• 제목/요약/키워드: Thermal-degradation

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$^{60}Co\;{\gamma}$-선 조사에 따른 클로프렌 고무의 열적 특성 (Thermal Properties of Chloroprene Rubber with $^{60}Co\;{\gamma}$-ray Irradiation)

  • 김기엽;이청;류부형
    • 한국안전학회지
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    • 제18권4호
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    • pp.64-70
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    • 2003
  • The thermal properties of chloroprene rubber (CR) with $^{60}Co\;{\gamma}$-ray irradiation has been investigated. The prepared CR was irradiated up to 1000kGy radiation dose by $^{60}Co\;{\gamma}$-ray and the radiation degradation of CR was investigated by thermogravimetric analysis and differential acanning calorimetry. Dynamic mechanical properties measurement and FT-IR observation are carried out as well. From these analyses results, the glass transition temperature($T_g$), decomposition onset temperature(DOT), oxidative induction time(OIT), the peak temperature of loss modulus and mechanical tan ${\delta}$ values were compared for the radiation degradation level of CR. The tendency between $T_g$ and peak temperature of loss modulus and mechanical tan ${\delta}$ agreed well with radiation doses. Decomposition temperature, OIT and DOT showed the same tendencies as increasing radiation doses. It was verified that these analyses are available to estimate the degradation level of CR.

플라스틱 커플러를 채용한 프로젝션 TV의 휘도저감 (Brightness Degradation of Projection TV with Plastic Coupler)

  • 김남웅;김국원
    • 한국산학기술학회논문지
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    • 제7권6호
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    • pp.1028-1033
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    • 2006
  • 일반적으로 프로젝션 TV의 냉각을 위해서는 알루미늄 커플러와 냉매를 사용한다. 본 연구에서는 비용절감의 차원에서 플라스틱 커플러를 사용하는 경우, 냉각성능 저감에 따른 휘도저감의 문제에 대해 연구하였다. 형광체의 밝기와 온도변화와의 관계를 조사하고, 프로젝션 TV 내 CRT의 온도분포를 유한요소법을 이용하여 해석하였다. 이러한 결과로부터 플라스틱 커플러를 채용하는 프로젝션 TV의 휘도저감을 예측할 수 있었다.

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철도차량 견인전동기의 가속열화수명평가 기술현황 (A technology State of Accelerating Degradation and Life Estimation on the Traction Motor for Railway Rolling Stock)

  • 왕종배;김기준;최영찬
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2000년도 제2회 학술대회 논문집 일렉트렛트 및 응용기술전문연구회
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    • pp.25-28
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    • 2000
  • In this paper, the technology for accelerating degradation & life estimation on the traction motor was introduced with the stator form-winding sample coils of the 200 Class insulation system The accelerative degradation was performed in 10 cycles, which were composed of thermal stress, fast rising surge voltage, vibration, water immersion and overvoltage applying. After aging of 10 cycles, condition diagnosis test such as insulation resistance & polarization index, capacitance & dielectric loss and partial discharge properties were investigated in the temperature range of $20{\sim}160^{\circ}C$. Relationship between degradation conditions and diagnosis results were analyzed to find an dominative degradation factor at the end-life point

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잎담배의 열분석 I. 열중량분석과 시차열분석 (Thermal Analysis of Tobacco Leaf I. Thermogravimetric and Differential Thermal Analysis)

  • 박영수;양광규
    • 한국연초학회지
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    • 제3권2호
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    • pp.89-93
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    • 1981
  • Some or the parameters affecting the thermal analysis of different types of ground tobacco have been discussed. The sample, Korean flue- cured and burley and Greek orient tobacco leaves were run in air at heating rate of $10^{\circ}$ and 20^{\circ}C$ per minute. The thermograms obtained were divided into four temperature zones. The effect of different heating rates on thermal degradation has been discussed At the lower heating rate the maxima of DTA curves in zone 3 and 4 were 25-$40^{\circ}C$ lower than that of the higher heating rate.

