• Title/Summary/Keyword: Thermal storage density

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Physical Properties of Microencapsulated Phase Change Material Slurries (미립잠열슬러리의 물성에 관한 실험적 연구)

  • 이효진;홍재창;이재구
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.12 no.9
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    • pp.860-869
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    • 2000
  • The thermal conductivity and density of slurries entrained with the particles of Micro-PCM are measured with respect to its temperatures as well as concentrations. For the thermal conductivity of slurries, a device made from P.A. Hilton (Model No. H470) is adopted. There is a well-scaled 0.3 mm gap between shells into which the slurry is injected. The temperatures of the slurry are changed to $5~25^{\circ}C$ , for which it is controled by the supplied voltage and cooling water circulated around the outer shell. The concentrations of Micro-PCM slurries are varied from 5 wt% to 50 wt%. Some general equations such as Maxwell's equation, are evaluated for their applicability with Micro-PCM slurry. As a result, it happens to be some 20% discrepancy between the experiment and the applied equations. The density measurements of Micro-PCM slurry to its temperature and concentration are peformed by hydrometer. For the experiment, tetradecane encapsulated slurry (($t_m≒6^{\circ}C$) and a mixed wax ($t_m≒50^{\circ}C$) are tested. The temperature changes of tetradecane are applied for $0^{\circ}C\;to\;$20^{\circ}C$and a mixed wax for $20^{\circ}C\;to\;$60^{\circ}C$ and its concentrations are changed from 5 wt% to 30 wt%. The results are compared with a general equation and the referenced data. For the conclusion, the experimental result and a general equation are well agreed.

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Adiabatic Performance of Layered Insulating Materials for Bulk LH2 Storage Tanks (대용량 액체 수소 저장탱크를 위한 다층단열재의 단열성능 분석)

  • KIM, KYEONGHO;SHIN, DONGHWAN;KIM, YONGCHAN;KARNG, SARNG WOO
    • Journal of Hydrogen and New Energy
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    • v.27 no.6
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    • pp.642-650
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    • 2016
  • One of the most feasible solution for reducing the excessive energy consumption and carbon dioxide emission is usage of more efficient fuel such as hydrogen. As is well known, there are three viable technologies for storing hydrogen fuel: compressed gas, metal hydride absorption, and cryogenic liquid. In these technologies, the storage for liquid hydrogen has better energy density by weight than other storage methods. However, the cryogenic liquid storage has a significant disadvantage of boiling losses. That is, high performance of thermal insulation systems must be studied for reducing the boiling losses. This paper presents an experimental study on the effective thermal conductivities of the composite layered insulation with aerogel blankets($Cryogel^{(R)}$ Z and $Pyrogel^{(R)}$ XT-E) and Multi-layer insulation(MLI). The aerogel blankets are known as high porous materials and the good insulators within a soft vacuum range($10^{-3}{\sim}1$ Torr). Also, MLI is known as the best insulator within a high vacuum range(<$10^{-6}{\sim}10^{-3}$ Torr). A vertical axial cryogenic experimental apparatus was designed to investigate the thermal performance of the composite layered insulators under cryogenic conditions as well as consist of a cold mass tank, a heat absorber, annular vacuum space, and an insulators space. The composite insulators were laminated in the insulator space that height was 50 mm. In this study, the effective thermal conductivities of the materials were evaluated by measuring boil-off rate of liquid nitrogen and liquid argon in the cold mass tank.

Heat Transfer Characteristics of High Temperature molten salt storage for Solar Thermal Power Generation (태양열 발전을 위한 고온 축열 물질의 열전달 특성)

  • Aiming, Mao;KIm, Ki-Man;Han, Gui-Young;Seo, Tae-Beom;Kang, Yong-Heack
    • Journal of the Korean Solar Energy Society
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    • v.27 no.3
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    • pp.63-69
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    • 2007
  • The heat transfer characteristics of inorganic salt for high temperature heat storage material of solar power system were examined. The inorganic salts employed in this study was a mixture of $NaNO_3$ and $KNO_3$ and the operating temperature range was determined by measuring the melting temperature with DSC and by measuring the thermal decomposition temperature with TGA. The heat transfer characteristics was qualitatively obtained in terms of temperature profiles of salt in the tanks during the heat storage and heat release process as a function of steam flow rates, steam inlet temperature and the inlet position of steam. The effects of steam flow rates and inlet temperature of steam were experimentally determined and the effect of natural convection was observed due to significant density difference with temperature.

