• Title/Summary/Keyword: Thermal restraint

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A Study on Supercooling Repression of TMA-Water Clathrate Compound II (TMA-물계 포접화합물의 과냉각 억제에 대한 연구 II)

  • Kim Chang-Oh;Kim Jin-Heung;Chung Nak-Kyu
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 2006.05a
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    • pp.317-324
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    • 2006
  • This study aims to find out cooling characteristics of TMA(Tri-Methyl-Amine, ($CH_{3})_{3}N$) 25wt%-clathrate compound with ethanol($CH_{3}CH_{2}OH$) such as supercooling, phase change temperature and specific heat. For this purpose, ethanol is added as per weight concentration and cooling experiment is performed at $-6{\sim}-8^{\circ}C$, cooling heat source temperature, and it leads the following result. (1) Phase change temperature is decreased due to freezing point depression phenomenon. Especially, it is minimized as $3.8^{\circ}C$ according to cooling source temperature in case that 0.5w% of ethanol is added. (2) If 0.5wt% of ethanol is added, average supercooling degree is $0.9^{\circ}C $ and minimum supercooling is $0.8,\;0.7^{\circ}C$ according to cooling heat source temperature. The restraint effect of supercooling is shown. (3) Specific heat shows tendency to decrease if ethanol is added. It is $3.013{\sim}3.048\;kJ/kgK$ according to cooling heat source temperature if 0.5wt% of ethanol is added. Phase change temperature higher than that of water and inhibitory effect against supercooling can be confirmed through experimental study on cooling characteristics of TMA 25wt%-water clathrate compound by adding additive, ethanol. This can lead to shorten refrigerator operation time of low temperature thermal storage system and improve COP of refrigerator and efficiency of overall system. Therefore energy can be saved and efficiency can be improved much more.

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Mechanical Properties of High-Early-Strength Concrete for Early Traffic Opening (조기교통개방 콘크리트의 강도특성)

  • Won, Jong-Pil;Kim, Hyun-Ho;Ahn, Tae-Song
    • International Journal of Highway Engineering
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    • v.3 no.2 s.8
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    • pp.123-130
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    • 2001
  • This study was performed to enhance mechanical properties of high-early-strength concrete using regulated-set cement for early traffic opening with various mixtures. Restraint of moisture and thermal movements of concrete pavement in actual field conditions, by external or internal restraining factors, generates tensile stresses which introduce microcracks and thus reduce the mechanical properties of concrete. Fiber reinforcement of concrete is an effective approch to the control of microcrack and crack development under tensile stresses. Three different types of regulated-set cement which recently have been used in Korea and two different types of fiber were adopted. Fibers were added and their mixtures are compared with plain high-early-strength concrete mixture. From the test results, fiber reinforced concrete was increased mechanical properties of high-early-strength concrete using regulated-set cement than the plain concrete.

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A Proposal of Autogenous Deformation and Self-induced Restrained Stress Test Using Thermal Analysis Results to Predict Early-Age Cracks of Externally Restrained Concrete Members (외부구속 콘크리트 부재의 초기균열 예측을 위해 온도해석 결과를 이용한 자가변형 및 구속응력 측정 실험의 제안)

  • Byun, Jong-Kwan;Kang, Won Ho;Kang, Jeong-Kil;Bae, Seong-Jae
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.38 no.1
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    • pp.1-10
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    • 2018
  • It is difficult to predict the early-age cracks of strain restrained concrete members due to environmentally sensitive parameters. A new method is proposed to predict the cracks by test of autogenous deformation and self-induced restrained stress of specimens which simulates early-age crack state by hydration heat of the'Wall-On-Foundation'members. For this purpose, thermal analysis of entire structure considering the environmental condition is performed at first, and the specimens are set up where hydration heat was electronically controlled according to the analysis results. By measuring free deformation and force to compensate the autogenous strain including relaxation, feasibility of cracks can be estimated. The proposed method can predict the occurrence of cracks better than the material test of the early age concrete which has large variance. The method of this study is particularly useful when it is used as a preliminary experiments to predict the crack more precisely before full-scale concrete placement in construction of large structures.