• Title/Summary/Keyword: Thermoplastic Composite

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Thermogravimetric Analysis of Rice Husk Flour for a New Raw Material of Lignocellulosic Fiber-Thermoplastic Polymer Composites

  • Kim, Hyun-Joong;Eom, Young-Guen
    • Journal of the Korean Wood Science and Technology
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    • v.29 no.3
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    • pp.59-67
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    • 2001
  • Rice husk flours were analyzed by chemical composition and thermogravimetric methods in nitrogen atmosphere to discuss its feasibility as a raw material for manufacturing agricultural lignocellulosic fiber-thermoplastic polymer composite. It was revealed in the chemical composition analysis that rice husk flour was composed of moisture, 5.0%; lignin, 21.6%; holocellulose, 60.8%; ash, 12.6%. In the thermogravimetric analysis (TGA), thermal decomposition behavior of rice husk flour from room temperature to $350^{\circ}C$ was similar to that of wood flour, but rice husk flour was more thermally stable from 350 to $800^{\circ}C$ than wood flour because of higher silica content in the rice husk flour and smaller particle size of rice husk flour. The activation energy of thermal decomposition was evaluated using Flynn & Wall expression. As the thermal decomposition proceeded in rice husk flour, the activation energy of thermal decomposition appeared almost constant up to ${\alpha}=0.25$, but thereafter increased. Activation energy of thermal decomposition in wood flour, however, decreased steeply up to ${\alpha}=0.3$, but thereafter remained almost constant. From the results, rice husk flour was thought be a substitute for wood flour in manufacturing agricultural lignocellulosic fiber-thermoplastic polymer composite in the aspect of thermal decomposition.

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Effect of Cork Extract on the Mechanical Property of Thermoplastic Polyurethane

  • Taehoon Oh;Seung-Hyun Cho;Bumyong Yoon;Hyejung Yoon;Jonghwan Suhr
    • Composites Research
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    • v.36 no.2
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    • pp.86-91
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    • 2023
  • Thermoplastic polyurethane (TPU) is a material whose mechanical properties change according to the phase separation of its unique internal microstructure and is therefore used in various industries. Use of TPU as composites helps in improving the desirable characteristics and properties in accordance with usage. Eco-friendly fillers one of the fillers are on the rise and those are mostly used for reinforcing role. Suberin, which can be extracted from cork, is the main component of cork. It is known to serve high damping property of elastomer composite. The original chemical structure of Suberin is an aliphatic polyester aggregate. In this research, Suberin is obtained after depolymerization into an oligomer having 2 or 3 ester bonds through alkaline hydrolysis. The extracted suberin was added to the matrix which is thermoplastic polyurethane as an eco-friendly filler for improving vibration damping property. As a result, when 10 wt% of suberin was added into thermoplastic polyurethane the existing trade-off relationship was overcome. And it is attained the elastic modulus and damping factor at room temperature improving 92 and 59%, respectively, compared to the original matrix. Those results are from the interaction between the microstructure of TPU and suberin.

Development of Thermoplastic Carbon Composite Bipolar Plates for High-temperature PEM Fuel Cells (고온 양성자 교환막 연료전지용 열가소성 탄소 복합재료 분리판 개발)

  • Lim, Jun Woo;Kim, Minkook;Lee, Dai Gil
    • Composites Research
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    • v.29 no.5
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    • pp.243-248
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    • 2016
  • Although thermoset carbon fiber composite bipolar plates not only have high mechanical properties but also high corrosion resistance in acid environment, high manufacturing cost and low bulk electrical conductivity are the biggest obstacle to overcome. In this research, thermoplastic polymer is employed for the matrix of carbon composite bipolar plate to increase both the manufacturing productivity and bulk electric conductivity of the bipolar plate. In order to increase the electrical conductivity and strength, plain type carbon fabric rather than chopped or unidirectional fibers is used. Also nano particles are embedded in the thermoplastic matrix to increase the bulk resistance of the bipolar plate. The area specific resistance and the mechanical strength of the developed bipolar plate are measured with respect to the environmental temperature and stack compaction pressure.

Comparative Evaluation of Manufacturing Properties of Carbon Fiber Reinforced Thermoplastic Polymer (CFRTP) according to Nanofiller Type (나노필러 종류에 따른 열가소성 탄소 섬유강화 복합재료의 제작 물성 비교 평가)

  • Jun Ha Park;Soon Ho Yoon;Minkook Kim
    • Composites Research
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    • v.37 no.3
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    • pp.186-189
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    • 2024
  • This study compared and evaluated the mechanical properties of carbon fiber reinforced thermoplastic polymer (CFRTP) mixed with nanofillers. After mixing various nanofillers such as Multi-wall carbon nanotube (MWCNT), Silicon oxide, Core shell rubber, and Aramid nanofiber with Polyamide 6 (PA6) resin, this is used as a matrix to create a carbon fiber reinforced composite material (CFRP) was manufactured and its physical properties were measured. Depending on the type and mixing ratio of nanofiller, tensile strength, inter-laminar shear strength (ILSS), and Izod impact strength were measured. In terms of tensile strength and impact strength, the highest values were obtained when mixing core shell rubber, however the ILSS was optimal when mixing less than 1 wt.% of silicon oxide.

