• 제목/요약/키워드: Thermo-Stability

검색결과 154건 처리시간 0.027초

액체 로켓엔진에서 선형 연소 불안정 해석을 이용한 연소 안정한계 곡선 계산 (Calculation of Combustion Stability Limits Using Linear Stability Analysis in Liquid Rocket Engines)

  • 손채훈;문윤완;허환일
    • 한국항공우주학회지
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    • 제32권10호
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    • pp.93-101
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    • 2004
  • 액체 로켓엔진에서 발생하는 고주파 연소 불안정성을 예측하기 위해 선형 안정한계를 계산하는 방법을 연구하였다. 기존의 선형이론에 근거하여 유도된 선형 안정한계를 나타내는 안정한계 식을 채택하였으며, 그 식을 구성하는 각각의 항을 정량적으로 평가하는 방안들이 제시되었다. 안정한계 계산에 필요한 열-화학 물성치와 유동 변수를 열역학적 평형계산과 CFD 해석 및 실험 결과로부터 평가하는 구체적 절차들을 상세히 제시하였다. 실제 로켓엔진으로서 시험 데이터가 확보되어 있는 KSR-III 로켓엔진에 대해서 제시한 방법을 적용하여 안정한계 곡선을 구하였다. 계산결과는, 해당 엔진에 대해 정량적으로 타당한 안정한계 곡선을 보여주었다. 이를 토대로 해당 엔진의 안정성 특성을 분석하였다. 본 연구에서 제시된 선형 안정한계 계산 방법은 진정한 예측의 1차적 근사로서 활용할 만한 가치가 있으며, 엔진 개발 초기에 근사적으로 안정성 경향을 분석하기에 유용할 것이다.

포르말계 에너지화 가소제의 합성 및 특성분석 (Systhesis and Characterization of energetic plasticizers, Formal)

  • 김진석;이근득;조진래
    • 한국군사과학기술학회지
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    • 제5권4호
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    • pp.49-56
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    • 2002
  • For the purpose of the increase in the performance and thermal stability of PBX's, the mixed formal consisting of BDNPF, DNPBF and BDNBF were synthesized. In order to find out the optimal condition for the synthesis of energetic plasticizer, BDNPF, DNPBF and BDNBF, the synthetic procedures have been investigated. We synthesized DNP-OH and DNB-OH through oxidative nitration and controlled various composition of mixed formal by $H_{2}SO_{4}$ and s-trioxane to investigate optimal composition, and then characterized its thermo-physical properties.

Azo-Dyes Photo-Aligning; Physics and Applications

  • Chigrinov, V.G.;Kwok, H.S.;Takada, Hirokazu;Takatsu, Haruyoshi
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2005년도 International Meeting on Information Displayvol.I
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    • pp.759-763
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    • 2005
  • This review presents the status of our research in liquid crystal display (LCD) photo-aligning. We present the basic mechanisms of the photo-induced order in various photo-aligning materials and in azo-dye layers in particular and show that photo-aligning methods can provide a controllable pretilt angle and anchoring energy of the liquid crystal cell, as well as its high thermo and UV stability. The photo-aligning of various types of liquid crystal displays is also discussed.

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나노유체의 분산안정성 및 열물성치와 그 응용에 관한 연구 (Stability and Thermo-physical Properties of Nanofluids and Its Applications)

  • 황유진;이광호;김경민;이재근
    • 한국전산유체공학회:학술대회논문집
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    • 한국전산유체공학회 2008년도 춘계학술대회논문집
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    • pp.474-478
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    • 2008
  • It has been shown that a nanofluid consisting of nanoparticles dispersed in base fluid has much higher effective thermal conductivity than pure fluid. In this study, four kinds of nanofluids such as multiwalled carbon nanotube (MWCNT) in water, CuO in water, SiO2in water, and CuO in ethylene glycol, are produced. Their thermal conductivities are measured by a transient hot-wire method. The thermal conductivity of water-based MWCNT nanofluid is shown to be increased by up to 11.3% at a volume fraction of 0.01. The measured thermal conductivities of MWCNT nanofluids are higher than those calculated with Hamilton-Crosser's model due to neglecting solid-liquid interaction at the interface. The results show that the thermal conductivity enhancement of nanofluids depends on the thermal conductivities of both particles and the base fluid. Stability of nanofluids is estimated by UV-vis spectrum analysis. Stability of nanofluid depends on the type of base fluid and the suspended particles. Also it can be improved in addition of a surfactant.

