• Title/Summary/Keyword: Thermal evolution

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Properties and Synthesis of Porous Cordierite from Fly Ash (플라이 애쉬를 이용한 다공성 코디어라이트의 합성 및 특성)

  • Kim, Sung-Jin;Bang, Hee-Gon;Park, Sang-Yeup
    • Journal of the Korean Ceramic Society
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    • v.43 no.6 s.289
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    • pp.344-350
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    • 2006
  • Porous cordierite was synthesized by the mechano-chemical processing using fly ash. The phase evolution of cordierite was investigated as a function of processing variables such as milling time and sintering temperature. In this study, the phase transition path of cordierite from fly ash was followed by sapprine/spinel ${\to}$ mullite/spinel ${\to}{\alpha}$-cordierite. Porous cordierite fabricated after 32 h of milling time and sintering at $1150^{\circ}C$ showed relatively low thermal expansion coefficient ($2.5{\times}10^{-6}/^{\circ}C\;(25{\sim}1000^{\circ}C$)) and high porosity (75%).

Adsorption Characteristics of Furan, Thiophene, and Selenophene on Si(100) Surface

  • Park, Jinwoo;Lee, Han-Koo;Chung, J.W.;Hong, Suklyun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.202.2-202.2
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    • 2014
  • We have studied the bonding structures of five membered aromatic ring heterocyclic molecules, such as furan, thiophene, and selenophene, adsorbed on the Si(100) surface at room temperature with density functional theory. Additionally, we have investigated the evolution upon annealing of thiophene and selenophene molecules on the Si(100) surface by the core-level photoemission spectroscopy and near-edge X-ray absorption fine structure (NEXAFS). The core-level-spectra measured at different temperatures are consistently interpreted in terms of various adsorption structures suggested by theoretical calculations. In this study, we found the most suitable structures by theoretical and experimental results considering room temperature and mild thermal annealing.

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Wet Cleaning Process for Cobalt Salicide (코발트살리사이드를 위한 습식세정 공정)

  • 정성희;송오성
    • Journal of Surface Science and Engineering
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    • v.35 no.6
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    • pp.377-382
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    • 2002
  • We investigated the appropriate wet cleaning process for Co-Ti-Si compounds formed on top of cobalt disilicide made from Co/Ti deposition and two rapid thermal annealing (RTA). We employed three wet cleaning processes, WP1 ($H_2$SO$_4$ etchant), WP2 ($NH_4$OH etchant), and WP3 which execute sequentially WP1 and WP2 after the first RTA. All samples were cleaned with BOE etchant after the second RTA. We characterized the sheet resistance with process steps by a four-point probe, the microstructure evolution by a cross detail sectional transmission electron microscope, a Auger depth profiler, and a X-ray diffractometer (XRD). We confirmed WP3 wet cleaning process were the most suitable to remove CoTiSi layer selectively.

Thermal Annealing Effects on the Structural and Optical Properties of Sputtered TiO$_2$ Films (스퍼터링 TiO$_2$막의 구조 및 광학적 성질에 미치는 열처리 효과)

  • 박성진;이수일;오수기
    • Journal of Surface Science and Engineering
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    • v.30 no.1
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    • pp.63-68
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    • 1997
  • The effects of the post-deposition annealing on the structural optical properties of sputtered $TiO_2$ thin films were studied; annealing was carried out in air up to $1000^{\circ}C$ for different duration. The results of the X-ray diffraction and the raman spectroscopy showed the annealing-condition dependent structural transformation of $TiO_2$ films from the as-deposited amorphous phase to the anatase and rutil phases. The spectroscopic elliposometry was used to investigate the deposition-condition dependence of the as-deposted films optical constants and also the evolution of the optical constants correlated with the annealing-induced structural transformation.

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GENERAL PROPERTIES OF NEAR-CONTACT BINARIES (근접촉쌍성(NCBs)의 일반적 특성)

  • 오규동;김호일;강영운;이우백
    • Journal of Astronomy and Space Sciences
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    • v.17 no.2
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    • pp.151-162
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    • 2000
  • The general properties of the NCBs, divided into A and F types according to their spectral types, have been presented. The evolutionary status of the F type near-contact binaries are closer to that of the contact systems, i.e., W UMa type binaries, if it is assumed that the evolution of the NCBs is governed by the thermal relaxation oscillation theory. The mass-radius relation, mass-luminosity relation and H-R diagram of the NCBs provide that the A type NCBs suffer from more active mass transfer than F types. The components of the NCBs ar still in main-sequence like W UMa type stars and their two components lines parallel to the ZAMS.

