• Proceedings of the Korean Society of Propulsion Engineers Conference
• /
• 2010.11a
• /
• pp.495-498
• /
• 2010

This test cell is developed to the institutes or laboratories research and study gas turbine engine for academic purpose with this test data to provide the fundamentals of operational mechanism and structural configuration, and further to verify thermodynamic calculation The test cell is installed to monitor and compare real-time data with reference engine model performance simulation data. using by NI DAQ(Data acquisition)device and LabVIEW program based on 80 lbf-micro turbojet engine.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.28 no.11
• /
• pp.1302-1314
• /
• 2004

Turbulent heat transfer to $CO_2$ at supercritical pressure flowing in vertical tubes is investigated using direct numerical simulation (DNS). A conservative space-time discretization scheme for variable-density flows at low Mach numbers is adopted in the present study to treat steep variations of fluid properties at supercritical pressure just above the thermodynamic critical point. The fluid properties at these conditions are obtained using PROPATH and used in the form of tables in the simulations. The buoyancy influence induced by strong variation of density across the pseudo-critical temperature proved to play a major role in turbulent heat transfer at supercritical state. Depending on the degree of buoyancy influence, turbulent heat transfer may be enhanced or significantly deteriorated, resulting in local hot spots along the heated surface. Based on the results of the present DNS combined with theoretical considerations, the physical mechanism of this local heat transfer deterioration is elucidated.

• The Journal of Natural Sciences
• /
• v.10 no.1
• /
• pp.1-7
• /
• 1998

A Lennard-Jones fluid layer adsorbed on a smooth solid surface was studied at coverages $\theta$ ~ 0.8 to 1.8 on an isotherm by performing intensive grand canonical Monte Carlo simulations. The results clearly show a picture of two-step melting process which used to be observed in recent thermodynamic measurements of argon monolayer melting on graphite. The observed melting process consist of an abrupt density change followed by a gradual transition. Snapshots of monolayer configurations indicate that the creation and dissociation of a dislocation pair are involved in the melting mechanism. Taking the effect of system size into account, it is suggested that, while the abrupt density change may be not related to the theory of Kosterlitz, Thouless, Halperin, Nelson, and Young (KTHNY), the second gradual transition is probably a KTHNY-type melting transition.

• Bulletin of the Korean Chemical Society
• /
• v.15 no.1
• /
• pp.33-36
• /
• 1994

The x values of nonstoichiometric chemical formula, $Tb_4O_{7-{\delta}}\;or\;TbO_{1.5+x}$, have been determined in temperature range from 600$^{\circ}$C to 1000$^{\circ}$C under oxygen partial pressure of 2 ${\times}$ 10$^{-1}$ to 1 ${\times}$ 10$^{-5}$ atm by using quartz microbalance. The x values varied from 0.0478 to 0.1964 in the above conditions. The enthalpy of formation for x' in TbO$_{1.5+(0.25-xo-x')}$, ${\delta}H_f$, was 4.93-3.40 kcal mol$^{-1}$ and the oxygen partial pressure dependence was -1/8.80∼-1/11.8 under these conditions. The electrical conductivity of the $TbO_{1.5+x}$ was measured under the same conditions and the values varied from about 10$^{-3}$ to 10$^{-6}\;{\Omega}^{-1}cm^{-1}$ within semiconductor range. The activation energies for the conduction increase with oxygen partial pressure from 0.83 to 0.89 eV under the above conditions. The l/n values obtained from the oxygen pressure dependence of the conductivity are 1/4.4-1/5.2. The conduction mechanism, defect structure, and other physical properties of the oxides are dicussed with the x values, the electrical conductivity values, and the thermodynamic data.

• Proceedings of the Korean Society of Propulsion Engineers Conference
• /
• 2008.11a
• /
• pp.31-35
• /
• 2008

This test cell is developed to provide the fundamentals of operational mechanism and structural configuration, and further to verify thermodynamic calculation with this test data to the institutes or laboratories research and study gas turbine engine for academic purpose. The test cell is installed to monitor and collect real-time data as to temperature, pressure, thrust, fuel flow, and air flow etc. using by NI DAQ(Data acquisition)device and LabVIEW program based on 30lbf-micro turbojet engine.

• Journal of The Korean Astronomical Society
• /
• v.55 no.6
• /
• pp.215-220
• /
• 2022

To seek an atmospheric heating mechanism operating on the Sun we investigated a heating source generated by a downflow, both of which may arise in a magnetic loop dynamically formed on the Sun via flux emergence. Since an observation shows that the illumination of evolving magnetic loops under the dynamic formation occurs sporadically and intermittently, we performed a magnetohydrodynamic simulation of flux emergence to obtain a high-cadence simulated data, where temperature enhancement was identified at the footpoint of an evolving magnetic loop. Unlike a rigid magnetic loop with a confined flow in it, the evolving loop in a low plasma β atmosphere is subjected to local compression by the magnetic field surrounding the loop, which drives a strong supersonic downflow generating an effective footpoint heating source in it. This may introduce an energy conversion system to the magnetized atmosphere of the Sun, in which the free magnetic energy causing the compression via Lorentz force is converted to the flow energy, and eventually reduced to the thermal energy. Dynamic and thermodynamic states involved in the system are explained.

