• Journal of the Korea Concrete Institute
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• v.21 no.5
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• pp.557-563
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• 2009

This study is on the properties of inorganic porous calcium silicate material made from silica powder through the autoclaving curing, the results of this study should be utilized fundamental data for the development of noise reduction porous solid material using siliceous byproduct generated by various manufacture process. For the manufacture of autoclave curing specimen, various calcareous materials used and siliceous materials used silica powder. In this study, properties in density and compressive strength according to the change of W/B and C/S ratio, microscopy for the shape of pore, SEM and XRD for the examination of hydrate after autoclave curing are carried out respectively. The test results shown that the more slurry density decrease, the more W/B increase at the fresh state, this tendency shown similar to in hardened state. Among the specimens of C/S ratio, the compressive strength of C/S ratio of 0.85 gave the highest the compressive strength. In the results of XRD, tobermorite generated by autoclaving curing was created all of specimens regardless of C/S ratio. To ascertain pore structure, we compared with existing porous calcium silicate product(ALC, organic sound absorbing porous material). The results of microscope observation, pore structure of specimen of this study was similar to that of existing inorganic sound absorbing foam concrete. therefore, we could conformed a possibility of sound absorbing porous solid material on the basis of the results.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.17 no.6
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• pp.670-675
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• 2016

Both melting temperature and enthalpy of MBCA/DMTDA mixtures were measured as a function of DMTDA compositions using DSC. The thermal properties of polyurethane elastomer samples prepared with MBCA, DMTDA, and 40/60 MBCA/DMTDA mixture as curing agents were also observed using TGA. MBCA and DMTDA showed good miscibility over the entire composition range, exhibiting individual DSC melting peaks. Peak temperatures were non-linearly reduced as DMTDA concentrations increased, being approximately $60^{\circ}C$ in the case of the 40/60 MBCA/DMTDA mixture. Furthermore, melting enthalpy of the mixture was calculated as 3.8 J/g, which was only 4.3% compared to 87.3 J/g of MBCA. Based on these results, crystallization of the mixture was considered to occur very slowly, and the fluidic gel-state of the mixture was visually confirmed to be maintained over 5 days at room temperature. Thermal decomposition of polyurethane elastomer prepared with 40/60 MBCA/DMTDA curative started at about $190^{\circ}C$, which is similar to that observed for DMTDA, only except decomposition behavior over higher temperature of $400^{\circ}C$.

• Elastomers and Composites
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• v.46 no.2
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• pp.132-137
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• 2011

In the present investigation, thermal aging behavior of H-NBR/NBR blend with various H-NBR content was investigated. Mixture of dicumyl peroxide and sulfur were used as a curing agent. The influence of the thermal aging of the H-NBR/NBR blends on the solid state properties such as tensile strength, elongation at break, hardness and abrasion resistance was investigated. Tensile strength was increased with increasing H-NBR content, while abrasion resistance was decreased. Both elongation at break and hardness were not affected by the addition of H-NBR. The properties such as hardness, tensile strength and elongation at break of the aged samples were lower than unaged samples. However, the rate of deterioration of those properties was decreased by increasing the H-NBR content, which indicated that improved thermal aging behavior was obtained by the addition of H-NBR. Abrasion loss was increased with increasing aging time, but it became less by the addition of H-NBR addition.

• Journal of the Microelectronics and Packaging Society
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• v.12 no.1 s.34
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• pp.9-16
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• 2005

This paper presents the development of new anisotropic conductive adhesives with enhanced thermal conductivity for the wide use of adhesive flip chip technology with improved reliability under high current density condition. The continuing downscaling of structural profiles and increase in inter-connection density in flip chip packaging using ACAs has given rise to reliability problem under high current density. In detail, as the bump size is reduced, the current density through bump is also increased. This increased current density also causes new failure mechanism such as interface degradation due to inter-metallic compound formation and adhesive swelling due to high current stressing, especially in high current density interconnection, in which high junction temperature enhances such failure mechanism. Therefore, it is necessary for the ACA to become thermal transfer medium to improve the lifetime of ACA flip chip joint under high current stressing condition. We developed thermally conductive ACA of 0.63 W/m$\cdot$K thermal conductivity using the formulation incorporating $5 {\mu}m$ Ni and $0.2{\mu}m$ SiC-filled epoxy-bated binder system to achieve acceptable viscosity, curing property, and other thermo-mechanical properties such as low CTE and high modulus. The current carrying capability of ACA flip chip joints was improved up to 6.7 A by use of thermally conductive ACA compared to conventional ACA. Electrical reliability of thermally conductive ACA flip chip joint under current stressing condition was also improved showing stable electrical conductivity of flip chip joints. The high current carrying capability and improved electrical reliability of thermally conductive ACA flip chip joint under current stressing test is mainly due to the effective heat dissipation by thermally conductive adhesive around Au stud bumps/ACA/PCB pads structure.

• Journal of the Microelectronics and Packaging Society
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• v.13 no.3 s.40
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• pp.39-45
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• 2006

This study was investigated the thermal properties of underfill with various epoxy resins using thermal analysis methods such as differential scanning calorimetry (DSC), thermo gravimetry analysis (TGA), dynamic mechanical analysis (DMA) and thermo-mechanical analysis (TMA). And, the adhesion strength of the underfills/FR-4 substrate was evaluated. The glass transition temperature (Tg) of underfill which was composed the cycolaliphatic epoxy resin was lower than that of underfill which was not composed the cycolaliphatic epoxy resin. The thermal degradation of underfill was composed of two processes, which involved chemical reactions between the degrading polymer and oxygen from the air atmosphere. The coefficient of thermal expansion (CTE) of underfill which was composed the cycolaliphatic epoxy resin was higher than that of underfill which was not composed the cycolaliphatic epoxy resin. The excessive curing temperatures caused a weak boundary layer of epoxy resin, which resulted in a deterioration of mechanical properties in the epoxy resin and thus led to poor adhesion property between the underfill/FR-4 substrate.