Structure-property relations for polymer melts: comparison of linear low-density polyethylene and isotactic polypropylene

  • Drozdov, A.D.;Al-Mulla, A.;Gupta, R.K.
    • Advances in materials Research
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    • v.1 no.4
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    • pp.245-268
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    • 2012
  • Results of isothermal torsional oscillation tests are reported on melts of linear low density polyethylene and isotactic polypropylene. Prior to rheological tests, specimens were annealed at various temperatures ranging from $T_a$ = 180 to $310^{\circ}C$ for various amounts of time (from 30 to 120 min). Thermal treatment induced degradation of the melts and caused pronounced decreases in their molecular weights. With reference to the concept of transient networks, constitutive equations are developed for the viscoelastic response of polymer melts. A melt is treated as an equivalent network of strands bridged by junctions (entanglements and physical cross-links). The time-dependent response of the network is modelled as separation of active strands from and merging of dangling strands with temporary nodes. The stress-strain relations involve three adjustable parameters (the instantaneous shear modulus, the average activation energy for detachment of active strands, and the standard deviation of activation energies) that are determined by matching the dependencies of storage and loss moduli on frequency of oscillations. Good agreement is demonstrated between the experimental data and the results of numerical simulation. The study focuses on the effect of molecular weight of polymer melts on the material constants in the constitutive equations.

Experimental Study on Calcium Chloride Impregnated Perlite for Thermochemical Heat Storage (염화칼슘이 함침된 펄라이트를 이용한 화학축열에 대한 실험적 연구)

  • Jung, Han Sol;Kim, Hak Seong;Hwang, Kyung Yub;Kim, Kwang Ho
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.27 no.3
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    • pp.123-127
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    • 2015
  • Thermochemical heat storage is a cutting-edge technology which can balance the energy usage between supplies and demands. Recent studies have suggested that thermochemical heat storage has significant advantages, compared to other storage methods such as latent heat storage or sensible heat storage. Nevertheless, ongoing research and development studies showed that the thermochemical heat storage has some serious problems. To bring the thermochemical heat storage method into market, we introduce experimental setup with composite material using perlite that supports calcium chloride sorbent. Also, to compare thermal properties with composite material, we used pure thermochemical material. Then, we found that the composite material has higher heat storage density by mass than pure calcium chloride. Moreover, it can be easily regenerated, which was impossible in the pure thermochemical materials.

Performance of a direct methanol fuel cell (DMFCs)Using Nation 115 (Nafion 115를 사용한 DMFC MEA 의 성능실험)

  • Choi, Hoon;Hwang, Yong-Sheen;Cha, Suk-Won
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.11a
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    • pp.43-46
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    • 2007
  • To find out the optimum design of hydrogen storage and supply tank using Metal Hydride (briefly MH) and to make clear the performance characteristics under various conditions are our research purpose. In order to use the low-temperature exhaust heat, $LaNi_{4.7}Al_{0.3}$ which operates under the low pressure of 1MPa is chosen, and we measure the basic properties, namely density, specific heat, PCT(Pressure-Concentration-Temperature) characteristic, and effective thermal conductivity. Then, a numerical calculation model of hydrogen storage using MH alloy is suggested and this thermal diffusion equation of model is solved by the backward difference method. This calculation results rate compared with the experimental results of the systems which installed 1kg MH alloy and, it is found out that our calculation model can well predict the experimental results. By the experimental using MH alloy, it is recognized that the hydrogen flow rate can control by the step adjustment of brine temperature.

