• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1997.11a
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• pp.389-392
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• 1997

Glutaronitrile(GN) was introduced to diglycidyl ether of bisphenol A(DGEBA)/ 4,4'-methylene dianiline(MDA) system to improve toughness. Effects of GN contents on thermal decomposition of epoxy resin system were investigated. To study the characteristics of thermal decomposition, thermo-gravimetric analysis(TGA) and Kissinger equation were used. Thermal degradation temperatures were about 365$^{\circ}C$ regardless of GN contents. Activation energies of thermal decomposition in epoxy resin system were almost constant below 10 phr and decreased above 15 phr.

• 한국신재생에너지학회:학술대회논문집
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• 2010.11a
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• pp.76.1-76.1
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• 2010

Recently, many efforts to solve the durability problem of PEM fuel cell are carried on constantly. However, despite this attention, durability researches of gas diffusion layer (GDL) are not much reported yet. Generally, GDL of PEM fuel cell experiences three external attacks, which are dissolution of water, erosion of gas flow, corrosion of electric potential. In this study, among these degradation factors, carbon corrosion of electric potential was focused and investigated with accelerated carbon corrosion test. Through the test, it is confirmed that carbon corrosion occurred at GDL, and corroded GDL decreased a performance of operating fuel cell. The property changes of GDL were measured with various methods such as air permeability meter, pore distribution analyzer, thermo gravimetric analyzer, and tensile stress test to discover the effects of carbon corrosion. Carbon corrosion caused not only loss of weight and thickness, but also degradation of mechanical strength of GDL. In addition, to analysis the reason of GDL property changes, a surface and a cross section of GDL were observed with scanning electron microscope. After 100 hours test, the GDL showed serious damage in center of layer.

• Structural Engineering and Mechanics
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• v.64 no.6
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• pp.793-802
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• 2017

The damage of concrete due to the expansion of alkali-aggregate reaction (AAR) and thermal-chemical reactions affecting the strength of concrete is studied. The empirical equations for the variations of expansion of AAR, compressive strength and degradation of the modulus of elasticity with time, and compressive strength with degradation of the modulus of elasticity are proposed by analysing numerous experimental data. It is revealed that the expansion of AAR and compressive strength increase with time. The proposed combination of the time variations of chemical and mechanical parameters provides a satisfactory prediction of the concrete strength. Seismic analysis of the aged Koyna dam is conceded for two different long-term experimental data of concrete incorporating the proposed AAR based properties. The responses of aged Koyna dam reveal that the crest displacement of the Koyna dam significantly increases with time while the contour plots show that major principal stress at neck level reduces with time. As the modulus of elasticity decreases with ages the stress generated in the concrete structure get reduces. On the other hand with lesser value of modulus of elasticity the structure becomes more flexible and the crest displacement becomes very high that cause the seismic safety of the dam reduce.

• Bulletin of the Korean Chemical Society
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• v.35 no.12
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• pp.3535-3541
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• 2014

Bisphenol A is considered as pollutant, because it is toxic and hazardous to living organisms even at very low concentrations. Biological oxidation used for removing this organic from waste water is not suitable and consequently application of catalytic wet oxidation has been considered as one of the best options for treating bisphenol A. We have developed Fe/SBA-15, Ni/SBA-15 and Fe-Ni/SBA-15 as heterogeneous catalysts using the advanced impregnation method for oxidation of bisphenol A in water. The catalysts were characterized with physico-chemical characterization methods such as, powder X-ray diffraction (PXRD), FT-IR measurements, N2 adsorption-desorption isotherm, thermo-gravimetric analysis (TGA), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and inductively coupled plasma optical emission spectroscopy (ICP-OES) analysis. This work illustrates activity of the catalysts for heterogeneous catalytic degradation reaction revealed with excellent conversion and recyclability. The degradation products identified were not persistent pollutants. GC-MS analysis identified the products: 2,4-hexadienedioic acid, 2,4-pentadienic acid and isopropanol or acetic acid. The leachability study indicated that the catalysts release very little metals to water. Therefore, the possibility of water contamination through metal leaching was almost negligible.

• Journal of Hydrogen and New Energy
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• v.34 no.3
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• pp.307-315
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• 2023

The physical and chemical changes exhibited by high density polyethylene (HDPE) after treatment with hydrogen at a pressure of 90 MPa followed by rapid release of the hydrogen were studied. X-ray diffraction, differential scanning calorimetry, thermo gravimetric analysis, and attenuated total reflectance (ATR)-fourier transform infrared (FTIR) were used for this purpose. As a result, it was found that the degree of crystallinity of HDPE decreased after hydrogen pressure treatment, while the average thickness of lamellae that constitute the crystals and the melting temperature of the crystalline region actually increased. The decomposition temperature also increased by about 3℃. In addition, it was found that the hydrogen bonding network between -OH groups in the HDPE sample was strengthened and partial chain scission occurred. These cut chains were found to be terminated by oxidative degradation such as cross-linking between chains, -C=O, -C-O, and -CHO, or by the formation of -CH₃ at the chain ends, as confirmed by ATR-FTIR.

