• 제목/요약/키워드: Thermal soaking

검색결과 47건 처리시간 0.024초

Y-TZP/Ce-TZP 구조세라믹스의 제조 및 특성연구 (Fabrication and Characteristics of Y-TZP/Ce-TZP Structural Ceramics)

  • 이종현;이윤복;김영우;오기동;박흥채
    • 한국세라믹학회지
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    • 제33권10호
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    • pp.1177-1185
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    • 1996
  • Y-TZP/Ce-TZP ceramics having relative sintered densities of>95% average grain sizes of 0.36$\mu\textrm{m}$ microhar-dness of 1150 kg/mm2 fracture strength of 390-830 MPa and toughness of 6.4-10.2 MPa$.$mm1/2 were prepared by conventional sintering of 3 mol% Y2O3-ZrO2 and 12 mol% CeO2-ZrO2 powders at 1400 and 1500$^{\circ}C$ The average grain sizes of Y-TZP/Ce-TZP ceramics were mainly governed by those of Ce-TZP. White increasing Ce-TZP content toughness increased while microhardness and fracture strength decreased. With comparing microhardness and toughness fracture strength was more sensitive on not only grain size but also other factors such as microstructural and compositional variations. The densification of Y-TZP/Ce-TZP cermaics was not greatly affected by composition and soaking time at temperature over 1400$^{\circ}C$ With increasing CE-TZP content the stability of t-ZrO2 decreased under thermal aging in air whereas increased in hydrothermal atmosphere and aqueous solution.

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Fabrication of ZnO and CuO Nanostructures on Cellulose Papers

  • Nagaraju, Goli;Ko, Yeong Hwan;Yu, Jae Su
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
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    • pp.315.1-315.1
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    • 2014
  • The use of cellulose papers has recently attracted much attention in various device applications owing to their natural advantageous properties of earth's abundance, bio-friendly, large-scale production, and flexibility. Conventional metal oxides with novel structures of nanorods, nanospindles, nanowires and nanobelts are being developed for emerging electronic and chemical sensing applications. In this work, both ZnO (n-type) nanorod arrays (NRAs) and CuO (p-type) nanospindles (NSs) were synthesized on cellulose papers and the p-n junction property was investigated using the electrode of indium tin oxide coated polyethylene terephthalate film. To synthesize ZnO and CuO nanostructures on cellulose paper, a simple and facile hydrothermal method was utilized. First, the CuO NSs were synthesized on cellulose paper by a simple soaking process, yielding the well adhered CuO NSs on cellulose paper. After that, the ZnO NRAs were grown on CuO NSs/cellulose paper via a facile hydrothermal route. The as-grown ZnO/CuO NSs on cellulose paper exhibited good crystalline and optical properties. The fabricated p-n junction device showed the I-V characteristics with a rectifying behaviour.

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탄소나노튜브와 그래핀 강화 하이브리드 알루미나 복합재료의 재료특성 및 마이크로방전가공 성능 (Material properties and machining performance of CNT and Graphene reinforced hybrid alumina composites for micro electrical discharge machining)

  • 성진우;김남경;강명창
    • 한국기계가공학회지
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    • 제12권6호
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    • pp.3-9
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    • 2013
  • Aluminum Oxide($Al_2O_3$) ceramics are excellent candidates for such applications due to their outstanding mechanical, thermal, and tribological properties. However, they are difficult to machine using conventional mechanical methods. Carbon fillers, such as carbon nanotubes(CNT) and graphene nanoplatelets(GNP)can be dispersed in a ceramic matrix to improve the mechanical and electrical properties. In this study, CNT and Graphene reinforced hybrid ceramic composites were fabricated using the spark plasma sintering method at a temperature of $1,500^{\circ}C$, pressure of 40 MPa, and soaking time of 10min. Besides this, the material properties such as microstructure, crystal structure, hardness, and electrical conductivity were analyzed using FE-SEM, XRD, Vickers, and the 4-point probe method. A micro machining test was carried out to compare the effects of the material properties and the machining performance for CNT and Graphene reinforced ceramic composites.

Computer Simulation of an Automotive Air-Conditioning in a Transient Mode

  • Oh, Sang-Han;Won, Sung-Pil
    • International Journal of Air-Conditioning and Refrigeration
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    • 제10권4호
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    • pp.220-228
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    • 2002
  • The cool-down performance after soaking is very important in an automotive air-conditioning system and is considered as a key design variable. Therefore, transient characteristics of each system component are essential to the preliminary design as well as steady-state performance. The objective of this study is to develop a computer simulation model and ostinato theoretically the transient performance of an automotive air-conditioning system. To do that, the mathematical modelling of each component, such as compressor, condenser, receiver/drier, expansion valve, and evaporator, is presented first of all. The basic balance equations about mass and energy are used in modelling. For detailed calculation, condenser and evaporator are divided into many sub-sections. Each sub-section is an elemental volume for modelling. In models of expansion valve and compressor, dynamic behaviors are not considered in this analysis, but the quasisteady state ones are just considered, such as the relation between mass flow rate and pressure drop in expansion device, polytropic process in compressor, etc. Also it is assumed that there are no heat loss and no pressure drop in discharge, liquid, and suction lines. The developed simulation model is validated by comparing with the laboratory test data of an automotive air-conditioning system. The overall time-tracing properties of each component agreed well with those of test data in this case.

