용한 방사선수술시 회전중심점의 재현성)

  • 이동준;손문준;이기택;최찬영;황금철;황충진
    • Progress in Medical Physics
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    • v.13 no.3
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    • pp.135-138
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    • 2002
  • Fractionated stereotactic radiosurguy (FSRS) requires precise and reproducible patient set up. For these reasons non-invasive mask fixation methods have been used in Linac based FSRS. In this study, we measured and assessed the isocenter reproducibility using a commercial head mask fixation system based on thermoplastic materials. For the verification and the measurement of isocenter deviation a special acrylic brain phantom was designed. The designed phantom has 22 vertical rods and each rod has different lengths. At the end of the 8 rods, the monochromic film is attached and irradiated due to planned target position. Deviations of isocenter were measured separately for each direction. The mean deviation showed 0.4 mm in longitudinal direction, 0.1 mm in the lateral direction, 0.1 mm in the anterior-posterior direction of the treatment couch. The data demonstrates the high accuracy and reproducibility. This study reinforces previous literature published.

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Development of two-component polyurethane metering system for in-mold coating (인몰드 코팅을 위한 2액형 폴리우레탄 공급장치 개발)

  • Seo, Bong-Hyun;Lee, Ho-Sang
    • Design & Manufacturing
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    • v.10 no.2
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    • pp.18-23
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    • 2016
  • Injection molded thermoplastic parts may need to be coated to facilitate paint adhesion, or to satisfy other surface property requirements, such as appearance, durability, and weather resistance. In this paper, a two-component polyurethane metering system was developed for the simultaneous injection and surface coating of a plastic substrate. The system was composed of storage tanks, feed pumps, axial piston pumps, mixing head. The tank was designed to be double-jacket structured and fabricated for polyol and isocyanate, respectively. A temperature chamber was used to maintain the material temperature to be $80^{\circ}C$ during flowing from storage tank to mixing head. Inside the chamber, feed pump, low pressure filter, high pressure pump, high pressure filter, pressure sensor, flow meter were installed. A mixing head of L-type was used for homogeneous mixing of polyol and isocyanate. Inside the mixing head, a cartridge heater and a temperature sensor were installed to control the temperature of the materials. The flow rate of axial-piston pump was controlled by using closed-loop feedback control algorithm. The input flow-rates were compared with the measured values. The output error was 6.7% for open-loop control, whereas the error was below 2.2% for closed-loop control. In addition, the pressure generated through mixing-head nozzle increased with increasing flow rate. It was found that the pressure drop between metering pump and mixing-head nozzle was almost 10 bar.

Numerical and Experimental Investigation on Impact Performance of Fiber Metal Laminates Based on Thermoplastic Composites (열가소성 복합재료를 기반한 섬유금속적층판의 충격 거동에 관한 실험 및 수치적 연구)

  • Lee, Byoung-Eon;Kang, Dong-Sik;Park, Eu-Tteum;Kim, Jeong;Kang, Beom-Soo;Song, Woo-Jin
    • Transactions of the Korean Society of Automotive Engineers
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    • v.24 no.5
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    • pp.566-574
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    • 2016
  • Fiber metal laminates, which are hybrid materials consisting of metal sheets and composite layers, have contributed to aerospace and automotive industries due to their reduced weight and improved damage tolerance characteristics. In this study, the impact performance of the laminates, which are comprised of a self-reinforced polypropylene and two aluminum sheets, and the pure aluminum alloy sheet material were investigated experimentally via numerical simulation. In order to compare the impact performance, the laminates and aluminum alloy were examined by assessing the impact force, energy time histories, and specific energy absorption. ABAQUS is a commercial software that is used to simulate the actual drop-weight tests. Based on this study, it is noted that the impact performance of the laminates was superior to that of the aluminum alloy. In addition, a good agreement between the experimental and numerical results can be achieved when the impact force and energy time histories from the experiments and the numerical simulations are compared.

Effect of the Calcium Nitrate Solution Treatment on the Tensile, Bending, and Shear Properties of Silk Fabric

  • Park, Su-Zin;Kang, Ji-Young;Seol, Da-Won;Yang, Hye-Min;Lee, Ji-Min;Ahn, Ye-Ji;Han, Seo-Young;Kim, Jong-Jun
    • Journal of Fashion Business
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    • v.14 no.6
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    • pp.39-52
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    • 2010
  • Interests in creating three-dimensionally designed fabric materials are growing rapidly in the sectors of the fashionable textiles with the creativity, new functions, and aesthetics. A number of finishing methods have been developed and proposed to add or create new functions and designs for silk fabrics. Due to the strong hydrogen bonds between the molecules of silk fibroins, the thermal treatment methods used in thermoplastic fiber processing, which can easily deform the synthetic filament fabrics to endow three-dimensional appearance to the fabrics, are not applicable to the silk fabric treatment. In order to modify the fine structure of silk fiber, neutral salt solution treatment methods have been suggested. In this study, the effect of the calcium nitrate solution on the physical and mechanical properties of silk fabrics was investigated by using the KES(Kawabata Evaluation System) equipment. Based on these findings, relationships between parameters, for example, the thickness and the compressional energy, the thickness and the compressional linearity, and the air permeability and the pore area statistical analysis were investigated. The relationships between the process parameters such as treatment temperature/time and the resulting fabric property parameters were also analyzed by using several SAS procedures.

