• Title/Summary/Keyword: Thermal regeneration

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Adsorption and Thermal Regeneration of Toluene and Benzene on the Fixed Bed Packed with Activated Carbon and Activated Carbon Fiber

  • Kim, Jong-Hwa;Oh, Ok-Kyun;Haam, Seung-Joo;Lee, Chang-Ha;Kim, Woo-Sik
    • Carbon letters
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    • v.2 no.1
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    • pp.44-54
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    • 2001
  • The characteristics of adsorption and desorption of benzene and toluene were investigated at a fixed bed packed with the activated carbon and activated carbon fiber. Through breakthrough experiments under various feed concentration conditions, it was found that the slope of mass transfer zone and the tailing in the breakthrough curves were different from the feed conditions due to different heats of adsorption. In hot nitrogen desorption, the regeneration time and mass transfer zone of the toluene desorption curve were longer than those of the benzene desorption curve because of the difference in adsorption affinity. With an increase in the regeneration temperature, the height of roll-up and the sharpness of desorption curves increased but the regeneration times decreased. The adsorption capacities of the activated carbon and activated carbon fiber after three-time thermal regenerations decreased about 25% and 37% for benzene and 18% and 25% for toluene, respectively. To investigate the effect of the regeneration temperature on the energetic efficiency, the characteristic desorption temperatures of toluene and benzene were investigated by calculating purge gas consumption and temperature.

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Numerical Study on the Effect of Changes of Geometric Shape of Diesel Particulate Filter on Light-Off Characteristics and Transient Thermal Behavior during Regeneration (디젤입자상물질필터의 기하학적 형상변화가 재생과정 중 활성화 특성 및 비정상 온도거동에 미치는 영향에 관한 수치적 연구)

  • Jeong, Soo-Jin;Lee, Sang-Jin;Kim, Woo-Seung;Lee, Chun-Beom
    • Transactions of the Korean Society of Automotive Engineers
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    • v.14 no.4
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    • pp.68-76
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    • 2006
  • The minimization of maximum DPF wall temperature and the fast Light-off during regeneration are the targets for the high durability of the DPF system and the high efficiency of regeneration. In order to predict transient thermal response of DPF, one-channel numerical modeling has been adopted. The effect of the ratio of length to diameter(L/D), cell density, the amount of soot loading on temporal thermal response and regeneration characteristics has been numerically investigated under two different running conditions: city driving mode and high speed mode. The results indicate that the maximum wall temperature of DPF increase with increasing 'L/D' in 'High speed mode'. For 'City driving mode', the maximum wall temperature decreases with increasing 'L/D' in the range of $'L/D{\geq}0.6'$. The maximum temperature decreases with increasing cell density because heat conduction and heat capacity are increased. It is also found that the effect of amount of soot loading on light-off time is negligible.

An Experimental Study on the Control of the Combustion Rate by Temperature Control of Gas Entrained into the Filter in Burner-Type Particulate Trap (버너방식 DPF 시스템에서 가스온도 제어를 통한 입자상물질 연소율제어의 실험적 검증)

  • Park, D. S.;Kim, J. U.;Cho, H.;Kim, E. S.
    • Transactions of the Korean Society of Automotive Engineers
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    • v.5 no.4
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    • pp.130-141
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    • 1997
  • Work on the reduction of particulate matter(PM) from a diesel vehicl has led to a new trp system and a control method to control the combustion rate of the PM filtrated in the trap, which was named as 'Active Exhaust Feeding Regeneration(AEFR) System' by its operation mechanism. Ceramic cordierite filter is a major component of the trap and susceptible to thermal shock. Therefore the system should be designed to reduce the peak temperature and temperature gradients in the trap ; these have been considered to be the main factors causing thermal shock of the filter during the regeneration. It uses the engine's exhaust gas partially for the regeneration of the ceramic filter. It controlled bypass flow rate of the engine's exhaust gas precisely to control the temperature of the gas entrained into the filter. Gas temperatures were measured inside filter, and the oxygen concentration at the outlet of the filter was also monitored during the regeneration to analyze the combustion process of the PM. The temperature distributions and temperature gradients in the filter during the regeneration varied widely according to the regeneration control schemes. Finally, this system shows relatively low peak temperature and temperature gradients in the filter during its regeneration. It is considered that this system uses a mew method to control the combustion rate of the PM, which is different from the methods used in the previous studies.

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The Effect of Flow Distribution on Transient Thermal Behaviour of CDPF during Regeneration (배기의 유속분포가 CDPF의 재생 시 비정상적 열적 거동에 미치는 영향)

  • Jeong, Soo-Jin;Lee, Jeom-Joo;Choi, Chang-Ho
    • Transactions of the Korean Society of Automotive Engineers
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    • v.17 no.2
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    • pp.10-19
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    • 2009
  • The working of diesel particulate filters(DPF) needs to periodically burn soot that has been accumulated during loading of the DPF. The prediction of the relation between an uniformity of gas velocity and soot regeneration efficiency with simulations helps to make design decisions and to shorten the development process. This work presents a comprehensive combined 'DOC+CDPF' model approach. All relevant behaviors of flow fluid are studied in a 3D model. The obtained flow fields in the front of DPF is used for 1D simulation for the prediction of the thermal behavior and regeneration efficiency of CDPF. Validation of the present simulation are performed for the axial and radial direction temperature profile and shows goods agreement with experimental data. The coupled simulation of 3D and 1D shows their impact on the overall regeneration efficiency. It is found that the flow non-uniformity may cause severe radial temperature gradient, resulting in degrading regeneration efficiency.