자동차 에어컨 비정상과정 시뮬레이션 (Transient Simulation of an Automotive Air-Conditioning System)

  • 오상한;원성필
    • 설비공학논문집
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    • 제13권11호
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    • pp.1089-1096
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    • 2001
  • The cool-down performance after soaking is very important in an automotive air-conditioning system and is considered as the key design variable. Therefore, understanding of the overall transient characteristics of the system is essential to the preliminary design as well as steady-state characteristics. The objective of this study is to develop a computer simulation model and estimate theoretical1y the transient performance of an automotive air-conditioning system. To accomplish this, a mathematical modelling of each component, such as compressor, condenser, expansion valve, and evaporator, is presented first of all. For a detailed calculation, condenser and evaporator are divided into many subsections. Each sub-section is an elemental volume for modelling. In models of expansion valve and compressor, dynamic behaviors are not considered in an attempt to simplify the ana1ysis, but the quasi-static ones are just considered, such as the relation between mass flow rate and pressure drop in expansion device, polytropic process in compressor, etc. The developed simulation model is validated with a comparison to laboratory test data of an automotive air-conditioning system. The overall time-tracing properties of each component agreed fairly well wish those of test data in this case.

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글레이즈 컬러를 적용한 의치상 레진의 비커스 경도 평가 (Evaluation of the Vickers hardness on denture acrylic resins by glaze color)

  • 임용운
    • 대한치과기공학회지
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    • 제44권4호
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    • pp.111-117
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    • 2022
  • Purpose: This study was conducted to compare the Vickers hardness on the denture acrylic resins using the glaze color system. Methods: The specimens (20×2 mm) were prepared by mixing according to the manufacturer's protocols through thermal polymerization and self-polymerization. The surface roughness was measured using a testing machine after water-soaking for 48 hours. For the Vickers hardness measurement, the completed specimen was soaked in water for 48 hours and then applied at 200 gf for 30 seconds. Was the specimen immersed after being soaked in water for 48 hours at temperatures of 5℃ and 55℃, respectively, for 30 seconds for the thermos-cycling treatment, and it was carried out 5,000 times. Results: Surface roughness was higher in the more glazing group than in the control group. A significant difference was observed in all groups, except for the Retec Don 2000 and Luciton 199 groups (p<0.05). As a result of measuring the Vickers hardness, the treatment by glaze color showed slightly lower but the thermo-cycling treatment group appeared higher than control group in all. Conclusion: Therefore, the glaze color was found to affect the surface roughness and showed a significant difference. The surface glaze color showed a very high Vickers hardness after the thermo-cycling treatment, indicating that the surface-strengthening effect is greater in the oral environment.

열산화법에 의한 티타늄 임플란트의 인산칼슘 결정의 형성 능력 증진 (Improvement of Calcium Phosphate Forming Ability of Titanium Implant by Thermal Oxidation Method)

  • 황규석;안준형;이선옥;윤연흠;강보안;오정선;김상복
    • 한국세라믹학회지
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    • 제39권5호
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    • pp.460-466
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    • 2002
  • 티타늄 임플란트의 표면을 열산화법을 이용하여 티타늄의 표면 위에 생체활성을 갖는 $TiO_2$ 박막을 생성시켜 다양한 의료분야의 응용 가능성을 검토하였다. 시판되고 있는 순수한 티타늄 디스크를 세척 공정을 거친 후, 공기와 아르곤 분위기에서 500, 550, 600, 650, 700${\circ}C$의 온도로 10분간 각각 열산화 처리를 실시하였다. 열처리된 시편의 인산칼슘 결정의 형성 능력을 시험하기 위하여 36.5${\circ}C$의 Eagle's minimum essential medium 용액에서 15일 동안 침적시험을 행하였다. 침적하기 전과 후의 시편의 표면 형상과 표면 조성을 Field Emission-Scanning Electron Microscopy(FE-SEM)와 Energy Dispersive X-ray Spectrometry(EDS)로 각각 분석하였다. In vitro 시험에서 미세한 $TiO_2$ 결정이 생성된 박막의 표면에는 탄소가 함유된 인산칼슘 결정이 생성됨을 확인하였다.

