• 한국수소및신에너지학회논문집
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• 제2권1호
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• pp.69-75
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• 1990

The effect of thermal cycling on the hydrogenation characteristics of the $Mg_2Cu-H$ system was investigated in order to study of intrinsic degradation of the system. The hydrogen storage capacity decreased with thermal cycling from $573^{\circ}K$ to $663^{\circ}K$. By the thermal analysis it is found that stable $MgH_2$ hydride is formed during thermal cycling. With a heat treatment at $693^{\circ}K$ at a hydrogen pressure of 16 atm, the hydrogenation rate drastically decreased. From these observation, it suggested that the intrinsic degradation of $Mg_2Cu$ system results from mainly the formation of stable $MgH_2$ hydride phase.

• 폴리머
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• 제33권5호
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• pp.446-451
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• 2009

신뢰성 평가 시험법인 RS M 0042에 따라, 열화시간 경과에 따른 선형저밀도 폴리에틸렌 파이프의 신뢰성 평가를 수행하였다. 열화시간이 증가함에 따라, 인장강도는 250일 열화시점까지 비례적으로 증가하였고, 경도는 비교적 미소한 증가를 보였으며, 연신율은 점진적으로 감소하는 경향을 보였다. 이러한 결과는 열화시간이 증가함에 따른, 결정화도의 증가와 열산화에 의한 가교밀도의 증가, 사슬 전단 및 사슬 운동성의 감소 등에 기인한 것으로 판단된다. 장기정수압시험 결과는 초기의 연성파괴에서 차후 취성파괴로 전환되는 시점이 존재함을 확인하였다. 산화유도시간 측정은 선형저밀도폴리에틸렌 파이프의 열산화 정도를 관찰하기 위해 도입되었다. 측정 결과는 250일 이후 선형저밀도폴리에틸렌 파이프에 첨가된 산화방지제가 거의 고갈되었음을 보여준다. $100^{\circ}C$ 열화 조건에서 산화방지제의 잔존량을 계산할 수 있는 실험식을 열화시간의 함수로 표현하여 제안하였다. 적외선분광분석 결과는 열화된 선형저밀도폴리에틸렌 파이프 표면상에 카르보닐 및 하드록실 관능기가 증가하였음을 보여준다. 이는 선형저밀도폴리에틸렌 표면의 탄화수소 그룹의 산화가 국부적으로 발생하였음을 나타낸다.

• Transactions on Electrical and Electronic Materials
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• 제13권4호
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• pp.204-207
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• 2012

Epoxy nanocomposite was synthesized through the exfoliation of organoclay in an epoxy matrix, which was composed of diglycidyl ether of bisphenol A (DGEBA), 4,4'-methylene dianiline (MDA) and malononitrile (MN). Organoclay was prepared by treating the montmorillonite with octadecyl trimethyl ammonium bromide (ODTMA). The exfoliation of the organoclay was estimated by wide angle X-ray diffraction (WAXD) analysis. In order to measure the cure rate of DGEBA/MDA (30 phr)/MN (5 phr)/organoclay (3 phr), differential scanning calorimetry (DSC) analysis was performed at various heating rates, and the data were interpreted by Kissinger equation. Thermal degradation kinetics of the epoxy nanocomposite were studied by thermogravimetric analysis (TGA), and the data were introduced to the Ozawa equation. The activation energy for cure reaction was 45.8 kJ/mol, and the activation energy for thermal degradation was 143 kJ/mol.

• Journal of Electrical Engineering and Technology
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• 제12권2호
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• pp.840-845
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• 2017

In this paper, in order to investigate the lifetime of oil-paper insulation, specimens were artificially aged with thermal and electrical multiple stresses. Accelerated ageing factors and equivalent operating years for each aging temperatures were derived from results of tensile strengths for the aged paper specimens. Also, the evaluation for the multi-stress aged specimens were carried out through the measurement of impulse breakdown voltage at high temperature of $85^{\circ}C$. The lifetimes of the oil-paper insulations were calculated with the value of 66.7 for 1.0 mm thickness specimens and 69.7 for 1.25 mm thickness specimens throughout the analysis of impulse BD voltages using equivalent operating years, which means that dielectric strengths would not be severely decreased until the mechanical lifetime limit. Therefore, for the lifetime evaluation of the oil-paper insulation, thermal aging would be considered as a dominant factor whereas electrical degradation would be less effective.