Mathematical analysis on thermal regeneration of ceramic monolith filter in diesel engine (CI기관에서 세라믹 모노리스 필터의 열재생에 관한 수학적 해석)

  • 강호인;조재명;한영출
    • Journal of the korean Society of Automotive Engineers
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    • v.14 no.6
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    • pp.60-66
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    • 1992
  • This study describes a theoretical analysis for the wall temperature of ceramic filter trap and pressures of inlet and outlet channel in the filter trap. In this study, the maximum wall temperature through filter trap length with time during the regeneration period showed a tendency moving from forward to backward. The pressure change of filter trap increased at the initial combustion but decreased with the combustion to be activated. So the pressure difference between initial and end regeneration at the inlet channel showed about 2kPa. The thermal regeneration period of this filter trap in the theoretical analysis showed about 200seconds in which the wall temperature was similar to the case of initial condition and the pressure showed about 1 kPa.

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Regeneration of Spent Carbon by a Novel Oxidative Thermal Process

  • 류건상;Shybender Kapila
    • Bulletin of the Korean Chemical Society
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    • v.18 no.8
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    • pp.811-814
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    • 1997
  • An oxidative thermal regeneration process was developed and evaluated for its potential applicability in several environmental areas. The feasibility of the process is affected strongly by the gradual carbon loss, energy consumption, physical changes of carbon, and effective destruction efficiency of adsorbed materials during the regeneration. The aim of the study is to determine the optimum conditions to maintain acceptable destruction efficiency for adsorbed organics, controlling oxidant flow rate. Prior to its applications, various preliminary tests were carried out to determine the effects of experimental parameters on the process. The tests performed were reaction temperature, carbon loss, surface area, surface structure, and adsorptive property. The results of these tests show that the parameters are dependent on oxidant flow rate, and suggest that the process is comparable and, in some ways, possibly superior to conventional regeneration techniques because the oxidative process is a single step and less energy intensive.

Effect of vacuum regeneration of activated carbon on volatile organic compound adsorption

  • Pak, Seo-Hyun;Jeon, Yong-Woo
    • Environmental Engineering Research
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    • v.22 no.2
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    • pp.169-174
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    • 2017
  • Vacuum swing adsorption (VSA) is a promising treatment method for volatile organic compounds (VOCs). This study focuses on a VSA process for regenerating activated carbon spent with VOCs, and then investigates its adsorption capacities. Toluene was selected as the test VOC molecule, and the VSA regeneration experiments results were compared to the thermal swing adsorption process. Cyclic adsorption-desorption experiments were performed using a lab-scale apparatus with commercial activated carbon (Samchully Co.). The VSA regeneration was performed in air (0.5 L/min) at 363.15 K and 13,332 Pa. The comparative results depicted that in terms of VSA regeneration, it was found that after the fifth regeneration, about a 90% regeneration ratio was maintained. These experiments thus confirm that the VSA regeneration process has good recovery while operating at low temperatures (363.15 K) and 13,332 Pa.

Research on the Performance of a Solar Air Conditioning System using a Liquid Desiccant in Summer (액체흡수제 이용 태양열 공조시스템의 하계 능력에 관한 연구)

  • Choi, K.H.;Yoon, J.I.;Kim, B.C.
    • Journal of the Korean Solar Energy Society
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    • v.22 no.2
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    • pp.33-38
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    • 2002
  • In order to find out whether solar air conditioning system could be applied to building or not, the performance and evaluation on thermal environment of the system suggested was done during summer. A solar model house was constructed to find out the performance and thermal environment evaluation when it actually operated outside. As a result, regeneration rate increased rapidly when LiCl solution temperature was over $50^{\circ}C$ and the regeneration rate was $13\sim15kg$ during 9 hours operation. Furthermore the dehumidification rate was 12kg at maximum during 10 hours operating of a dehumidifier and indoor temperature and relative humidity was $28.4^{\circ}C$ and 39.1% in average respectively. On evaluation of thermal environment during summer, PMV value was slightly high, but thermal sensation vote was 71% within the comfort zone.

Computational Simulation by One-Dimensional Regeneration Model of Wall-Flow Monolith Diesel Particulate Filter Trap (벽-유동(Wall-Flow) 모노리스(Monolith) 디젤 입자상물질 필터 트랩의 재생모델에 의한 수치 시뮬레이션)

  • Kim, G.H.;Park, J.K.
    • Transactions of the Korean Society of Automotive Engineers
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    • v.3 no.6
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    • pp.41-54
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    • 1995
  • A mathematical model for wall-flow monolith ceramic diesel particulate filter was developed in order to describe the processes which take place in the filter during regeneration. The major output of the model comprises ceramic wall temperature and regeneration time(soot reduction). Various numerical tests were performed to demonstrate how the gas oxygen concentration, flow rate and the initial particulate trap loading affect the regeneration time and peak trap temperature. The model is shown to b in reasonable agreement with the published experimental results. This model can be applied to predict the thermal shock failure due to high temperature during combustion regeneration process.

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Ambient CO2 Adsorption and Regeneration Performance of Zeolite and Activated Carbon (제올라이트와 활성탄을 이용한 대기 중 CO2 흡착 및 재생 특성)

  • Park, Il-Gun;Hong, Min-Sun;Kim, Byum-Seok;Kang, Ho-Geun
    • Journal of Korean Society of Environmental Engineers
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    • v.35 no.5
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    • pp.307-311
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    • 2013
  • Direct Air Capture (DAC) technology using reusable energy is a plausible process to capture $CO_2$ from non-point sources. In this paper, adsorption and desorption were repeatedly tested using low concentration $CO_2$. Three types of adsorbents were examined in cyclic $CO_2$ adsorption and thermal regeneration. Adsorption capacities of zeolite 5A, zeolite 13X and activated carbon were 21 mg/g, 12 mg/g and 6 mg/g, respectively. Zeolite 5A shows the highest adsorption capacities after cyclic thermal regeneration.