• Title/Summary/Keyword: Thermodynamic critical point

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A Numerical Study on the Laminar Flow Field and Heat Transfer Coefficient Distribution for Supercritical Water in a Tube

  • Lee Sang-Ho
    • International Journal of Air-Conditioning and Refrigeration
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    • v.13 no.4
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    • pp.206-216
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    • 2005
  • Numerical analysis has been carried out to investigate laminar convective heat transfer at zero gravity in a tube for supercritical water near the thermodynamic critical point. Fluid flow and heat transfer are strongly coupled due to large variation of thermodynamic and transport properties such as density, specific heat, viscosity, and thermal conductivity near the critical point. Heat transfer characteristics in the developing region of the tube show transition behavior between liquid-like and gas-like phases with a peak in heat transfer coefficient distribution near the pseudo critical point. The peak of the heat transfer coefficient depends on pressure and wall heat flux rather than inlet temperature and Reynolds number. Results of the modeling provide convective heat transfer characteristics including velocity vectors, temperature, and the properties as well as the heat transfer coefficient. The effect of proximity on the critical point is considered and a heat transfer correlation is suggested for the peak of Nusselt number in the tube.

A Study on the Laminar Flow Field and Heat Transfer Coefficient Distribution for Supercritical Water in a Tube (초임계상태의 물에 대한 관 내 층류유동장 및 열전달계수 분포특성에 관한 연구)

  • 이상호
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.15 no.9
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    • pp.768-778
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    • 2003
  • Numerical analysis has been carried out to investigate laminar convective heat transfer in a tube for supercritical water near the thermodynamic critical point. Fluid flow and heat transfer are strongly coupled due to large variations of thermodynamic and transport properties such as density, specific heat, viscosity, and thermal conductivity near the critical point. Heat transfer characteristics in the developing region of the tube show transition behavior between liquid-like and gas-like phases with a peak in heat transfer coefficient distribution near the pseudocritical point. The peak of the heat transfer coefficient depends on pressure and wall heat flux rather than inlet temperature and Reynolds number, Results of the modeling provide convective heat transfer characteristics including velocity vectors, temperature, and the properties as well as the heat transfer coefficient. The effect of proximity to the critical point is considered and a heat transfer correlation is suggested for the peak of Nusselt number in the tube.

A Study on the Transient Convective Heat Transfer for Supercritical Water in a Vertical Tube (수직관 내 초임계상태 물의 천이상태 대류열전달현상에 관한 연구)

  • Lee Sang-Ho
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.17 no.12
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    • pp.1095-1105
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    • 2005
  • Numerical analysis has been carried out to investigate transient turbulent convective heat transfer in a vertical tube for supercritical water near the thermodynamic critical point. Heat transfer and fluid flow in the tube we strongly coupled due to the large variations of thermodynamic and transport properties such as density, specific heat, and turbulent viscosity. As pressure in the tube approaches to the critical pressure, the properties variation with time becomes larger. Heat transfer coefficient rapidly decreases along the tube near the pseudocritical temperature at the tube wall for $P_R<1.2$. Stanton number variation with time is largely reduced in the region of gas-like phase in comparison with Nusselt number. Turbulent viscosity ratio close to the wall increases near the pseudocritical temperature and it gradually decreases with time.

Investigation on a Prediction Methodology of Thermodynamic Properties of Supercritical Hydrocarbon Aviation Fuels (초임계 탄화수소 항공유의 열역학적 물성치 예측 기법 연구)

  • Hwang, Sung-rok;Lee, Hyung Ju
    • Journal of ILASS-Korea
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    • v.26 no.4
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    • pp.171-181
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    • 2021
  • This study presents a prediction methodology of thermodynamic properties by using RK-PR Equation of State in a wide range of temperature and pressure conditions including both sub-critical and super-critical regions, in order to obtain thermophysical properties for hydrocarbon aviation fuels and their products resulting from endothermic reactions. The density and the constant pressure specific heat are predicted in the temperature range from 300 to 1000 K and the pressure from 0.1 to 5.0 MPa, which includes all of the liquid and gas phases and the super-critical region of three representative hydrocarbon fuels, and then compared with those data obtained from the NIST database. Results show that the averaged relative deviations of both predicted density and constant pressure specific heat are below 5% in the specified temperature and pressure conditions, and the major sources of the errors are observed near the saturation line and the critical point of each fuel.

Laminar Forced Convective Heat Transfer to Near-Critical Water in a Tube

  • Lee, Sang-Ho
    • Journal of Mechanical Science and Technology
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    • v.17 no.11
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    • pp.1756-1766
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    • 2003
  • Numerical modeling is carried out to investigate forced convective heat transfer to near-critical water in developing laminar flow through a circular tube. Due to large variations of thermo-physical properties such as density, specific heat, viscosity, and thermal conductivity near thermodynamic critical point, heat transfer characteristics show quite different behavior compared with pure forced convection. With flow acceleration along the tube unusual behavior of heat transfer coefficient and friction factor occurs when the fluid enthalpy passes through pseudocritical point of pressure in the tube. There is also a transition behavior from liquid-like phase to gas-like phase in the developing region. Numerical results with constant heat flux boundary conditions are obtained for reduced pressures from 1.09 to 1.99. Graphical results for velocity, temperature, and heat transfer coefficient with Stanton number are presented and analyzed.

