• Title/Summary/Keyword: Thermal phase transition

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The effect of thermal treatment of shape memory alloy with the kind of impurity (불순물의 종류에 따른 형상기억합금의 열처리효과)

  • Park, Sung-Kun;Yoo, Pyung-Kil;Jeen, Gwang-Soo;Kim, Ki-Wan
    • Journal of Sensor Science and Technology
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    • v.6 no.6
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    • pp.500-507
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    • 1997
  • For fine control of operating temperature of shape memory alloy, we investigated the effect of thermal teratment of shape memory alloy with the impurity kind. The martensitic transformation temperature in a Cu-17.25Zn-15Al and Cu-17.25Zn-15Al-1Ag/Fe was measured using electrical resistivity as a function of quenching temperature. Order-disorder phase transition temperatures in parent phase were measured and kind of transition were distinguised by DSC(differential scanning calorimeter) with heating rate variation. And structual changes were studied with XRD. For the Cu-17.25Zn-15Al shape memory alloy, the order-disorder phase transition temperature, $T_{B2}$ and $T_{L21}$ was 809K and 610K and for the Cu-17.25Zn-15Al-1Ag and Cu-17.25Zn-15Al-1Fe specimen $T_{B2}$ and $T_{L21}$ was 794K and 610K, and 803K and 613K, respectively. In all the specimens, quenching from near $T_{B2}$ leads to an increase in martensitic temperature, whereas quenching from near $T_{L21}$ leads to an decrease in martensitic temperature.

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Power upgrading of WWR-S research reactor using plate-type fuel elements part I: Steady-state thermal-hydraulic analysis (forced convection cooling mode)

  • Alyan, Adel;El-Koliel, Moustafa S.
    • Nuclear Engineering and Technology
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    • v.52 no.7
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    • pp.1417-1428
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    • 2020
  • The design of a nuclear reactor core requires basic thermal-hydraulic information concerning the heat transfer regime at which onset of nucleate boiling (ONB) will occur, the pressure drop and flow rate through the reactor core, the temperature and power distributions in the reactor core, the departure from nucleate boiling (DNB), the condition for onset of flow instability (OFI), in addition to, the critical velocity beyond which the fuel elements will collapse. These values depend on coolant velocity, fuel element geometry, inlet temperature, flow direction and water column above the top of the reactor core. Enough safety margins to ONB, DNB and OFI must-emphasized. A heat transfer package is used for calculating convection heat transfer coefficient in single phase turbulent, transition and laminar regimes. The main objective of this paper is to study the possibility of power upgrading of WWR-S research reactor from 2 to 10 MWth. This study presents a one-dimensional mathematical model (axial direction) for steady-state thermal-hydraulic design and analysis of the upgraded WWR-S reactor in which two types of plate fuel elements are employed. FOR-CONV computer program is developed for the needs of the power upgrading of WWR-S reactor up to 10 MWth.

Thermal instability during the melting process in an isothermally heated horizontal cylinder (등온가열 수평원관내 융해과정동안의 열적 불안정성)

  • Jeong, Jae-Dong;Yu, Ho-Seon;Lee, Jun-Sik
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.20 no.6
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    • pp.2046-2056
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    • 1996
  • The constrained melting inside an isothermally heated horizontal cylinder has been repeatedly investigated in many studies only for the moderate Rayleigh numbers. This study extends the range of Rayleigh numbers to systematically investigate the transition during melting processes, especially focusing on the complex multi-cellular flow pattern and thermal instability. The enthalpy-porosity formulation, with appropriate source terms to account for the phase change, is employed. For low Rayleigh numbers, initially developed single-cell base flow keeps the flow stable. For moderate Rayleigh numbers, even small disturbances in balance between thermal buoyance force and viscous force result in branched flow structure. For high Rayleight numbers, Benard type convection is found to develop within a narrow gap between thee wall and the unmelted solid. The marginal Rayleigh number and the corresponding wave number are in excellent agreement with those from linear stability theory.

Production of Alumina with High Purity (고순도 알루미나의 제조)

  • Song, Si Jeong;Lee, Man Seung
    • Resources Recycling
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    • v.28 no.1
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    • pp.15-22
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    • 2019
  • There are three hydrometallurgical methods by which pure alumina can be prepared, such as hydrolysis of aluminum alkoxides, thermal decomposition of ammonium alum and thermal cracking of ammonium aluminum carbonate (AACH). The effect of solution pH and temperature and the nature of the impurities on the phase transition and the purity of the alumina thus produced was investigated. Hydrolysis of aluminum alkoxides and thermal decomposition of ammonium alum produce ${\alpha}$ and ${\gamma}$ alumina, while only ${\alpha}$ alumina can be produced by thermal cracking of AACH.

Laminar Forced Convective Heat Transfer to Near-Critical Water in a Tube

  • Lee, Sang-Ho
    • Journal of Mechanical Science and Technology
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    • v.17 no.11
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    • pp.1756-1766
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    • 2003
  • Numerical modeling is carried out to investigate forced convective heat transfer to near-critical water in developing laminar flow through a circular tube. Due to large variations of thermo-physical properties such as density, specific heat, viscosity, and thermal conductivity near thermodynamic critical point, heat transfer characteristics show quite different behavior compared with pure forced convection. With flow acceleration along the tube unusual behavior of heat transfer coefficient and friction factor occurs when the fluid enthalpy passes through pseudocritical point of pressure in the tube. There is also a transition behavior from liquid-like phase to gas-like phase in the developing region. Numerical results with constant heat flux boundary conditions are obtained for reduced pressures from 1.09 to 1.99. Graphical results for velocity, temperature, and heat transfer coefficient with Stanton number are presented and analyzed.