• 한국미생물·생명공학회지
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• 제17권4호
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• pp.365-369
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• 1989

Tyichoderma viride가 생산하는 cellobiohydrolase의 열불활화 특성을 잔류효소역가 측정방법과 면역학적 정량방법으로 측정하였다. 정제된 cellobiohydrolase의 열불활 곡선은 Arrhenius plots에서 직선관계를 가졌고 이 때의 Z-값은 carboxymethyl cellulase의 정량시 5.2$^{\circ}C$, filter pa per degradation activity 정량시 6.4$^{\circ}C$, Immunoassay시 5.8$^{\circ}C$로 각기 나타났다. 열역학 상수 산출시는 immunoassay 와 filter paper degradation activity 측정이 carboxymethyl cellulase의 역가 측정보다 잘 일치하는 것을 알 수 있었다.

• 한국항해항만학회:학술대회논문집
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• 한국항해항만학회 2000년도 추계학술대회논문집
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• pp.57-60
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• 2000

In this paper, study on the properties of the thermal degradated epoxy resin which is used in indoor insulation apparatus is performed to investigate the problems of the decreasing insulation characteristics and crack in the indoor insulation apparatus. As a parameter of variation, SEM, contact angle, surface resistivity, relative dielectric constant and weight loss are measured. As the results of the above measurements, the contact angle and surface resistivity of the epoxy resin has increased to 200$^{\circ}C$ in but at the above 200$^{\circ}C$ the values have decreased. The relative dielectric constants the thermal treated samples have increased on with the temperature increase. We find the volatile components of the epoxy resin compound has disappeared during thermal degradation by SEM. The insulation properties of the epoxy resin have increased by the 200$^{\circ}C$ but decreased in the above 200$^{\circ}C$.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2002년도 하계학술대회 논문집 Vol.3 No.2
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• pp.1060-1062
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• 2002

Spherical and dense BAM phosphor particles were prepared by spray pyrolysis. The key idea of dense BAM particles is to lead gelation in droplets, which was successfully achieved by using the aluminum polycation as the precursor solution for the spray pyrolysis. The BAM phosphor particles prepared by spraying the aluminum polycation solution have completely spherical shape and dense structure. When directly applied to make phosphor film on the glass by the screen-printing method, the prepared spherical BAM phosphor particles showed better packing density and surface morphology than that of commercial one, which has irregular shape and large particle size. It was also found that the thermal degradation in the photoluminescence intensity for dense and spherical BAM particles was less than that of commercial one.

• 한국자원리싸이클링학회:학술대회논문집
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• 한국자원리싸이클링학회 2005년도 추계정기총회 및 제26회 학술발표대회 고분자리싸이클링기술 특별심포지엄
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• pp.360-367
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• 2005

PMMA는 우수한 물성으로 인하여 각종 소재 및 건축자재로 널리 활용되고있다. PMMA는 열 분해시 모노머 단위가 일정하게 이탈하는 unzip reaction을 나타내어 모노머로의 회수가 용이한 특징을 가지고있다. PMMA를 열분해하여 MMA를 회수하기 위한 기초연구로써 본 연구에서 TGA를 이용한 열분해특성을 조사하였다.

• 한국세라믹학회지
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• 제27권2호
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• pp.226-232
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• 1990

The degradation phenomena and thermal stability of 2.5Y-TZP at low-temperature were studied by means of XRD, Raman spectra and microstructural analysis. The degradation of heat-treated 2.5Y-TZP at 20$0^{\circ}C$-20hr in air was observed on the TZP surface, be caused by the cracks generated from tlongrightarrowm transformation, and the cracks was propagated inside the polycrystalline body. The ZrO2 grain boundaries and grains near the crack were revealed as if these were diffused and dissolved. And it was also observed mlongrightarrowt transformation as the degraded TZP was refired at 140$0^{\circ}C$, and it was thought to be the fact that the moisture in atmosphere during the aging process contributed to the degradation. The thermal stability of 2.5Y-TZP was improved dramatically with an addition of 3w/o CeO2 or a provision of high Y2O3 concentration on the TZP surface.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2000년도 추계학술대회 논문집
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• pp.57-60
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• 2000

In this paper, study on the properties of the thermal degradated epoxy resin which is used in indoor insulation apparatus is performed to investigate the problems of the decreasing insulation characteristics and crack in the indoor insulation apparatus. As a parameter of variation, SEM, contact angle, surface resistivity, relative dielectric constant and weight loss are measured. As the results of the above measurements, the contact angle and surface resistivity of the epoxy resin has increased to 200$^{\circ}C$ in but at the above 200$^{\circ}C$ the values have decreased. The relative dielectric constants the thermal treated samples have increased on with the temperature increase. We find the volatile components of the epoxy resin compound has disappeared during thermal degradation by SEM. The insulation properties of the epoxy resin have increased by the 200$^{\circ}C$ but decreased in the above 200$^{\circ}C$.