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Simulation Study on Liquid Air Energy Storage (LAES) System using Dual Refrigeration Cycles and Thermal Oil Circulation (냉매사이클과 열매체유 순환을 활용한 액화공기에너지저장 시스템 공정모사 연구)

  • Jang, Soonnam;Park, Jongpo
    • Journal of the Korean Institute of Gas
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    • v.22 no.4
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    • pp.63-73
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    • 2018
  • Innovative technical process for Energy Storage System (ESS), Liquid Air Energy Storage system (LAES) is mature technologies based on the gas liquefaction process. In spite of many advantages such as high energy density, no geographical constraints, low investment costs and long useful life, the system has not yet widely commercialized due to low round trip efficiency. To improve RTE and acquire high yield of liquid air, various configurations of LAES process have been considered. In this research, dual refrigerants cycle (R-600a and methanol) for air liquefaction and thermal oil circulation for power generation via liquid air gasification have been applied to improve cycle performance significantly using Aspen HYSYS simulator.

Energy Storage Characteristics In Fixed Beds (Charging, Storing, Discharging)

  • Hassanein, Soubhi A.;Choi, Sang-Min
    • 한국연소학회:학술대회논문집
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    • 2004.11a
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    • pp.17-23
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    • 2004
  • In the present work, the numerical model was refined to predict the thermal analysis of energy storage in a fixed beds during (charging ,storing, discharging) mode. The governing energy equations of both fluid and the solid particles along with their initial and boundary conditions are derived using a two-phase, one dimensional model. The refined model is carried out by taking into account change of (air density , air specific heat) with air temperature and also by taking into considerations heat losses from bed to surrounding. Finite difference method was used to obtain solution of two governing energy equations of both fluid and solid particles through a computer program especially constructed for this purpose. The temperature field for the air and the solid are obtained, also efficiency of energy stored inside the bed is computed. Finally using refined model the effect of air flow rate per unit area Ga (0.2, 0.3, and 0.4 kg/$m^2$-s), and inlet air temperature (200, 250, 300 $^{\circ}C$) on energy storage characteristics was studied in three mode ( charging ,storing, discharging). The rock particles of diameter 1 em is used as bed material in this research.

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A Study on Thermo-Physical Properties of Microencapsulated Phase Change Material Slurry (마이크로캡슐 잠열 축열재 혼합수의 열물성에 관한 연구)

  • 임재근;최순열;김명준
    • Journal of Advanced Marine Engineering and Technology
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    • v.28 no.6
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    • pp.962-971
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    • 2004
  • This paper has dealt with thermo-physical properties of microencapsulated phase change material slurry as a latent heat storage material having a low melting point. The measured results of the thermo-physical properties of the test microencapsulated phase change material slurry, those are, density, specific heat, thermal conductivity and viscosity, were discussed for the temperature region of solid and liquid phases of the dispersion material (paraffin). The measurements of these properties of microencapsulated phase change material slurry have been carried out by using a specific-gravity meter, a water calorimeter, a differential scanning calorimeter(DSC), a transient hot wire method and rotating type viscometer, respectively. It was clarified that the additional properties law could be applied to the estimation of the density and specific heat of microencapsulated phase change material slurry and also the Euckens equation could be applied to the estimation of the thermal conductivity of this slurry.

The lyophilization and stability of Salmonella typhi Ty21a (Salmonella thphi Ty21a의 동결 건조와 안정성)

  • 김세란;박동우;전홍렬;김희준;한성순;김기호;김홍진
    • YAKHAK HOEJI
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    • v.43 no.6
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    • pp.793-797
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    • 1999
  • Salmonella typhi Ty21a is an attenuated strain of S. typhimurium and used for oral typhoid vaccine. In an attempt to increase the stability of Ty21a manufacturing typhoid vaccine, we studied about the stability of freeze-dried Th21a including additives at various temperature conditions. In order to investigate the freeze-drying rate of Ty21a according to various absorbance, we lyophilized Ty21a by using 8% sucrose as a stabilizer. The optimal freeze-drying rate of Ty21a was appeared when OD (optical density) value of the growth was between 2.5 and 3.0. To investigate the stability of Ty21a at various temperature, the viability was measured after storaging the freeze-dried Ty21a at the room temperature, cold and freezing condition for 1 week. The viability of Ty21a in cold and freezing storage condition was 5 times more stable than in room temperature. To search the most stable additives for the freeze-dried Ty21a, the viability of Ty21a including additives at the various storage condition was estimated. Mannitol and loctose were the most stable additives. Theses results suggest that the OD value of Ty21a growth, low temperature, mannitol and lactose are important factors for the optimal freeze-drying rate, the stable storage and the most stable additives, respectively.

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