• Bulletin of the Korean Chemical Society
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• v.30 no.10
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• pp.2227-2232
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• 2009

Novel polythiol materials of urethane lens series for plastic optical lens were synthesized from polyol materials via thioisouronium of thiourea with c-HCl in refluxing aqueous solution, in which polythiol material was carried out from hydrolysis of thioisouronium by ammonia water. Their structure properties were identified by EA, EI-MS, FT-IR, $^1H\;and\;^{13}C$ NMR spectroscopies and TGA. Their ophthalmic lenses as polythiourethane material were prepared by thermal curing to an injected glass mold using the evenly solutions of diisocyanates series (TDI, XDI, HDI or IPDI) with polythiols. Polythiourethane shows that the strong stretching mode for SH group of polythiol disappeared in FT-IR spectra after thermosetting polymerization. Thermal deformation starting temperature of ophthalmic lenses was determined by TMA. Ophthalmic lenses made from characteristic polythiol and diisocyanate series have transparency, colorless and good impact strength, in which thermal resistance and impact strength of ophthalmic lenses were influenced by diisocyanate series. Physical properties of ophthalmic lens have contrast thermal resistance with impact strength. The property of thermal resistance and impact strength for respective ophthalmic lenses was examined by TMA and drop ball test.

• Journal of the Korean Ceramic Society
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• v.49 no.6
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• pp.549-555
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• 2012

Silicon carbide(SiC) exhibits many unique properties, such as high strength, corrosion resistance, and high temperature stability. In this study, a SiC-fiber web was prepared from polycarbosilane(PCS) solution by employing the electrospinning process. Then, the SiC-fiber web was pyrolyzed at $1800^{\circ}C$ in argon atmosphere after it was subjected to a thermal curing. The SiC-fiber web (ground web)/phenolic resin (resol) composite was fabricated by hot pressing after mixing the SiC-fiber web and the phenolic resin. The SiC-fiber web composition was controlled by changing the fraction of filler (filler/binder = 9:1, 8:2, 7:3, 6:4, 5:5). Thermal conductivity measurement indicates that at the filler content of 60%, the thermal conductivity was highest, at 6.6 W/mK, due to the resulting structure formed by the filler and binder being closed-packed. Finally, the microstructure of the composites of SiC-fiber web/resin was investigated by FE-SEM, EDS, and XRD.

• Journal of the Korean Recycled Construction Resources Institute
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• v.8 no.4
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• pp.596-603
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• 2020

In this paper, an experimental study was conducted to investigate the applications of bottom ash, which is an industrial by-product obtained from thermal power plants. Bottom ash was used as fine aggregate in this study, and an experiment was conducted to determine the characteristics of the bottom ash aggregate. In addition, 25, 50, 75, and 100% contents of crushed (natural) fine aggregate were replaced with bottom ash aggregate to produce concrete mixture including bottom ash. Thereafter, test results of the unit weight, ultrasonic velocity, compressive strength, and thermal conductivity of bottom ash concrete were obtained. Moreover, the effect of the curing ages of 28 and 91 days on the material characteristics of bottom ash concrete were identified. Test results showed that bottom ash used as fine aggregate had pozzolanic reaction. Finally, based on the extensive experimental results, relationships between thermal conductivity and unit weight, ultrasonic velocity, and compressive strength was suggested.

• Journal of the Korean Chemical Society
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• v.47 no.3
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• pp.250-256
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• 2003

In this work, the effect of cationic initiator content on the electron-beam (EB) curing process of diglycidylether of bisphenol-A (DGEBA) resin was studied using near-infrared spectroscopy (NIRS), thermogravimetric analysis (TGA), and critical stress intensity factor $(K_{IC})$. Benzylquinoxalinium hexafluoroantimonate (BQH) were used as an initiator and its content was varied from 0.5 to 3 phr. NIRS measurements showed that the hydroxyl group of EB-cured epoxy resin was increased with increasing the BQH content. Thermal stability and $K_{IC}$ value of EB-cured epoxy resin were increased with increasing the BQH content but were decreased above 2 phr content. These results could be attributed to the decrease of the conversion and degree of crosslinking. In another word, the conversion and degree of crosslinking were restricted by the incomplete network structure from high reactivity at the BQH content above 2 phr, resulting in decreasings of thermal stability and $K_{IC}$.

• Journal of the Korea Concrete Institute
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• v.23 no.6
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• pp.773-780
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• 2011

In this study, thermal stress analysis are carried out considering material properties, curing condition, ambient temperature, and casting date of the mass concrete placed in bottom slab and side wall of the in-ground type LNG tank as a super massive structure. Also, based on the numerical results, cracking possibility is predicted and counter measures to prevent the cracking are proposed. For the tasks, two optimum mix proportions were selected. From the results of the thermal stress analysis, the through crack index of 1.2 was satisfied for separately caste concrete lots except for the bottom slab caste in 2 separate sequences. For the double caste bottom slab, it is necessary introduce counter measures such as pre-cooling prior to the site construction. Also, another crack preventive measure is to lower the initial casting temperature by $25^{\circ}C$ or less to satisfy 1.2 through crack index criterion. In the $1^{st}$ and $2^{nd}$ caste bottom slab, the surface crack index was over 1.2. Therefore, the surface cracks can be controlled by implementing the curing conditions proposed in this study. Since the side wall's surface crack index was over 1.0, it is safe to assume that the counter preventive measures can control width and number of cracks.