Synthesis and characterization of visible light active photocatalytic $TiO_2$

  • Kim, Duk-Su;Park, Kyu-Sung;Kim, Il-Doo;Kim, Ho-Gi
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.07b
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    • pp.1116-1120
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    • 2002
  • Using thermal hydrolysis and hydrothermal treatment, photocatalytic $TiO_2$ powders were synthesized. During the synthesis, the addition of other transition metals such as iron, copper, etc., affected the photocatalytic capability of synthesized powders, and enabled the activation by visible light. To enhance photocatalytic capacity of gas phase decomposition, the rate-determining adsorption rate of pollutant gases were improved via surface modification of $TiO_2$ powders. The surface modifiers were implanted using mechanochemical synthesis of dopants and photocatalytic powders.

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Comparison between Water and N-Tetradecane as Insulation Materials through Modeling and Simulation of Heat Transfer in Packaging Box for Vaccine Shipping

  • Dao, Van-Duong;Jin, Ik-Kyu;Hur, Ho;Choi, Ho-Suk
    • Clean Technology
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    • v.22 no.1
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    • pp.45-52
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    • 2016
  • This study reports on the modeling and simulation of heat transfer in packaging boxes used for vaccine shipping. Both water and n-tetradecane are used as primary insulation materials inside a multi-slab system. The one-dimensional model, which is a spherical model using a radius equivalent to the rectangular geometry of container, is applied in this study. N-tetradecane with low thermal diffusivity and proper phase transition temperature exhibits higher heat transfer resistance during both heating and cooling processes compared to water. Thus, n-tetradecane is a better candidate as an insulating material for packaging containers for vaccine shipping. Furthermore, the developed method can also become a rapid and economic tool for screening appropriate phase change materials used as insulation materials with suitable properties in logistics applications.

A study of the effect of the temperature on the As Te Ge Si amorphous semiconductor (As Te Ge Si 무정형 반도체의 온도영향)

  • 박창엽
    • 전기의세계
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    • v.23 no.6
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    • pp.49-55
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    • 1974
  • Amorphous semiconductor from As 30 Te 48 Ge 10 Si 12 was prepared, and studied electron microscopy, X-ray analysis and resistivity measurement. It's resistivity is 1.56*10$^{6}$ .ohm.-cm when small ampule is used for preparing sample it is found that no phase separation has occurced by electron microscopy, and that phase transition temperature is 232.deg. C by differential Thermal Analysis. The specimen showed threshold switching that the low resistance state occur at critical electric field and the resistance recover at low applied field. Critical electric field of the switching is 10$^{5}$ V/cm at room temperature. Threshold voltage secreace exponentially with increasing ambient temperature and at that each voltage resistance of the switching device increase exponentially. According to the series resistance and applied vottage current slope on the V-I curve is varied. When applied voltage is decreased after switching, the resistance of the switching device is increased. By this result the origin of the switching is the Joule's heating.

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Raman spectroscopy of PLZT thin films prepared by Sol-Gel processing (Sol-Gel법으로 제작된 PLZT박막의 Raman 연구)

  • 방선웅;장낙원;박정흠;마석범;박창엽;최형욱
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1997.11a
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    • pp.52-55
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    • 1997
  • In this study, PLZT stock solutions were prepared by sol-gel processing to fabricate PLZT thin films. The stock solutions were spin-coated on ITO-glass and the film were annealed by rapid thermal annealing(RTA). The variation of tile crystallographic structure of the thin films and the phase transition with respect to it were observed using Raman spectra. Raman result showed that the band of spectra are broad as the amount of Zr substitution increased and specially, abrupt change occurs in the raman spectra upon crossing the tetragonal-rhombohedral phase boundry at 2/55/45 PLZT thin film. So, the fact that the crystallographic structure was transitted from tetragonal to rhombohedral structure was certified.

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Effect of La and Si Addition on Thermal Stabilization of Alumina (La 및 Si 첨가에 의한 알루미나의 열안정화 효과)

  • Lee, Chae-Hyun;Lim, Dae-Young;Kim, Jong-Ock;Seo, Doo-Won;Han, Moon-Hee
    • The Journal of Engineering Research
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    • v.3 no.1
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    • pp.215-222
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    • 1998
  • The effect of La and Si addition of the thermal stabilization of $\gamma-alumina$ powers have been studied. Reagent grade $La(NO_3)_3{\cdot}6H_2O$ and $Si(OC_2H_5)_4$ were used as starting materials. These additives were introduced by wet impregnation method. Both La and Si additives suppressed the sintering of alumina and were found to be good thermal stabilizers of $\gamma-alumina$. Especially, Si drastically suppressed the phase transition of alumina at high temperatures. The major mechanisms for the thermal stabilization of alumina were seemed to be new phase formation and retardation of surface diffusion by addition of La or Si into alumina matrix.

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