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Mechanical strength of FBG sensor exposed to cyclic thermal load for structural health monitoring

  • Kim, Heonyoung;Kang, Donghoon;Kim, Dae-Hyun
    • Smart Structures and Systems
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    • 제19권3호
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    • pp.335-340
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    • 2017
  • Fiber Bragg grating (FBG) sensors are applied to structural health monitoring (SHM) in many areas due to their unique advantages such as ease of multiplexing and capability of absolute measurement. However, they are exposed to cyclic thermal load, generally in the temperature range of $-20^{\circ}C$ to $60^{\circ}C$, in railways during a long-term SHM and the cyclic thermal load can affect the mechanical strength of FBGs. In this paper, the effects of both cyclic thermal load and the reflectivity of FBGs on the mechanical strength are investigated though tension tests of FBG specimens after they are aged in a thermal chamber with temperature changes in a range from $-20^{\circ}C$ to $60^{\circ}C$ for 300 cycles. Results from tension tests reveal that the mechanical strength of FBGs decreases about 8% as the thermal cycle increases to 100 cycles; the mechanical strength then remains steady until 300 cycles. Otherwise, the mechanical strength of FBGs with reflectivity of 6dB (70%) and 10dB (90%) exhibits degradation values of about 6% and 12%, respectively, compared to that with reflectivity of 3dB (50%) at 300 cycles. SEM photos of the Bragg grating parts also show defects that cause their strength degradation. Consequently, it should be considered that mechanical strength of FBGs can be degraded by both thermal cycles and the reflectivity if the FBGs are exposed to repetitive thermal load during a long-term SHM.

계면활성제를 이용한 합성고분자 수용액의 마찰저항감소 및 퇴화 특성 향상 연구 (The Study on Drag Reduction Rates and Degradation Effects in Synthetic Polymer Solution with Surfactant Additives)

  • 이동민;김남진;윤석만;김종보
    • 설비공학논문집
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    • 제13권3호
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    • pp.194-199
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    • 2001
  • The turbulent flow resistance of water solution with polymer is reduced as compared with that of pure water. This effects is named th drag reduction and offers the significant reduction of the pumping power and the energy consumption. But the intense shear forces and the high temperature experienced by the polymer solution when passing through the pipes cause the degradation a loss of drag reduction effectiveness. Especially, the degradation behavior is found to be strongly dependent on temperature. This mechanical and thermal degradation can be avoided by adding materials such as surfactant to the polymer solution, which enhance the bonding force between molecules. In the present study, Copolymer and SDS were utilized and they were mixed in 10 different mixture ratios, while total concentration was fixed as 100wppm. Degradation of Copolymer-SDS mixture solutions was investigated experimentally in closed loop at the temperature of $10^{\circ}C\; and\; 80^{\circ}C$ with various flow average velocities of 1.5 m/sec, 3.0m/sec, and 4.5m/sec. Degradation characteristics of polymer solution without surfactant show a radical loss of drag reduction effectiveness at high temperature. Degradation alleviation ability of surfactant is especially effective at high temperature. Consequently, this results show that the addition of surfactant to the polymer solution can control unfavorable degradation phenomena for high temperature systems.

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황벽 추출염료와 염직물의 열적 퇴화 거동 연구 (Analysis of Amur Cork Tree Extract and Dyed Silk upon Thermal Degradation Treatment)

  • 안춘순
    • 한국의류학회지
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    • 제35권10호
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    • pp.1228-1241
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    • 2011
  • This research compares the change in berberine content in liquid dye and the color and dye uptake of amur cork tree dyed silk upon thermal degradation treatment. Thermal degradation of amur cork tree extract and liquid dye of standard berberine was carried out at room temperature, $4^{\circ}C$ refrigeration, and $100^{\circ}C$ oven conditions for 0-192 hours. Amur cork tree dyed silk was treated in a $100^{\circ}C$ oven for 0-240 hours. The berberine content in liquid dye was measured by the relative abundance of the berberine peak in the HPLC-MS chromatograms. The color and dye uptake of dyed silk was measured using K/S value and colorimetric data. The berberine content in standard berberine dye was 2.4 times that of the amur cork tree extract. A similar result was observed between the K/S value of standard berberine dyed silk and that of amur cork tree dyed silk. The berberine dyed silk showed the highest dye uptake after 120 hours in a $100^{\circ}C$ oven. This result was similar to the change in a berberine content in liquid dye in a $100^{\circ}C$ oven treatment. The change of the K/S value of amur cork tree dyed silk and berberine content of amur cork tree extract was similar up to 24 hours. The result suggests that there is a direct relationship between the color change of amur cork tree dyed silk and the berberine content in amur cork tree dye.