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로켓 연소기의 동압 진폭엔벨롭을 이용한 안정성 해석 (Stability Analysis Using the Amplitude Envelope of Dynamic Pressure in the Rocket Combustor)

  • 이수용
    • 한국추진공학회지
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    • 제25권1호
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    • pp.42-49
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    • 2021
  • 얼마나 쉽게 연소불안정 해지는지에 대한 척도로서, 작동 안정성 여유를 예측하기 위해 로켓연소기시스템의 열음향 불안정을 검토하였다. 연소기 시스템의 동적거동 특성파악을 위해 연소성능시험 중 측정한 연소기의 동압 데이터를 바탕으로 시간이 지남에 따라 시스템이 안정해지는지를 결정하는 파라미터로서 성장속도 계수를 구하였다. 파라미터 추출은 시계열 압력데이터를 주파수 도메인으로 전환하여 관심모드의 성장속도나 감쇠계수를 도출하는 방법을 우선 검토하였으며, 스토캐스틱 해석의 경우에는 압력진동의 진폭 엔벨롭으로 부터 압력진폭 PDF를 추출했다.

알칼리 수전해를 위한 상용 음이온교환막의 고온 특성 (High Temperature Characteristics of Commercially Available Anion Exchange Membrane for Alkaline Water Electrolysis)

  • 장수연;유철휘;황갑진
    • 한국수소및신에너지학회논문집
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    • 제33권4호
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    • pp.330-336
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    • 2022
  • In order to evaluate the possibility as a separator in alkaline water electrolysis, the high temperature characteristics were evaluated by measuring the membrane resistance and durability of 5 types of commercial anion exchange membranes in 7 M KOH solution and at 80℃. The membrane resistance of AEM membrane measured in 7 M KOH solution and at 80℃ had a lower value of about 8-24 times compared to the other membranes. The durability of AEM membrane tested with the soaking time in 7 M KOH solution and at 80℃ showed a very good stability and that of FAAM40 and FAAM75-PK showed secondly a good stability. The thermal stability with the soaking time in 7 M KOH solution and at 80℃ of FAAM40 and FAAM75-PK membrane analyzed by thermo-gravimetric analysis showed a good stability compared to the other membranes.

A New Class of Sol-Gel Transition Hydrogels for Macromolecular Delivery

  • Lee, Yu-Han;Park, Sung-Young;Chung, Hyun-Jung;Park, Tae-Gwan
    • 한국고분자학회:학술대회논문집
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    • 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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    • pp.52-53
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    • 2006
  • A new series of PEO-PPO-PEO and PPO-PEO-PPO copolymers having several hydroxyl groups on the PPO chain segment were synthesized, further modified with various poly(lactic acid) PLA oligomeric chains to confer physical stability after thermo-gelation in the body fluid. Gel stability was endowed by either increasing hydrophobic interaction between PLA chains or inducing stereocomplex formation between enatiomeric isomers of PLA chains. Macromolecular drugs were incorporated within the gels and their release patterns were investigated using Pluronic F127 as a control.

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반복되는 열주기환경에 노출된 에폭시/탄소섬유 복합재료의 열산화 안정성 연구 (Thermo-Oxidative Stability of Epoxy/Carbon Fiber Composites under Thermal Cycling Conditions)

