• Title/Summary/Keyword: Thermal stability

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Deintercalation and Thermal Stability of Na-graphite Intercalation Compounds

  • Oh, Won-Chun
    • Carbon letters
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    • v.2 no.1
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    • pp.22-26
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    • 2001
  • Na alloyed graphite intercalation compounds with stage 1 and 2 were synthesized using the high temperature and pressure technique. Thermal stability and staging transitions of the compounds were investigated depending on heating rates. The thermal stability and temperature dependence of the deintercalation compounds were characterized using differential scanning calorimeter (DSC) analyzer. Enthalpy of formations were confirmed at temperatures between 25 and $500^{\circ}C$, depending on the various heating rates. The structure ions and interlayer spaces of the graphite were identified by X-ray diffraction (XRD). Diffractograms of stages with non-integral (00l) values were obtained in the thermal decomposition process, and stacking disorder defects and random stage modes were observed. The average value of the interlayer C-C bond lengths were found approximately $2.12{\AA}$ and $1.23{\AA}$ from the diffractions. Based on the stage transition, the degree of the deintercalaton has a inverse-linear relationship against the heating rate.

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Analysis of Dopant Dependency and Improvement of Thermal stability for Nano CMOS Technology (Nano-CMOS에서 NiSi의 Dopant 의존성 및 열 안정성 개선)

  • 배미숙;오순영;지희환;윤장근;황빈봉;박영호;박성형;이희덕
    • Proceedings of the IEEK Conference
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    • 2003.07b
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    • pp.667-670
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    • 2003
  • Ni-silicide has low thermal stabiliy. This point is obstacle to apply NiSi to devices. So In this paper, we have studied for obtain thermal stability and analysis of dopant dependency of NiSi. And then we applied Ni-silicide to devices. To improvement of thermal stability, we deposit Ni70/Co10/Ni30/TiN100 to sample. Co midlayer is enhanced thermal stability of NiSi. Co/Ni/TiN, this structure show very difference between n-poly and p-poly in sheet resistance. But Ni/Co/Ni/TiN, structure show less difference. Also junction leakage is good.

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The Thermal Stability of Teflon AF/FEP Double Layer Film Electret (Teflon AF/FEP 이중 필름 일렉트렛트의 열적 안정성)

  • 김병수;이덕출
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.16 no.8
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    • pp.693-699
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    • 2003
  • To improve thermal stability of Teflon FEP which is the most widely used materials for electret application, Teflon AF film of 1 $\mu\textrm{m}$ thick was spin coated on FEP film and the charge storage properties were investigated. The surface potential depend on aging temperature. Thermal Stimulated Current(TSC), Atomic Force Microscopy(AFM), and Fourier Transform-Infrared Spectroscope(FT-lR) measurements were carried out. It is shown that the AF/FEP dual film have more higher electrical property and thermal stability than that FEP film have caused by charge stored at interface of AF and FEP.

Parametric Study of Thermal Stability on Continuous Welded Rail

  • Choi, Dong-Ho;Na, Ho-Sung
    • International Journal of Railway
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    • v.3 no.4
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    • pp.126-133
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    • 2010
  • The thermal buckling analysis of curved continuous welded rail (CWR) is studied for the lateral buckling prevention. This study includes a thermal buckling theory which accounts for both thermal and vehicle loading effects in the evaluation of track stability. The parameters include rail size, track lateral resistance, track longitudinal and torsional stiffnesses, initial misalignment amplitude and wavelength, track curvature, tie-ballast friction coefficient and truck center spacing. Parametric studies are performed to evaluate the effects of the individual parameters on the upper and lower critical buckling temperatures. The results show that the upper critical buckling temperature is highly affected by the uplift due to vehicle loads. This study provides a guideline for the improvement of stability for dynamic buckling in curved CWR track.

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The Effect of Fumed Silica Loading on the Thermal Stability of Fluorosilicone Composites

  • Muhammet Iz;Jinhyok Lee;Myungchan Choi;Yumi Yun;Hyunmin Kang;Jungwan Kim;Jongwoo Bae
    • Elastomers and Composites
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    • v.57 no.4
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    • pp.165-174
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    • 2022
  • The effect of fumed silica loading on the thermal stability and mechanical properties of fluorosilicone (FVMQ) rubber was investigated. The distribution of fumed silica inside FVMQ was characterized using scanning electron microscopy, and the thermal stability of composites was evaluated using thermogravimetric analysis and by the changes in mechanical performance during thermo-oxidative aging. The function mechanism of fumed silica was studied by Fourier transform infrared spectroscopy. The results show that with increasing silica content, the crosslink density of composites, the modulus at 100%, and tensile strength also increased, whereas the elongation at break decreased. Furthermore, increasing the silica content of composites increased the initial decomposition temperature (Td) and residual weight of the composite after exposure to nitrogen. In addition, the thermal oxidative aging experiment demonstrated improved aging resistance of the FVMQ composites, including lower change in tensile strength, elongation at break, and modulus at 100%.

A thermal stability testing and analysis for a surge protector installed in residential distribution board (주택용 분전반에 설치되는 서지보호기의 열적 안전성 시험 및 분석)

  • Kim, Ju-Chul;Park, Jang-Bum;Ki, Che-Ouk
    • Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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    • 2009.10a
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    • pp.339-341
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    • 2009
  • Surge Protective Device(SPD) is installed by increasing information and communication equipments and home network equipments by individual home, and the amount of SPD used is increasing by revision industry regulations and strengthening equipotential grounding system. Parts of SPD installed in residential distribution board has ZnO varistor, voltage constraint type devices, but it is exposed to Temporary Overvoltage Characteristic. This thesis analyzes products through Thermal Stability test for SPD for general house and suggests the better method. As results of analysis, Gas Discharge Tube(GDT) to cut off from a leakage current and more than two kinds of safety devices to protect Thermal Runaway were needed.

