• 제목/요약/키워드: Thermodynamic function

검색결과 167건 처리시간 0.021초

전산수치해석을 통한 가스차단기의 차단성능 평가 (Evalution of Current interrupting capability in GCB by computational approach)

  • 최영길;이광식
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2002년도 하계학술대회 논문집 C
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    • pp.1677-1681
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    • 2002
  • A computational approach of the arc quenching process in GCB was developed. it is capable to calculates the thermodynamic quantities of the gas as a function of time taking into account of all spaces concerned with the arc quenching. Basically using so-called FLIC method, this program adoptes 'Simplified Enthalpy Arc Model', which is somewhat modified. And, to examine whether our works were done properly, it was simulated the whole process of the arc quenching that is based on self-flow generation phenomena/current interruption in a thermal expansion type circuit breaker. This program was verified by experiments, both showed fairly good agreement.

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이상 진단을 위한 왕복동식 펌프 모델링 (Reciprocating pump modeling for diagnosis)

  • 이종겸;채장범;이진우
    • 한국소음진동공학회:학술대회논문집
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    • 한국소음진동공학회 2014년도 추계학술대회 논문집
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    • pp.330-331
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    • 2014
  • A mathematical model is suggested for diagnosis on a reciprocating pump. To the end, kinematic, thermodynamic and fluidic analyses are carried out for a simplified reciprocating pump model. The pressure inside the cylinder is expressed as a function of the rotation angle of a crank axle. The mathematical model consists of one cylinder with suction and discharge valves and an accumulator. The effect of valve leakage on the discharge angle is investigated. The discharge angle difference between normal state and leakage state increases with the leakage extent.

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이성분 액체 혼합물의 통계열역학적 연구 (Transient State Theory of Significant Liquid Structure applied to Binary Mixture, Benzene-Cyclohexane)

  • 안운선
    • 대한화학회지
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    • 제10권3호
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    • pp.136-142
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    • 1966
  • 벤젠-시클로핵산 이성분 용액에다 Transient State Theory of Significant Liquid Structure를 확장 적용시켰다. 상태함을 구하고 이것으로부터 계의 전체압, 부분압, 몰부피 그리고 과량의 엔트로피와 같은 열역학적 양을 $303.15^{\circ},\;\313.15^{\circ}$$343.15^{\circ}K$에서 계산하였다. 이와 같이 구한 계산치들은 실측치와 대단히 잘 맞았다.

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액체구조에 관한 천이상태이론의 싸이클로 핵산에 대한 적용 (Transient State Theory of Significant Liquid Structure applied to Cyclohexane)

  • 이해방;장세헌
    • 대한화학회지
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    • 제10권3호
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    • pp.129-132
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    • 1966
  • 싸이클로핵산의 분자는 액체상태에서 대부분이 chair form으로 되어 있음이 알려져 있다. 이 사실로 부터 싸이클로핵산의 액체는 Chair form 만으로 되어있다는 가정하에 액체구조의 천이상태이론을 적용시켜 상태함을 구하고 이로부터 싸이클로핵산의 몰부피, 증기압, 한계점, 증발엔트로피 및 압축률 등의 열역학적 량을 계산한 결과 측정치와 잘 맞는 값을 얻었다.

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Cobalt를 첨가한 $Cd_4GeS_6$ 단결정에서 Energy Gap의 온도의존성 및 열역학적 함수 추정 (Temperature Dependence of Energy Gap and Thermodynamic Function Properties of Coblt-doped $Cd_4GeS_6$Single Crystals)

  • 김덕태
    • 한국전기전자재료학회논문지
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    • 제11권9호
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    • pp.693-699
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    • 1998
  • In this work $Cd_4GeS_6:Co^{2+}$(0.5mole%) single crystals were grown by the chemical transporting reactiov(CTR) method using high purity(6N) elements. The grown single crystals crystallized in a monoclinic structure(space group Cc). The direct optical energy gap of this single crystals was found to be 2.445eV at 300K and the temperature dependence of optical energy gap was fitted well to Varshni equation. But at temperatures lower than 70K an anomalous temperature dependence of the optical energy gap was obtained. This anomalous temperature dependence accored well with the anomalous temperature dependence of the unit cell volume. Also, the entropy, enthalpy and heat capacity were deduced from the temperature dependence of optical energy gaps.

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단기통 4사이클 스파아크 점화기관 동력사이클의 시뮬레이션 (Simulation of a power cycle for a single-cylinder 4-stroke cycle spark ignition engine)

  • 조양수;유병철
    • 오토저널
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    • 제5권4호
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    • pp.47-61
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    • 1983
  • In this paper the simulation of a thermodynamic power cycle for a 4-stroke, single-cylinder, spark-ignition engine was studied. In this simulation the cylinder volume was restricted to two zones, a burnt and an unburnt zone, and the convective heat transfer from cylinder contents to surroundings was considered. The chemical species in burnt gas considered was 12 species including H$_{2}$O, H$_{2}$, OH, H, N$_{2}$, NO, N, CO$_{2}$, CO, $O_{2}$, O and Ar. Using this model, computer program for compression, ignition and expansion processes was composed and pressure, temperature and composition of cylinder gas at each crank angle were computed. The composition of CO$_{2}$, CO, $O_{2}$ in the burnt gas when exhaust valve opens, the maximum temperature, the maximum flame speed and the combustion duration were also computed as a function of equivalence ratio. The relation between burnt mass fraction and burnt volume fraction was also computed.

