• 한국화재소방학회논문지
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• 제15권4호
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• pp.34-40
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• 2001

HPMC의 자연발화는 일정한 주위온도에서 자연발화의 연구와 Godbret-Greenwald가 고안한 전기로에서 운상상태의 최소발화온도를 구하였으며, 시료를 용기에 충전했을 경우 용기의 크기가 클수록 발화한계 온도는 낮아졌으며 겉보기활성화에너지는 Frank-Kamenetskii의 열발화이론으로부터 계산하였고, 운상상태의 발화온도는 21%의 산소농도하에서 최소발화온도를 구하였으며, 산소농도 변화의 실험결과 산소농도 10%에서 발화되지 않았으며 한계산소농도를 구할 수 있었다.

• 한국안전학회지
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• 제14권2호
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• pp.90-96
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• 1999

The characteristics of spontaneous ignition of painting waste was investigated at constant ambient temperature in oven. As the results of experiments, the spontaneous ignition temperature decreased as the sample vessel became large, and the spontaneous ignition temperature of the sample in small, intermediate and large vessels was $165.5^{\circ}C$, $144.5^{\circ}C$ and $134.5^{\circ}C$ respectively. The apparent activation energy calculated by the Frank-Kamentskii's thermal ignition theory was 34.73 kcal/mol.

• 한국안전학회지
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• 제7권1호
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• pp.47-56
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• 1992

Spontaneous ignition charactenstics for fish meal were observed by performing experiments at constant ambient temperature and varying the ambient temperature sinusoidally. As the results of the experiments at a constant ambient temperature, the critical spontaneous ignition temperature of the sample for large, intermediate and small vessels was 170.5$^{\circ}C$, 177.5$^{\circ}C$ and 188.5$^{\circ}C$, respectively. The critical spontaneous ignition temperature decreased as the sample vessel size increased. Apparent activation energy of used fish meal calculated from the Frank-Kamenetskii's thermal ignition theory was 37.60Kcal/mol. In case of varying the ambient temperature sinusoidally, the amplitudes of temperature were 1$0^{\circ}C$, 2$0^{\circ}C$ and 3$0^{\circ}C$ respectively with the period in each amplitude 1hr, 2hrs and 3hrs. The results showed that the critical spontaneous ignition temperatures at the varied amplitudes of temperature were lower than that at the constant anbient temperature and increased as the amplitude increased. At the same amplitude, the critical spontaneous ignition temperature increased with the period.

• 한국안전학회지
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• 제7권4호
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• pp.45-53
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• 1992

Sponataneous ignition characteristics for granulated activated carbon were observed by performing experiments at constant ambient temperature and varying the ambient temperature sinusoidally. In case of varying the ambient temperature sinusoidally, the amplitudes of temperature were 5$^{\circ}C$, 1$0^{\circ}C$ and 15$^{\circ}C$ respectively, and the period in each amplitude was varied at an interval of 30minutes from zero to 3hours. As the results of experiments at a constant ambient temperature, the critical spontaneous ignition temperature of the sample decreased as the sample vessel size increased. Apparent activation energy of the sample calculated from the Frank-Kamenetskii's thermal Ignition theory was 38.82［kca1/mo1］ In case of varying the ambient temperature sinusoidally, the critical spontaneous ignition tempera-ture was lower than that at the constant ambient temperature, and the minimum critical spontaneous ignition temperature decreased with the amplitude of heating sinusoidal curve. At the same amplitude, the critical spontaneous ignition temperature decreased until it reached the minimum point and then in-creased as the period increased.

• 한국안전학회지
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• 제6권4호
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• pp.66-72
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• 1991

Spontaneous ignition characteristics were observed by performing experiments for granulated activated carbon at constant ambient temperature in an oven. As the results of the experiments, the critical spontaneous ignition temperature of sample for large, intermediate and small vessels was 158.5$^{\circ}C$ , 165.5$^{\circ}C$ and 174.5$^{\circ}C$, respectively. It was found that the critical spontaneous ignition temperature decreased and the ignition induction time increased as the sample vessel size increased. Apparent activation energy of the sample calculated from the Frank= kamenetskii's thermal ignition theory was 17.81＊10$^3$J/mol.

• 에너지공학
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• 제20권4호
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• pp.346-352
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• 2011

본 연구의 목적은 한국화력발전소에서 사용되는 석탄의 촤 산화반응율을 연구하는 것이다. 석탄촤 산화반응율은 입자의 점화온도에 근거한 Semenov의 열착화이론을 활용하여 도출하였다. 석탄촤의 입자를 열전대를 통해 직접 가열 및 온도 측정을 할 수 있으며, 광각기 센서를 통해 석탄촤점화시 발생되는 빛의 강도를 계측함으로써 점화시점을 결정 할 수 있는 실험장치를 제안 하였다. 아역청탄인 Wira와 역청탄인 Yakutugol의 석탄촤 점화온도는 입자 직경의 변화에 따라 측정을했으며, 입자의 직경이 커질수록 석탄촤 점화온도는 상승하였다. 입자 직경에 따른 석탄촤 점화온도의 결과를 통해 활성화에너지 및 빈도인자를 도출하였다. 본 연구를 통해 도출한 석탄촤 산화반응율 값을 기존의 연구 데이터와 비교한 결과 유사함도 확인할 수 있었다.