Retort Pouch 쌀밥의 가열살균시(加熱殺菌時) 파우치 포장내(包裝內)의 진공도(眞空度)가 열전달(熱傳達) 및 물성(物性)에 미치는 영향(影響) (The Effect of the Levels of Package Vacuum on the Heat Penetration and Texture of Cooked Rice Packed in Retort Pouch during Thermal Process)

  • 최광수;김창식
    • 한국식품영양과학회지
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    • 제11권4호
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    • pp.17-24
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    • 1982
  • retort pouch 쌀밥 제조 시간을 단축시키고 가열살균 중의 진공도가 열전달 속도 및 물성에 미치는 영향을 조사하기 위하여 본 연구를 실시하였다. 쌀의 수침시 평형수분 함량에 도달하는 시간이 품종에 별로 관계 없이 실온$(24^{\circ}C)$에서는 $2.5{\sim}3$시간이고 증미를 실온에서 침지하여 약 60% 수분의 최적 쌀밥 수분함량에 도달하는 시간이 약 1시간이라는 것을 발견하였다. $111^{\circ}C$에서 49분간 살균했을때 고진공 포장에서의 Fo값은 3.16분이고 저진공포장 쌀밥의 2.90분으로써 고진공 포장에서의 살균값이 더 컸다. fh 값도 $111^{\circ}C$ 살균시 고진공포장은 8.5분(j값=1.08), 저진공포장에서는 12.9분(j값=1.18)로서 고진공포장이 열전달 속도가 빠르다는 것을 알았고 $121.1^{\circ}C$에서도 진공도의 영향은 같은 경향을 보였다. 고진공포장 쌀밥이stickiness/Hardness의 비율로 봐서는 우수하게 보였으나 저진공포장의 쌀밥보다 stickiness, adhesiveness가 현저히 증가하고 쌀알이 파괴되고 엉켜서 품질이 좋지 않았다.

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트리페닐아민을 이용한 염료감응형 태양전지 고효율 염료합성 (Highly Efficient and Stable Organic Photo-Sensitizers based on Triphenylamine with Multi-anchoring Chromophore for Dye-sensitized Solar Cells)

  • 양현식;정대영;정미란;김재홍
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2010년도 춘계학술대회 초록집
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    • pp.88.1-88.1
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    • 2010
  • Organic dyes, because of their many advantages, such as high molar extinction coefficients, convenience of customized molecular design for desired photophysical and photochemical properties, inexpensiveness with no transition metals contained, and environment-friendliness, are suitable as photosensitizers for the Dye-sensitized Solar Cell (DSSC). The efficiency of DSSC based on metal-free organic dyes is known to be much lower than that of Ru dyes generally, but a high solar energy-to-electricity conversion efficiency of up to 8% in full sunlight has been achieved by Ito et al. using an indoline dye. This result suggests that smartly designed and synthesized metal-free organic dyes are also highly competitive candidates for photosensitizers of DSSCs with their advantages mentioned above. Recently, the performance of DSSC based on metal-free organic dyes has been remarkably improved by several groups. We had reported the novel organic dye with double electron acceptor chromophore, which was a new strategy to design an efficient photosensitizer for DSSC. To verify the strategy, we synthesized organic dyes whose geometries, electronic structures and optical properties were derived from preceding density functional theory (DFT) and time-dependent density functional theory (TD-DFT) calculations. In this paper, we successfully synthesized the chromophore containing multi-acceptor push-pull system from triphenylamine with thiophene moieties as a bridge unit. Organic dyes with a single electron acceptor and double acceptor system were also synthesized for comparison purposes. The photovoltaic performances of these dyes were compared, and the recombination dark current curves and the incident photon-to-current (IPCE) efficiencies were also measured in order to characterize the effects of the multi-anchoring groups on the open-circuit voltage and the short-circuit current. In order to match specifications required for practical applications to be implemented outdoors, light soaking and thermal stability tests of these DSSCs, performed under $100mWcm^{-2}$ and $60^{\circ}C$ for 1000h.

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Production techniques to Improve the Quality of Steamed and Freeze-Dried Mature Silkworm Larval Powder

  • Ji, Sang-Deok;Son, Jong-Gon;Kim, Seong-wan;Kim, Nam-Suk;Kim, Kee-Young;Kweon, Hae-Yong;Seong, Gyu-Byeong;Koh, Young-Ho
    • International Journal of Industrial Entomology and Biomaterials
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    • 제34권2호
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    • pp.17-22
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    • 2017
  • Cooked mature silkworms have received increasing attention as a new source of income for sericultural farms. Quality improvement of these worms as the end-product requires prevention of the following: inclusion of unfertilized silkworm eggs, mixing with impurities, producing undercooked or overcooked mature larvae, and mixing spewed silk substance. Preventing unfertilized eggs and impurities and reducing undercooked or overcooked mature larvae can be achieved by sericultural farms. However, the prevention of spewed silk substance requires the development of new techniques. This study developed new techniques for optimum cold storage temperature, soaking, and hydro-thermal treatment to minimize the spewing of mature larvae prior to steaming: when larvae mature after 7 days on the $5^{th}$ instar, they should be soaked in water at room temperature of $25^{\circ}C$ immediately upon collection and stored at $8^{\circ}C$ for less than 3 days. They should be soaked in boiling water for approximately 10 s immediately before steaming to kill the larvae and cooked with steam. This method allows for the production of high-quality mature larvae without spewed silk substance. These new techniques will considerably improve the production of well-cooked quality mature larvae by minimizing silk substance spewed out from the larvae.