Enhancing the oxidative stabilization of isotropic pitch precursors prepared through the co-carbonization of ethylene bottom oil and polyvinyl chloride

  • Liu, Jinchang;Shimanoe, Hiroki;Nakabayashi, Koji;Miyawaki, Jin;Choi, Jong-Eun;Jeon, Young-Pyo;Yoon, Seong-Ho
    • Journal of Industrial and Engineering Chemistry
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    • v.67
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    • pp.358-364
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    • 2018
  • An isotropic pitch precursor for fabricating carbon fibres was prepared by co-carbonization of ethylene bottom oil(EBO) and polyvinyl chloride (PVC). Various pre-treatments of EBO and PVC, and a high heating rate of $3^{\circ}C/min$ with no holding time, were evaluated for their effects on the oxidative stabilization process and the mechanical stability of the resulting fibres. Our stabilization process enhanced the volatilization, oxidative reaction and decomposition properties of the precursor pitch, while the addition of PVC both decreased the onset time and accelerated the oxidative reaction. Aliphatic carbon groups played a critical role in stabilization. Microstructural characterization indicated that these were first oxidised to carbon-oxygen single bonds and then converted to carbon-oxygen double bonds. Due to the higher heating rate and lack of a holding step during processing,the resulting thermoplastic fibers did not completely convert to thermoset materials, allowing partially melted, adjacent fibres to fuse. Fiber surfaces were smooth and homogeneous. Of the various methods evaluated herein, carbon fibers derived from pressure-treated EBO and PVC exhibited the highest tensile strength. This work shows that enhancing the naphthenic component of a pitch precursor through the co-carbonization of pre-treated EBO with PVC improves the oxidative properties of the resulting carbon fibers.

Analysis of Changes in Temperature and Humidity by Material Combination Using 3D Printing (3D 프린팅을 활용한 재료조합에 따른 온습도 변화 분석)

  • Lee, Heeran;Kim, Soyoung;Lee, Yejin;Lee, Okkyung
    • Fashion & Textile Research Journal
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    • v.24 no.1
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    • pp.127-137
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    • 2022
  • Recently, various clothing items are being developed using 3D printing technology, but comfort has become an issue while wearing them for a long time. Therefore, this study researched on how the temperature and humidity of the devices developed by 3D printing change depending on the material combination. Five types of material combinations (EVA foam, TPU density 10%, TPU density 30%, EVA foam+TPU density 10%, and EVA foam+TPU density 30%) were selected as variables, and the experiment was conducted for two different cases with and without a cover. All the ten types of samples were placed on the hot plate set at 36℃, and the surface temperature and humidity were measured at three different points for 10 minutes. As a result, the case with only TPU showed the greatest temperature change while the case with 100% EVA foam showed the least temperature change. The humidity of the surface layer gradually decreased with time for 100% EVA foam. For the case with TPU materials, the moisture was transferred to the surface layer at first, thereby increasing the humidity but then dropped significantly. Meanwhile, the cases with the cover on showed similar tendencies of change in both temperature and humidity where the overall temperature and humidity delivery were slow.

Evaluation of Mechanical Properties of Three-dimensional Printed Flexible Denture Resin according to Post-polymerization Conditions: A Pilot Study

  • Lee, Sang-Yub;Lim, Jung-Hwa;Shim, June-Sung;Kim, Jong-Eun
    • Journal of Korean Dental Science
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    • v.15 no.1
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    • pp.9-18
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    • 2022
  • Purpose: The purpose of this study was to evaluate whether three-dimensional (3D)-printed flexible denture resin has suitable mechanical properties for use as a thermoplastic denture base resin material. Materials and Methods: A total of 96 specimens were prepared using the 3D printed flexible denture resin (Flexible Denture). Specimens were designed in CAD software (Tinkercad) and printed through a digital light-processing 3D printer (Asiga MAX UV). Post-polymerization process was conducted according to air exposure or glycerin immersion at 35℃ or 60℃ and for 30 or 60 minutes. The maximum flexural strength, elastic modulus, 0.2% offset yield strength, and Vickers hardness of 3D-printed flexible denture resin were assessed. Result: The maximum flexural strength ranged from 64.46±2.03 to 84.25±4.32 MPa, the 0.2% offset yield strength ranged from 35.28±1.05 to 46.13±2.33 MPa, the elastic modulus ranged from 1,764.70±64.66 to 2,179.16±140.01 MPa, and the Vickers hardness ranged from 7.01±0.40 to 11.45±0.69 kg/mm2. Conclusion: Within the limits of the present study, the maximum flexural strength, 0.2% offset yield strength, elastic modulus, and Vickers hardness are sufficient for clinical use under the post-polymerization conditions of 60℃ at 60 minutes with or without glycerin precipitation.

A Study on the Development of Eco-friendly Materials Using EPDM Scrap : Functionalization of EPDM and PP (에틸렌-프로필렌 고무 스크랩을 이용한 친환경소재 개발에 관한 연구 : EPDM과 PP의 기능화)

  • Kim, Sub;Chung, Kyung-Ho
    • Clean Technology
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    • v.15 no.3
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    • pp.180-185
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    • 2009
  • The ethylene-propylene rubber (EPDM) scrap generated from automobile weatherstrip manufacturing process was used to make a thermoplastic elastomer through blending with polypropylene. The surface activated EPDM powder was obtained by the high temperature and shear pulverizer. The addition of surfactant resulted in more surface activated EPDM powder and the optimum loading amounts of surfactant was 1.5 phr. Maleic anhydride was grafted onto polypropylene by reactive blending to give functionalized polypropylene. The wetting property between EPDM scrap and polypropylene was improved by the addition of poly (ethylene-co-acrylic acid) as a compatibilizing agent. Poly(ethylene-co-acrylic acid) decreased the surface tension of polypropylene and thus would contribute to the wettability with EPDM powder.