• The Korean Journal of Ceramics
• /
• 제7권1호
• /
• pp.11-15
• /
• 2001

A thermodynamic assessment for the ZrO$_2$-TiO$_2$ system has been conducted. An optimal thermodynamic data set for this system is evaluated by the CALPHAD(CALculation of PHAse Diagram) method applied to experimental phase diagram and thermodynamic data. The liquid is described by ionic liquid model with two sublattices. The solubilities of the solid phases, tetragonal ZrO$_2$ and TiO$_2$(rutile), were described by subregular substitutional model with one sublattice. Two compounds, ZrTiO$_4$ and ZrTi$_2$O$_6$, are modeled as stoichiometric compounds.

• 한국자동차공학회논문집
• /
• 제9권6호
• /
• pp.94-102
• /
• 2001

The thermodynamic second law analysis, which means available energy or exergy analysis, for the indicated performance of Otto cycle engine has been carried out. Each operating process of the engine is simplified and modeled into the thermodynamic cycle. The calculation of the lost work and exergy through each process has been done with the thermodynamic relations and experimental data. The experimental data were measured from the test of single cylinder Otto cycle engine which operated at 2500 rpm, WOT(Wide Open Throttle) and MBT(Minimum advanced spark timing for Best Torque) condition with different fuels: gasoline, methanol and mixture of butane-methanol called M90. Experimental data such as cylinder pressure, air and fuel flow rate, exhaust gas temperature, inlet gas temperature and etc. were used for the analysis. The proposed model and procedure of the analysis are verified through the comparison of the work done in the study with experimental results. The calculated results show that the greatest lost work is generated during combustion process. And the lost work during expansion, exhaust, compression and induction process follows in order.

• 플랜트 저널
• /
• 제17권1호
• /
• pp.50-57
• /
• 2021

수력학적 효율측정 방법만으로는 펌프시스템 부속장치들의 개별효율 및 펌프 자체효율을 명확하게 산출해내기 매우 어렵다. 이에 본 연구에서는 국내 최초로 지역난방 중온수용 펌프시스템에 최신 열역학적 펌프 효율측정방법을 도입, 수력학적 방법과의 효율 병행측정 결과를 검토하였고, 그 결과 기존 수력학적 펌프효율 측정방법만으로는 데이터 불확실성이 높은 반면, 열역학적 및 수력학적 방법 병행측정 데이터를 적용한 펌프 및 유체커플링 효율값은 상호보완적 역할수행에 의해 펌프성능 측정방법의 신뢰성 및 적정성이 검증되는 의미 있는 결과를 도출할 수 있었다. 또한, 지역난방시스템에 열역학적 펌프효율 측정방법을 적용한 결과, 최대 120 ℃ 고온 환경에도 불구, 매우 안정적인 데이터 측정 및 측정장비의 내구성이 검증되는 등 열역학적 측정방법의 신뢰성을 검증할 수 있었다.

• 한국태양에너지학회 논문집
• /
• 제23권4호
• /
• pp.45-54
• /
• 2003

For cooling of double effect absorption heat pump system of solar heating source, analysis of thermodynamic design data has been done to find the property of Libr-water + ethylene Glycol mixture for working fluid by computer simulation. Derived thermodynamic design data, enthalpy based coefficient of performance and flow ratio for possible combinations of operating temperature for water - LiBr and Ethylene Glycol mixture ($H_2O$ : CHO ratio 10:1 by mole) by computer simulation are done. The obtained results, COP and mass flow ratio of the water - lithium bromide - ethylene glycol system, are compared with data for the water-Libr pair solution.

• 한국태양에너지학회 논문집
• /
• 제22권4호
• /
• pp.51-61
• /
• 2002

Analysis of thermodynamic design data of double effect solar absorption heat pump system for heating has been done to find the property of Libr-water + ethylene Glycol mixture for working fluid by computer simulation. Derived thermodynamic design data. enthalpy based coefficient of performance and flow ratio for possible combinations of operating temperature for water - LiBr and Ethylene Glycol mixture (H2O: CHO ratio 10:1 by mole) by computer simulation. The obtained results, COP and mass flow ratio of the water-lithium bromide-ethylene glycol system, are compared with data for the water-Libr pair solution.

• Bulletin of the Korean Chemical Society
• /
• 제21권1호
• /
• pp.105-109
• /
• 2000

High-performance liquid chromatography is suitable for getting thermodynamic information about solute-solvent interactions. We used a squalane impregnated $C_{18}$ phase as a presumably bulk-like stationary phase to secure a simple partition mechanism for solute retention in reversed phase liquid chromatographic system. We measured retention data of some selected solutes (benzene, toluene, ethylbenzene, propylbenzene, butylbenzene, phenol, benzylalcohol, phenethylalcohol, benzylacetone, acetophenone, benzonitrile, benzylcyanide) at 25, 30, 35, 40, 45, and 50 $^{\circ}C$ in 30/70, 40/60, 50/50, 60/40 and 70/30 (v/v%) acetonitrile/water eluents. The van't Hoff plots were nicely linear, thus we calculated dependable thermodynamic values such as enthalpies and entropies of solute transfer from the mobile phase to the stationary phase based on more than four retention measurements on different days (or weeks). We found that the cavity formation effect was the major factor in solute distribution between the mobile and stationary phases in the system studied here. Our data were com-pared with some relevant literature data.