• Journal of Welding and Joining
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• v.24 no.6
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• pp.21-27
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• 2006

This study was focused on the evaluation of the thermo-mechanical board-level reliability of Pb-bearing and Pb-free surface mount assemblies. The composition of Pb-bearing solder was a typical Sn-37Pb and that of Pb-free solder used in this study was a representative Sn-3.0Ag-0.5Cu in mass %. Thermal shock test was chosen for the reliability evaluation of the solder joints. Typical $Cu_6Sn_5$ intermetallic compound (IMC) layer was formed between both solders and Cu lead frame at the as-reflowed state, while a layer of $Cu_3Sn$ was additionally formed between the $Cu_6Sn_5$ and Cu lead frame during the thermal shock testing. Thickness of the IMC layers increased with increasing thermal shock cycles, and this is very similar result with that of isothermal aging study of solder joints. Shear test of the multi layer ceramic capacitor(MLCC) joints was also performed to investigate the degradation of mechanical bonding strength of solder joints during the thermal shock testing. Failure mode of the joints after shear testing revealed that the degradation was mainly due to the excessive growth of the IMC layers during the thermal shock testing.

• Journal of Technologic Dentistry
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• v.33 no.3
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• pp.193-202
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• 2011

Purpose: The aim of this study was to evaluate the effect of pre-treatment of core and hydrothermal treatment on the bond strength and flexural strength of ceramic veneered zirconia. Methods: 3Y-TZP specimens(KaVo Zr, $25mm{\times}3mm{\times}1mm$)were prepared by five pre-treatment methods and divided into seven groups including control two groups, subsequently the specimens veneered with the E-MAX ceram according to manufacturer's information(total specimen thickness 1.5mm). Two groups from ceramic-zirconia specimens(n=105, n=15 per group)were assigned into two experimental fatigue conditions, namely storage in an autoclave at $134^{\circ}C$ for 5h, thermo-cycling(3,000cycles, between 5 and $55^{\circ}C$, dwell time 45s, transfer time 2s). A flexural strength test was performed in a universal testing machine(crosshead speed: 0.5mm/min). Data were statistically analyzed using one-way ANOVA and Tukey's test(${\alpha}$=0.05). Results: The ceramic-zirconia bond strength value for liner application group(LLW, $27.3{\pm}3.8$) were significantly lower than those of the pre-treatment groups($30.72{\pm}5.3$). The ceramic-zirconia bond strength and zirconia flexural strength was not affected by thermo-cycling(p>0.05), whereas it was affected by storage in an autoclave at $134^{\circ}C$ for 5h(p<0.05). Conclusion: The results indicated that the ceramic-zirconia bond strength and zirconia flexural strength was affected by low temperature degradation.

• Journal of the Korean Society for Nondestructive Testing
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• v.23 no.4
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• pp.349-355
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• 2003

Material degradation due to corrosion fatigue was evaluated nondestructively using backward radiated Rayleigh surface wave. h corrosion fatigue test was carried out for the specimens made of thermo-mechanically controlled process steel in 3.5wt.% NaCl solution at $25^{\circ}C$. The backward radiation profile, which is the amplitude variation of backward radiated ultrasound according to the incident angle, of the specimens were measured in water at room temperature after the corrosion fatigue test. The velocity of Rayleigh surface wave, determined from the incident angle at which the profile of the backward radiated ultrasound became maximum, decreased for the specimen that had the large number of cycles to failure in the corrosion fatigue test. This fact implies that the corrosion degradation occurred at specimen surface in this specific test is dominantly dependant on the me exposed to corrosion environment. The result observed in the present work demonstrates the high potential of backward radiated Rayleigh surface wave as a tool for nondestructive evaluation of corrosion degradation of aged materials.

• Journal of Microbiology
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• v.42 no.4
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• pp.346-352
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• 2004

Poly(3-Hydroxybutyrate-co­3-Hydroxyvalerate), poly(3HB-co-3HV), copolyesters with a variety of 3HV contents (ranging from 17 to $60\;mol\%$) were produced by Alcaligenes sp. MT-16 grown on a medium containing glucose and levulinic acid in various ratios, and the effects of hydrophilicity and crystallinity on the degradability of the copolyesters were evaluated. Measurements of thermo-mechanical pro­perties and Fourier-transform infrared spectroscopy in the attenuated total reflectance revealed that the hydrophilicity and crystallinity of poly(3HB-co-3HV) copolyesters decreased as 3HV content in the copolyester increased. When the prepared copolyester film samples were non-enzymatically hydrolysed in 0.01 N NaOH solution, the weights of all samples were found to have undergone no changes over a period of 20 weeks. In contrast, the copolyester film samples were degraded by the action of extra­cellular polyhydroxybutyrate depolymerase from Emericellopsis minima W2. The overall rate of weight loss was higher in the films containing higher amounts of 3HV, suggesting that the enzymatic degra­dation of the copolyester is more dependent on the crystallinity of the copolyester than on its hydro­philicity. Our results suggest that the degradability characteristics of poly(3HB-co-3HV) copolyesters, as well as their thermo-mechanical properties, are greatly influenced by the 3HV content in the copoly­esters.

• Composites Research
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• v.17 no.1
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• pp.47-54
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• 2004

Vacuum hot pressing has been used for the development of titanium metal matrix composites using foil-fiber-foil technique. Subsequent micro-mechanical characteristics of the composites are then investigated by means of several experimental methods. The levels of consolidation, together with mechanism based failure processes of the materials have been analyzed by employing a thermo-acoustic emission technique. As shown by the results, fiber strength degradation occurs during the consolidation, and particularly residual stresses results from the thermal expansion mismatch between fiber and matrix materials during cooling process are incorporated in the changes of mechanical properties of the finished products. In industrial applications, both qualitative and quantitative evaluations of the material-mechanical characteristics are particularly important, and therefore must be included in process development. The present paper represents a methodology by which this can be achieved.