Physical Property of Carbon Fiber Reinforced Thermoplastic Polymer based Composites by Repeating Processing of PP Composition (PP 복합 조성물의 반복 가공에 의한 열가소성 폴리머 탄소섬유 강화 복합재료의 물리적 특성 변화 연구)

  • Jin-Woo Lee;Jae-Young Lee;Seoung-Bo Shin;Jae-Hyung Park;Hyun-Ju Park;Kyung-Hun Oh;Jin-Hyuk Huh;Yun-Hae Kim;Ji-Eun Lee
    • Composites Research
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    • v.37 no.2
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    • pp.68-75
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    • 2024
  • Polypropylene (PP), a thermoplastic resin with excellent mechanical, thermal, chemical, and water resistance properties, has been attracting attention due to its economic efficiency and recyclability. However, repeated processing of thermoplastic resins can lead to property degradation, and the point at which quality degradation occurs varies depending on the processing conditions. In this study, we evaluated the performance changes of composite materials with repeated processing by blending PP resin with various additives and conducting extrusion and injection processes repeatedly. In addition, we evaluated the mechanical properties of composite materials to evaluate the effect of MFI value change during repeated processing on fiber impregnation in composite material processing.

Impact Simulation of Automotive GMT Bumper (자동차용 유리섬유강화 매트 수지(GMT) 범퍼의 충돌성능 평가 수치모사)

  • 백승훈;문종근;정우식;김승조
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2003.10a
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    • pp.137-140
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    • 2003
  • Impact of Automotive GMT(Glassfiber reinforced Mat Thermoplastic) Bumper for '5Mhp Barrier Test'was simulated using ls-dyna. The FE model consists of foam which is energy absorber, bumper beam and stay etc. Bumper intrusion and deflection was compared with the experimental results. Effects of uncertainty of material property and deviation of impact velocity were considered and results were compared with those of base design. Effects of number of integration points through th thickness was also investigated.

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Effect of temperature and blank holder force on non-isothermal stamp forming of a self-reinforced composite

  • Kalyanasundaram, Shankar;Venkatesan, Sudharshan
    • Advances in aircraft and spacecraft science
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    • v.3 no.1
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    • pp.29-43
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    • 2016
  • Composite materials are rapidly gaining popularity as an alternative to metals for structural and load bearing applications in the aerospace, automotive, alternate energy and consumer industries. With the advent of thermoplastic composites and advances in recycling technologies, fully recyclable composites are gaining ground over traditional thermoset composites. Stamp forming as an alternative processing technique for sheet products has proven to be effective in allowing the fast manufacturing rates required for mass production of components. This study investigates the feasibility of using the stamp forming technique for the processing of thermoplastic, recyclable composite materials. The material system used in this study is a self-reinforced polypropylene composite material (Curv$^{(R)}$). The investigation includes a detailed experimental study based on strain measurements using a non-contact optical measurement system in conjunction with stamping equipment to record and measure the formability of the thermoplastic composites in real time. A Design of Experiments (DOE) methodology was adopted to elucidate the effect of process parameters that included blank holder force, pre heat temperature and feed rate on stamp forming. DOE analyses indicate that feed rate had negligible influence on the strain evolution during stamp forming and blank holder force and preheat temperature had significant effect on strain evolution during forming.

Characterization and 3D Analysis of PETG/POE Thermoplastic Composites (PETG/POE 열가소성 복합재료의 특성평가 및 전산해석)

  • Yu, Seong-Hun;Lee, Jong-Hyuk;Sim, Ji-Hyun
    • Composites Research
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    • v.32 no.6
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    • pp.360-367
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    • 2019
  • In order to apply thermoplastic composites using PETG resin to various industrial fields such as bicycle frames and industrial parts, it is necessary to verify the impact resistance, durability, mechanical properties and 3D analysis of the manufactured composite materials. To improve the mechanical properties, durability and impact resistance of PETG resin, an amorphous resin, in this study, compound and injection molding process were carried out enhanced various weight percent POE(polyolefin elastomer). The thermal and mechanical properties of the thermoplastic composites, and the charpy impact strength, The analysis was performed to evaluate the characteristics according to weight percent of POE. Charpy impact strength test was conducted to analyze the impact characteristics, and the fracture section was analyzed after the impact strength test. In the case of POE material-added thermoplastic composites, thermal and mechanical properties tend to decrease, but workability and impact resistance tend to be superior to those of PETG materials.

Physical Properties of Flame Retardant Particulate Reinforced Thermoplastic Polymer Composites for Cold-Resistant Cable (내한성 케이블 적용을 위한 난연 입자 강화 열가소성 고분자복합재료의 기계적 특성평가)

  • Lee, Jinwoo;Shim, Seung Bo;Park, Jae Hyung;Lee, Ji Eun
    • Composites Research
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    • v.35 no.5
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    • pp.309-316
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    • 2022
  • The demand for cold-resistant cable material is increasing due to the rapid increase in the development of devices that operate in a low temperature environment. Cold tolerance of a thermoplastic polymer largely depends on the type and content of about 20 or more additives used to make the polymer. The phenomenon of polymer hardening at low temperature can be classified into hardening by simple temperature effect, embrittlement at the glass transition temperature, and hardening by crystallization of polymers that tend to crystallize. In this study, a thermoplastic polymer having a low glass transition temperature, a flame retardant, and an additive were mixed to evaluate the mechanical properties of a thermoplastic polymer composite material for electric wires. It has been confirmed that mechanical properties and processability are determined depending on the additives and compatibilizers added, and this study is considered to be useful as basic data for optimization to meet the performance requirements of wires developed for low-temperature use.