Evolution of the Vortex Melting Line with Irradiation Induced Defects

  • Kwok, Wai-Kwong;L. M. Paulius;Christophe Marcenat;R. J. Olsson;G. Karapetrov
    • Progress in Superconductivity
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    • v.3 no.1
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    • pp.5-12
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    • 2001
  • Our experimental research focuses on manipulating pinning deflects to alter the phase diagram of vortex matter, creating new vortex phases. Vortex matter offers a unique opportunity for creating and studying these novel phase transitions through precise control of thermal, pinning and elastic energies. The vortex melting transition in untwinned YB $a_2$C $u_3$ $O_{7-}$ $\delta$/ crystals is investigated in the presence of disorder induced by particle irradiation. We focus on the low disorder regime, where a glassy state and a lattice state can be realized in the same phase diagram. We follow the evolution of the first order vortex melting transition line into a continuous transition line as disorder is increased by irradiation. The transformation is marked by an upward shift in the lower critical point on the melting line. With columnar deflects induced by heavy ion irradiation, we find a second order Bose glass transition line separating the vortex liquid from a Bose glass below the lower critical point. Furthermore, we find an upper threshold of columnar defect concentration beyond which the lower critical point and the first order melting line disappear together. With point deflect clusters induced by proton irradiation, we find evidence for a continuous thermodynamic transition below the lower critical point..

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Convective Heat Transfer to Water near the Critical Region in Horizontal Rectangular Ducts (수평 직사각 덕트 내 임계점 부근 물의 대류열전달 특성)

  • Lee, Sang-Ho
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.36 no.5
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    • pp.477-485
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    • 2012
  • Fluid flow and heat transfer in horizontal ducts are strongly coupled with large changes in thermodynamic and transport properties near the critical region as well as the gravity force. Numerical analysis has been carried out to investigate convective heat transfer in horizontal rectangular ducts for water near the thermodynamic critical point. Convective heat transfer characteristics, including velocity, temperature, and the properties as well as local heat transfer coefficients along the ducts are compared with the effect of proximity on the critical point. When there is flow acceleration because of a density decrease, convective heat transfer characteristics in the ducts show transition behavior between liquid-like and gas-like phases. There is a large variation in the local heat transfer coefficient distributions at the top, side, and bottom surfaces, and close to the pseudocritical temperature, a peak in the heat transfer coefficient distribution resulting from improved turbulent transport is observed. The Nusselt number distribution depends on pressure and duct aspect ratio, while the Nusselt number peak rapidly increases as the pressure approaches the critical pressure. The predicted Nusselt number is also compared with other heat transfer correlations.

Thermodynamic Incompatibility of Food Macromolecules (식품 거대분자의 열역학적 비혼합성)

  • 황재관;최문정
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.27 no.5
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    • pp.1019-1025
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    • 1998
  • Proteins and polysaccharides are major food macromolecules. Generally, the mixture of these macromolecules can be separated into two phases because of their thermodynamic incompatibility. Phase separ-ation is explained by equilibrium phase diagram, which comprises binodal curve, critical point, phase separation threshold, tie-line and rectilinear diameter. Phase separation of protein-polysacc-haride solution is affected by pH, temperature, ionic strength, molecular weight, molecular structure, etc. Membraneless osmosis has been developed to concentrate protein solutions, using the phase diagram constituted by proteins and polysaccharides. Protein-polysaccharide mixtures are very promising fat mimetics because solution of mixtures forms water-continuous system with two phase-separated gels, which give plastic texture and a fatty mouthfeel.

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Compressibility Factor Effect on the Turbulence Heat Transfer of Super-critical Carbon Dioxide by an Elliptic-blending Second Moment Closure (타원혼합모형을 이용한 초임계상태 이산화탄소의 압축성계수에 의한 난류열전달 특성)

  • Han, Seong-Ho;Seo, Jeong-Sik;Shin, Jung-Kun;Choi, Young-Don
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.31 no.1 s.256
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    • pp.40-50
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    • 2007
  • The present contribution describes the application of elliptic-blending second moment closure to predict the gas cooling process of turbulent super-critical carbon dioxide flow in a square cross-sectioned duct. The gas cooling process under super-critical state experiences a drastic change in thermodynamic and transport properties. Redistributive terms in the Reynolds stress and turbulent heat flux equations are modeled by an elliptic-blending second moment closure in order to represent strongly non-homogeneous effects produced by the presence of walls. The main feature of Durbin's elliptic relaxation second moment closure that accounts for the nonlocal character of pressure-velocity gradient correlation and the near-wall inhomogeneity guaranteed by the elliptic blending second moment closure.

Numerical Simmulation of Carbon Dioxide Compressible Fluid Flow and Heat Transfer under Supercritical State in a Straight Duct with Square Cross Section (초임계 상태 이산화탄소의 정사각 직덕트 내 압축성 유동 크기 열전달의 전산해석)

  • Joo, Kwang-Sup;Choi, Young-Don;Chun, Kun-Ho;Kim, Dong-Chul;Bae, Doo-Ho
    • Proceedings of the KSME Conference
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    • 2001.06e
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    • pp.524-529
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    • 2001
  • Because of the ozone layer depletion and global wanning, new alternative refrigerants are being developed. Among them, HFC refrigerants are thought promising, but some European countries are arguing that these refrigerants are also harmful to the global wanning. Therefore, natural refrigerants should be considered as an eventual alternative in refrigerators and heat pumps. In the present study, the supercritical gas cooling process are computationally analysed by employing various turbulence models of carbon dioxide in a trans critical refrigeration cycle. The gas cooling process near the critical point experiences a drastic change in thermodynamic and transport properties, thus the heat transfer characteristics would be different from those of two or single phases. Based on the computational results, the correlations to estimate the near-critical heat transfer characteristics will are obtained.

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