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Microstructure Evolution of UFG Steel Weld by Hybrid and Laser Welding (하이브리드 용접과 레이저 용접에 의한 세립강 용접부의 미세조직변화에 관한 연구)

  • Dong, H.W.;Lee, M.Y.;Ahn, Y.S.
    • Journal of Power System Engineering
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    • v.14 no.3
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    • pp.58-63
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    • 2010
  • A laser beam welding and an electric arc welding were combined, and the positive points of each welding method are drawn such as high speed, low thermal load, deep penetration, and high productivity. The fiber laser-MIG conjugated welding. namely the hybrid welding has been studied mainly for the automation industry of a pipeline welding. In this study, the MIG welding was combined with a fiber laser welding to make up the hybrid welding. The weld shapes, microstructures and mechanical properties for weld zones after the hybrid welding or only fiber laser welding were investigated on the 700 MPa grade Ultra Fine Grained(UFG) high strength steel. The amount of acicular ferrite in weld metals and HAZ(heat affected zone) was observed larger after hybrid welding compared with after only laser welding. The Vickers hardness of the top area of the fusion zone after fiber laser welding was higher compared with after hybrid welding.

A Study on the Ageing Behavior of Cu-bearing HSLA steels by thermal analysis (열분석법에 의한 Cu를 함유한 HSLA강의 시효 거동에 관한 연구)

  • 박태원;심인옥;김영우;강정윤
    • Proceedings of the KWS Conference
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    • 1994.05a
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    • pp.44-47
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    • 1994
  • The ageing behavior of Cu-bearing HSLA steels was studied by using Differential scanning calorimetry(DSC), Transmission electron microscopy and hardness tester. Two heat evolution peaks were observed during DSC scans over the temperature range of 25~590$^{\circ}C$ at a heating rate of 5$^{\circ}C$/min. The peaks appeared in low (241∼319$^{\circ}C$ : HSLA-A, 224∼310$^{\circ}C$ : HSLA-B) and high temperature (514∼590$^{\circ}C$ : HSLA-A, 451∼558$^{\circ}C$ : HSLA-B) are attributed to the formation of coherent Cu-clusters and noncoherent $\varepsilon$-Cu phase, respectively. It was confirmed that as ageing proceeds, the coherent bcc Cu-clusters transform to noncoherent fcc $\varepsilon$-Cu phase. In the case of the ageing to peak hardness at 300$^{\circ}C$ and 400$^{\circ}C$, the coherent Cu-clusters contributed to the hardening. As ageing time and temperature increase over peak hardness, noncoherent $\varepsilon$-Cu are formed and hardness decreases.

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Atomic-scale investigation of Epitaxial Graphene Grown on 6H-SiC(0001) Using Scanning Tunneling Microscopy and Spectroscopy

  • Lee, Han-Gil;Choe, Jeong-Heon;Kim, Se-Hun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.125-125
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    • 2012
  • Graphene was epitaxially grown on a 6H-SiC(0001) substrate by thermal decomposition of SiC under ultrahigh vacuum conditions. Using scanning tunneling microscopy (STM), we monitored the evolution of the graphene growth as a function of the temperature. We found that the evaporation of Si occurred dominantly from the corner of the step rather than on the terrace. A carbon-rich $(6{\sqrt{3}}{\times}6{\sqrt{3}})R30^{\circ}$ layer, monolayer graphene, and bilayer graphene were identified by measuring the roughness, step height, and atomic structures. Defect structures such as nanotubes and scattering defects on the monolayer graphene are also discussed. Furthermore, we confirmed that the Dirac points (ED) of the monolayer and bilayer graphene were clearly resolved by scanning tunneling spectroscopy (STS).

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Numerical predictions of the time-dependent temperature field for the 7th Cardington compartment fire test

  • Lopes, Antonio M.G.;Vaz, Gilberto C.;Santiago, Aldina
    • Steel and Composite Structures
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    • v.5 no.6
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    • pp.421-441
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    • 2005
  • The present work reports on a numerical simulation of a compartment fire. The fire was modeled using a simplified approach, where combustion is simulated as a volumetric heat release. Computations were performed with the commercial code CFX 5.6. Radiation was modeled with a differential approximation (P1 model), while turbulence effects upon the mean gas flow were dealt with a SST turbulence model. Simulations were carried out using a transient approach, starting at the onset of ignition. Results are provided for the temperature field time evolution, thus allowing a direct comparison with the analytical and experimental data. The high spatial resolution available for the results proved to be of great utility for a more detailed analysis of the thermal impact on the steel structure.

Influence of flexural loading on chloride ingress in concrete subjected to cyclic drying-wetting condition

  • Ye, Hailong;Fu, Chuanqing;Jin, Nanguo;Jin, Xianyu
    • Computers and Concrete
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    • v.15 no.2
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    • pp.183-198
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    • 2015
  • Chloride ingress implies a complex interaction between physical and chemical process, in which heat, moisture and chloride ions transport through concrete cover. Meanwhile, reinforced concrete structure itself undergoes evolution due to variation in temperature, relative humidity and creep effects, which can potentially change the deformation and trigger some micro-cracks in concrete. In addition, all of these process show time-dependent performance with complex interaction between structures and environments. In the present work, a time-dependent behavior of chloride transport in reinforced concrete beam subjected to flexural load is proposed based on the well-known section fiber model. The strain state varies because of stress redistribution caused by the interaction between environment and structure, mainly dominated by thermal stresses and shrinkage stress and creep. Finally, in order to clear the influence of strain state on the chloride diffusivity, experiment test were carried out and a power function used to describe this influence is proposed.