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Stability and Thermo-physical Properties of Nanofluids and Its Applications (나노유체의 분산안정성 및 열물성치와 그 응용에 관한 연구)

  • Hwang, Y.;Lee, K.;Kim, K.;Lee, J.
    • 한국전산유체공학회:학술대회논문집
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    • 2008.03b
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    • pp.474-478
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    • 2008
  • It has been shown that a nanofluid consisting of nanoparticles dispersed in base fluid has much higher effective thermal conductivity than pure fluid. In this study, four kinds of nanofluids such as multiwalled carbon nanotube (MWCNT) in water, CuO in water, SiO2in water, and CuO in ethylene glycol, are produced. Their thermal conductivities are measured by a transient hot-wire method. The thermal conductivity of water-based MWCNT nanofluid is shown to be increased by up to 11.3% at a volume fraction of 0.01. The measured thermal conductivities of MWCNT nanofluids are higher than those calculated with Hamilton-Crosser's model due to neglecting solid-liquid interaction at the interface. The results show that the thermal conductivity enhancement of nanofluids depends on the thermal conductivities of both particles and the base fluid. Stability of nanofluids is estimated by UV-vis spectrum analysis. Stability of nanofluid depends on the type of base fluid and the suspended particles. Also it can be improved in addition of a surfactant.

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Thermal Stability and Surface Hardnes of UV-curable Epoxy Acrylate Coatings for Wooden Flooring (마루바닥재용 자외선 경화형 에폭시 아크릴레이트 도료의 열안정성과 표면경도)

  • Hwang, Hyeon-Deuk;Choi, Jae-Hoon;Moon, Je-Ik;Kim, Hyun-Joong
    • Journal of the Korean Wood Science and Technology
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    • v.36 no.6
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    • pp.121-129
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    • 2008
  • Environmental friendly UV-curable coatings, having excellent hardness, gloss, mar and chemical resistance, are commonly used for the wooden flooring coatings. Especially epoxy acrylate oligomers are chosen for the wooden flooring coatings, due to their thermal stability and fast curing. In this study, we investigated the effect of the acrylate functionality on the thermal stability and surface hardness. The thermal degradations of monomers, oligomer, photoinitiator and formulated coatings with different acrylate functionality were measured using a thermogravimetric analysis (TGA). And the surface hardness was also measured with a pendulum hardness tester to compare relationship between the thermal stability and the physical property. The cured coatings became thermally stable by crosslinking during UV-curing. Both the thermal stability and surface hardness of cured coatings were improved with increasing acrylate functionality.

Stress Dependence of Thermal Stability of Nickel Silicide for Nano MOSFETs

  • Zhang, Ying-Ying;Lee, Won-Jae;Zhong, Zhun;Li, Shi-Guang;Jung, Soon-Yen;Lee, Ga-Won;Wang, Jin-Suk;Lee, Hi-Deok;Lim, Sung-Kyu
    • Transactions on Electrical and Electronic Materials
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    • v.8 no.3
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    • pp.110-114
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    • 2007
  • Dependence of the thermal stability of nickel silicide on the film stress of inter layer dielectric (ILD) layer has been investigated in this study and silicon nitride $(Si_3N_4)$ layer is used as an ILD layer. Nickel silicide was formed with a one-step rapid thermal process at $500^{\circ}C$ for 30 sec. $2000{\AA}$ thick $Si_3N_4$ layer was deposited using plasma enhanced chemical vapor deposition after the formation of Ni silicide and its stress was split from compressive stress to tensile stress by controlling the power of power sources. Stress level of each stress type was also split for thorough analysis. It is found that the thermal stability of nickel silicide strongly depends on the stress type as well as the stress level induced by the $Si_3N_4$ layer. In the case of high compressive stress, silicide agglomeration and its phase transformation from the low-resistivity nickel mono-silicide to the high-resistivity nickel di-silicide are retarded, and hence the thermal stability is obviously improved a lot. However, in the case of high tensile stress, the thermal stability shows the worst case among the stressed cases.

A Study of Thermal Properties of LDPE-Nanoclay Composite Films

  • Bumbudsanpharoke, Nattinee;Ko, Seonghyuk
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.21 no.3
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    • pp.107-113
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    • 2015
  • This work focused on the study of thermal properties and kinetic behavior of LDPE-nanoclay composite films. The effect of nanoclay content (0.5, 1, 3, and 5 wt%) on thermal stability and crystallization characteristics of the nanocomposites were investigated by Thermogravimetric Analysis (TGA) and Differential Scanning Calorimetry (DSC). The results from endothermic curve showed that the nanoclay played an important role in the crystallization of nanocomposites by acting as nucleating agent. From exothermic curve, there was a crystallization temperature shift which was attributed to crystallization process induced by nanoclay. The TGA results showed that the addition of nanoclay significantly increased the thermal stability of LDPE matrix, which was likely due to the characteristic of layered silicates/clays dispersed in LDPE matrix as well as the formation of multilayered carbonaceous-silicate char. A well-known Coats-Redfern method was used to evaluate the decomposition activation energy of nanocomposite. It was demonstrated that introducing of nanoclay to LDPE matrix escalated the activation energy of nanocomposite decomposition resulting in thermal stability improvement.