• Applied Biological Chemistry
• /
• v.40 no.1
• /
• pp.53-57
• /
• 1997

The rate of hydrolysis of insecticidal 1-(6-chloro-3-pyridylmethyl) -2-nitro-iminoimidazolidine (common name; imidacloprid) have been investigated in 15%(v/v) aqueous dioxane at $45^{\circ}C$. From the kinetics and non-kinetics data such as pH-effect, solvent effect(m=0.04, n=0.30 IT m<${\Delta}H^{\neq}=16.14kcal{\cdot}mol^{-1}\;&\;{\Delta}S^{\neq}=-0.03e.u.$), rate equation ($k_{obs.}=4.56{\times}10^{-3}[OH^-]$) and analysis of hydrolysis product, 1-(6-chloro-3-pyridylmethyl-2)-imidazolidinon, the hydrolysis mechanism of imidacloprid is proposed that the specific base catalyzed hydrolysis($K_{OH^-}$) through nucleophilic addition-elimination ($Ad_N-E$) mechanism proceed via intermediate, 1-(6-chloro-3- pyridylmethyl)-2-hydroxy-2-imidazolidinylisonitraminate (I) and ${\beta}$-3-(6-chloro-3-pyridylmethyl)aminoethyl-1-nitrourea(III). And the half-life(t1/2) of hydrolytic degradation at pH 8.0 and $45^{\circ}C$ was about 4.5 months.

• Applied Biological Chemistry
• /
• v.38 no.5
• /
• pp.455-462
• /
• 1995

The new six herbicidal N-[(pyrimidin-2-yl)aminocarbonyl]-2-substituted-6-(1-hydroxy-2-fluoroethyl)benzenesulfonamide derivatives(S) were synthesized and rate constants for the hydrolysis of thier in the range of pH $1.0{\sim}10.0$ have been studied in 15%(v/v) aqueous acetonitrile solution at $45^{\circ}C$. From the basis of the results, pH-effect, solvent effect, ortho-substituent effect, thermodynamic parameters(${\Delta}H^{\neq}$ & ${\Delta}S^{\neq}$), pKa constant(4.80), rate equation, analysis of hydrolysis products(2-(1-hydroxy-2-fluoroethyl)benzenesulfonamide & 4,6-dimethoxyaminopyrimidine), it may be concluded that the general acid catalyzed hydrolysis through $A-S_E2$ mechanism and specific acid catalyzed hydrolysis through A-2 type(or $A_{AC}2$) mechanism proceeds via conjugate acid($SH^+$) and tetrahedral intermediate(I) below pH 8.0, whereas, above pH 9.0, the general base catalyzed hydrolysis by water molecules(B) through $(E_1)_{anion}$ mechanism proceeds via conjugate base(CB). In the range between $pH\;7.0{\sim}pH\;9.0$, these two reactions occur competitively.

• Journal of Acupuncture Research
• /
• v.21 no.1
• /
• pp.119-135
• /
• 2004

Objective: The purpose of this study is to investigate the mechanism and effect of moxibustion with salt objectively, to be used as the quantitative data through the measurement of temperature, and to grasp the thermodynamic characteristics of moxibustion with salt. Methods: We have selected of the moxibustion with salt of indirect moxibustion. We make a comparative study of the thermodynamic characteristics of moxibustion with salt as a kind of the 4 salt. We examined combustion times, temperatures, temperature gradients in each period during a combustion of moxa. Results: 1. We make out that it is not significantly change the time of thermal conduction of moxibustion with salt as a kind of 4 salt. 2. The heating period of Refined Salt was long and that of Sun-dried Salt was a short time respectively. The heating period of maximum tamperature is high Sun-dried Salt, Mechanical Salt and Refined Salt orderly. Maximun heating speed in the heating period was $0.151{\sim}0.184^{\circ}C/sec$ and at the same tendency of the maximum temperature in the heating period. 3. The retaining period was shorter than the heating period respectively, that is 15~24% of the combustion time of in the heating period. We make out that it is not significantly different the time of the retaining period as a kind of 4 salt. The mean temperature of retaining period was $43.2{\sim}48.1^{\circ}C$, that was extraordinarily high temperature. 4. We make out that it is not significantly different the time of the cooling period as a kind of 4 salt. The cooling period was measured 223~233sec. Beacuse the same density and size of moxa combustion was made an experiment. 5. The effective combustion time of Refined Salt is longer(259sec) than that of Sun-dried Salt(173sec). It is significantly different the time of the combustion time as a kind of 4 salt. 6. It is significantly different the Sample deviation of the combustion time as a kind of 4 salt because of the water content of the 4 salt individually. Conclusions: As the base on this study, we obtained the conclusion as the follows. The salt of moxibustion with salt was fitted for Sun-dried Salt due to making to Mechanical Salt recently. The Refined Salt is composition rate to another and small size comparatively. So It was fitted for the salt of moxibustion with salt. It is necessary to study continuously about the more suitable moxibustion with salt and quantitative analysis about the moxibustion with salt.

• Applied Chemistry for Engineering
• /
• v.8 no.5
• /
• pp.777-783
• /
• 1997

$TiO_2$ powders were synthesized via hydrolysis reaction of titanium n-propoxide in n-propanol solvent and the reaction rates were studied by use of UV-vis spectroscopic method. Concentration of water, reaction temperature, reaction time and acid-base effects of the solution were investigated to determine the optimum conditions for $TiO_2$ powder synthesis. The reaction were controlled to proceed to pseudo-first orders reaction in the presence of excess water in n-propanol solvent. The rate constants which varied with temperature and concentration of water were calculated by Guggenheim method. Reaction using $D_2O$ was also carried out to determine the catalytic character of water. $TiO_2$ powders were synthesized only in the neutral and basic solution and those were almost spheric forms having average particle size of $0.4-0.7{\mu}m$ diameter. Particle size decreased with increasing concentration of water and reaction temperature, however, increased with increasing reaction time. Associative $S_N2$ mechanism for the hydrolysis was proposed from the data of n-value in the transition state and thermodynamic parameter. $D_2O$ solvent isotope effect showed that $H_2O$ molecules reacted as nucleophilic catalysis.