• 설비공학논문집
• /
• 제3권4호
• /
• pp.286-296
• /
• 1991

The thermodynamic properties of R134a, the prospective R12 alternative, have been computerized using Martin-Hou equation of state and the coefficients given by Willson-Basu. Several experimental results in literatures for PVT data, saturated vapor pressure, saturated liquid density are compared with the calculated results to investigate the accuracy. The average deviation (max. deviation) is 0.13% (0.25%) for saturated liquid density, 0.25% (0.8%) for PVT data. Thermodynamic properties, enthalpy, entropy are compared with the NIST's. The maximum percent difference is 3% for saturated liquid enthalpy, 1.5% for saturated vapor enthalpy, 4% saturated liquid entropy, and 0.7% for saturated vapor entropy. Correction of W-B's coefficients and inclusion of the sixth term of M-H EOS for improvement of accuracy are recommended. R134a and R12 are compared with respect to refrigeration performance. COP's are different from each other within 3%. Refrigeration effect of R134a is superior to that of R12 but refrigeration capacity of R134a is inferior to that of R12 because the volumetric efficiency of the system using R134a is lower than that of the system using R12.

• 방사성폐기물학회지
• /
• 제21권4호
• /
• pp.427-438
• /
• 2023

Thermodynamic sorption modeling can enhance confidence in assessing and demonstrating the radionuclide sorption phenomena onto various mineral adsorbents. In this work, Ca-montmorillonite was successfully purified from Bentonil-WRK bentonite by performing the sequential physical and chemical treatments, and its geochemical properties were characterized using X-ray diffraction, Brunauer-Emmett-Teller analysis, cesium-saturation method, and controlled continuous acid-base titration. Further, batch experiments were conducted to evaluate the adsorption properties of Cs(I) and Sr(II) onto the homoionic Ca-montmorillonite under ambient conditions, and the diffuse double layer model-based inverse analysis of sorption data was performed to establish the relevant surface reaction models and obtain corresponding thermodynamic constants. Two types of surface reactions were identified as responsible for the sorption of Cs(I) and Sr(II) onto Ca-montmorillonite: cation exchange at interlayer site and complexation with edge silanol functionality. The thermodynamic sorption modeling provides acceptable representations of the experimental data, and the species distributions calculated using the resulting reaction constants accounts for the predominance of cation exchange mechanism of Cs(I) and Sr(II) under the ambient aqueous conditions. The surface complexation of cationic fission products with silanol group slightly facilitates their sorption at pH > 8.

• Korean Chemical Engineering Research
• /
• 제62권2호
• /
• pp.173-180
• /
• 2024

Under ordinary atmospheric circumstances, the gravimetric technique was used to measure the solubility of L-cysteine (L-Cys) and L-alanine (L-Ala) in various solvents, including methyl alcohol, ethyl acetate, and mixtures of the two, in the range o 283.15 K to 323.15 K. Both individual solvents and their combinations showed a rise in the solubility of L-Cys and L-Ala with increasing temperature, according to the analyzed data but when analyzed at a constant temperature in the selected mixed solvents, the solubility declined with decreasing of initial mole fractions of methyl alcohol. To further assess, the relative utility of the four solubility models, we fitted the solubility data using the Jouyban-Acree (J-A), van't Hoff-Jouyban-Acree (V-J-A), Apelblat-Jouyban-Acree (A-J-A), and Ma models followed by evaluation of the values of the RAD information criteria and the RMSD were. The dissolution was also found to be an entropy-driven spontaneous mixing process in the solvents since the thermodynamic parameters of the solvents were determined using the van't Hoff model. In order to support the industrial crystallization of L-cysteine and L-alanine and contribute to future theoretical research, we have determined the experimental solubility, correlation equations, and thermodynamic parameters of the selected amino acids during the dissolution process.

• 설비공학논문집
• /
• 제3권4호
• /
• pp.250-255
• /
• 1991

Performance analysis of double-effect absorption heat pump system has been done to find improved working pairs (or mixture) by computer simulation. Based on the thermodynamic analysis, the coefficient of performance and mass flow ratio are investigated to compare three aqueous solutions [LiCl-water, LiSCN-LiBr-water, LiCl-$CaCl_2$-$Zn(NO_3)_2$-water] which was developed for only cooling, with conventional LiBr-water solution. It is found that the performances of the new aqueous solutions are better than that of LiBr-water solution not only in cooling systems, but also in heating systems. Theoretical thermodynamic performance data can be used in heat recovery systems by basic design data.