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화학수송법으로 성장한 $Cd_{4}GeSe_{6}$$Cd_{4}GeSe_{6}:Co$ 단결정에서 Energy Gap의 온도의존성 및 열역학함수 추정 (Temperature Dependence of Energy Gap and Thermodynamic Function Properties of Undoped and Co-doped $Cd_{4}GeSe_{6}$ Single Crystals by Chemical Transport Reaction Method)

  • 김덕태;김남오;최영일;김병철;김형곤;현승철;김병인;송찬일
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2002년도 제4회 영호남학술대회 논문집
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    • pp.31-36
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    • 2002
  • In this work $Cd_{4}GeSe_{6}$ and $Cd_{4}GeSe_{6}:Co^{2+}$ single crystals were grown by the chemical transport reaction method and the structure of $Cd_{4}GeSe_{6}$ and $Cd_{4}GeSe_{6}:Co$ single crystals were monoclinic structure. The temperature dependence of optical energy gap was fitted well to Varshni equation. Also, the entropy, enthalpy and heat capacity were deduced from the temperature dependence of optical energy gap.

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Application of Liquid Theory to Sodium-Ammonia Solution

  • Lee, Jong-Myung;Jhon, Mu-Shik
    • Bulletin of the Korean Chemical Society
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    • 제2권3호
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    • pp.90-96
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    • 1981
  • The significant structure theory of liquids has been successfully applied to the sodium ammonia solution. In applying the theory to sodium ammonia solution, we assumed there were four species in solution, i.e., sodium cation, solvated electron, triple ion, and free electron and equilibria existed between them. Based on these assumptions, we set up the model explaining the anomalous properties of sodium ammonia solution. The partition function for sodium ammonia solution is composed of the partition functions for the above four species and also for the Debye-Huckel excess free energy term. Agreements between calculated and experimental values of the thermodynamic quantities, such as molar volume, vapor pressure, partial molar enthalpy and entropy, and chemical potential as well as viscosity are quite satisfactory.

신경회로망을 이용한 증기표의 함수근사 (Function approximation of steam table using the neural networks)

  • 이태환;박진현
    • 한국정보통신학회논문지
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    • 제10권3호
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    • pp.459-466
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    • 2006
  • 열성능 평가를 위한 수치해석에서는 온도, 압력, 건도, 체적, 엔탈피, 엔트로피 등의 열역학적 성질들의 수치값이 필요하다. 그러나 이러한 성질들을 포함하고 있는 증기표를 그대로 사용할 수 없기 때문에, 효과적으로 모델링하여야 한다. 이러한 관점에서 함수근사 특성을 가진 신경회로망을 하나의 대안으로 검토하였다. 신경 회로망은 포화증기 영역과 과열증기 영역에 대해서 따로 구성하였다. 포화증기 영역에 대해서는 하나의 입력으로 7개의 출력을 얻을 수 있도록 하였으며, 각각 10개와 20개의 노드를 가진 은닉층을 구성 하였다. 과열증기 영역에 대해서는 2개의 입력으로 3개의 출력을 얻을 수 있도록 하였으며, 각각 15개와 25개의 노드를 가진 은닉층을 구성하였다. 제안된 모델은 온도, 엔탈피, 엔트로피의 백분율오차가 대부분 ${\pm}0.005%$, 압력이나 비체적의 백분율오차도 대부분 ${\pm}0.025%$ 범위 내로 수렴시킬 수 있었다. 이 성공적인 결과로부터 증기 표를 함수근사하는데 있어서 신경회로망이 아주 강력한 수단이 될 수 있음을 확인할 수 있었다.

Biosorption of uranium by Bacillus sp.FB12 isolated from the vicinity of a power plant

  • Xu, Xiaoping;He, Shengbin;Wang, Zhenshou;Zhou, Yang;Lan, Jing
    • Advances in environmental research
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    • 제2권3호
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    • pp.245-260
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    • 2013
  • Biosorption represents a technological innovation as well as a cost effective excellent remediation technology for cleaning up radionuclides from aqueous environment. In the present study, a bacteria strain FB12 with high adsorption rate of uranium ion was isolated from the vicinity of the nuclear power plant. It was tentatively identified as Bacillus sp.FB12 according to the 16S rDNA sequencing. Efforts were made to further improve the adsorption rate and genetic stability by UV irradiation and UV-LiCl cooperative mutagenesis. The improved strain named Bacillus sp.UV32 obtains excellent genetic stability and a high adsorption rate of 95.9%. The adsorption of uranium U (VI) by Bacillus sp.UV32 from aqueous solution was examined as a function of metal ion concentration, cell concentration, adsorption time, pH, temperature, and the presence of some foreign ions. The adsorption process of U (VI) was found to follow the pseudo-second-order kinetic equation. The adsorption isotherm study indicated that it preferably followed the Langmuir adsorption isotherm. The thermodynamic parameters values calculated clearly indicated that the adsorption process was feasible, spontaneous and endothermic in nature. These properties show that Bacillus sp.UV32 has potential application in the removal of uranium (VI) from the radioactive wastewater.