Thermal Degradation of BZO Layer on the CIGS Solar Cells

  • Choi, Pyungho;Kim, Sangsub;Choi, Byoungdeog
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2013년도 제44회 동계 정기학술대회 초록집
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    • pp.458-458
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    • 2013
  • We investigated a study on the thermal degradation of boron doped zinc-oxide (BZO) layer which used as a transparent conducting layer on the Cu (In1-xGax) Se2 (CIGS) based thin film solar cells. Devices were annealed under the temperature of $100^{\circ}C$ or 100 hours and then Hall measurement was carried out to characterize the parameters of mobility (${\mu}Hall$), resistivity (${\rho}$), conductivity (${\sigma}$) and sheet resistance (Rsh). The initial values of ${\mu}Hall$, ${\rho}$, ${\sigma}$ and Rsh were $29.3cm^2$/$V{\cdot}s$, $2.1{\times}10^{-3}{\Omega}{\cdot}cm$, $476.4{\Omega}^{-1}{\cdot}cm^{-1}$ and $19.1{\Omega}$/${\Box}$ respectively. After the annealing process, the values were $4.5cm^2$/$V{\cdot}s$, $12.8{\times}10^{-3}{\Omega}{\cdot}cm$, $77.9{\Omega}^{-1}{\cdot}cm^{-1}$ and $116.6{\Omega}$/${\Box}$ respectively. We observed that ${\mu}Hall$ and ${\sigma}$ were decreased, and ${\rho}$ and Rsh were increased. In this study, BZO layer plays an important role of conducting path for electrons generated by incident light onthe CIGS absorption layer. Therefore, the degradation of BZO layer characterized by the parameters of ${\mu}Hall$, ${\rho}$, ${\sigma}$ and Rsh, affect to the cell efficiency.

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나노사이즈 무기분말이 폴리우레탄복합체의 중합 및 열분해반응에 미치는 영향 (Effects of Nano-Sized Inorganic Fillers on Polymerization and Thermal Degradation of Polyurethane Composites)

  • 이준만;안원술
    • 한국산학기술학회논문지
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    • 제11권3호
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    • pp.1027-1034
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    • 2010
  • 상온경화 주형용으로 사용되는 상업적 폴리우레탄 수지에 평균 입자크기가 ${\mu}m$ 및 nm 크기의 서로 다른 무기물 파우더를 충전하여 만든 폴리우레탄 복합수지의 중합반응 및 분해반응 특성을 살펴보고 기계적물성의 변화를 연구하였다. 중합반응의 경우, 평균입자크기가 약 $0.5{\mu}m$로서 상대적으로 입경이 큰 Ce500 무기분말을 사용한 충전하는 경우에는 충전량이 많아질수록 최고 반응 속도점의 반응온도는 상대적으로 낮아지는 것으로 나타나는 반면, 나노두께크기의 MMT 충전제를 사용하는 경우에는 충전 함량에는 큰 차이가 없이 최고반응온도가 높아지면서 반응속도도 빨라지는 거동을 보였다. 또한 TGA 열중량 시험결과에 대하여 Kissinger method를 이용하여 분석한 결과로서 Ce500-복합체의 경우에는 분해반응의 활성화 에너지가 139.34 kJ/mol이었고 MMT-복합체의 경우에는 91.12 kJ/mol로 나타났으며 이로부터 MMT 분말의 분해촉매 효과를 확인할 수 있었다. 한편, 인장강도는 5phr 정도의 소량 충전함량에서는 별 변화를 보이지 않으나 그 이상의 함량에서는 MMT가 충전된 샘플의 강도 증가 현상이 뚜렷이 나타났다.