  • 남재도
    • 유변학
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    • 제10권2호
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    • pp.106-112
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    • 1998
  • 항공기용 소재로 개발된 에폭시/탄소섬유 복합재료가 매트릭스의 유리전이온도에 육 박하는 온도주기를 경험할 때 발생하는 복합재료의 구조 및 물성변화를 실험과 모델링을 통 하여 연구하였다. 복합재료의 표준 경화온도인 177$^{\circ}C$에서 2시간 체류시킨후 냉각시키는 바 복 열주기는 복합재료를 취약하게 하여 결국 표면에서부터 미세크랙이발생한다는 것을 알수 있었다. 이러한 열주기에 따른 미세크랙 현상은 매트릭스의 분해반응이 발생할수 있는 유효 표면적을 증가시키고 크랙을 통하여 산소의투과를 용이하게 함으로서 산화반응을 가속화하 여 복합재료시편의 무게감소를 가속화시키는 것으로 판단된다. 특히 본 연구에서는 등온과 등속도 승온조건을 주기적으로 반복하는 열주기 조건을 해석하기 위하여 열주기 조건을 특 정온도에서의 등오시간으로 전환할 수 있는 e-quivalent cycle time(ECT)를 제안하였고 이 를 이용하여 열주기에 의한 복합재료 손상의 가속/감속 현상을 규명할수있었다.

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Experimental investigation on thermal behavior, sound absorption, and flammability of natural fibre polymer composites

  • Ravi Kumar, B.;Hariharan, S.S.
    • Structural Engineering and Mechanics
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    • 제76권5호
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    • pp.613-618
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    • 2020
  • Exhausting oil resources and increasing pollution around the world are forcing researchers to look for new, renewable, biodegradable materials to lead sustainable development. The use of fiber reinforced composites based on natural fibres has increasingly begun as prospective materials for various engineering applications in the automotive, rail, construction and aerospace industries. The natural fiber chosen to make the composite material is plant-based fibre, e.g. jute fibre, and hemp fibre. Thermosetting polymer based Epoxy (LY556) was utilized as matrix material and The composites were produced using hand lay-up technique. The fabricated composites were tested for acoustic testing, thermo-gravimetric analysis (TGA) and flammability testing to asses sound absorption, thermal decomposition and fire resistivity of the structures. Hemp fibre composites have shown improved thermal stability over Jute fibre composites. However, the fire resistance characteristics of jute fibre composites are better as compared to hemp fibre composites. The sound absorption coefficient of composites was found to enhance with the increase of frequency.

Critical Factors to High Thermostability of an ${\alpha}$-Amylase from Hyperthermophilic Archaeon Thermococcus onnurineus NA1

  • Lim, Jae-Kyu;Lee, Hyun-Sook;Kim, Yun-Jae;Bae, Seung-Seob;Jeon, Jeong-Ho;Kang, Sung-Gyun;Lee, Jung-Hyun
    • Journal of Microbiology and Biotechnology
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    • 제17권8호
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    • pp.1242-1248
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    • 2007
  • Genomic analysis of a hyperthermophilic archaeon, Thermococcus onnurineus NA1 [1], revealed the presence of an open reading frame consisting of 1,377 bp similar to ${\alpha}$-amylases from Thermococcales, encoding a 458-residue polypeptide containing a putative 25-residue signal peptide. The mature form of the ${\alpha}$-amylase was cloned and the recombinant enzyme was characterized. The optimum activity of the enzyme occurred at $80^{\circ}C$ and pH 5.5. The enzyme showed a liquefying activity, hydrolyzing maltooligosaccharides, amylopectin, and starch to produce mainly maltose (G2) to maltoheptaose (G7), but not pullulan and cyclodextrin. Surprisingly, the enzyme was not highly thermostable, with half-life ($t_{1/2}$) values of 10 min at $90^{\circ}C$, despite the high similarity to ${\alpha}$-amylases from Pyrococcus. Factors affecting the thermostability were considered to enhance the thermo stability. The presence of $Ca^{2+}$ seemed to be critical, significantly changing $t_{1/2}$ at $90^{\circ}C$ to 153 min by the addition of 0.5 mM $Ca^{2+}$. On the other hand, the thermostability was not enhanced by the addition of $Zn^{2+}$ or other divalent metals, irrespective of the concentration. The mutagenetic study showed that the recovery of zinc-binding residues (His175 and Cys189) enhanced the thermo stability, indicating that the residues involved in metal binding is very critical for the thermostability.