• 제목/요약/키워드: Thermal curing

검색결과 517건 처리시간 0.021초

1차측 재질에 따른 유도가열의 특성해석 (Thermal Characteristic Analysis Of Induction Heating Roll According to Primary Material)

  • 장석명;윤인기;이성호;이중호;박희창;박찬일
    • 대한전기학회:학술대회논문집
    • /
    • 대한전기학회 2001년도 하계학술대회 논문집 B
    • /
    • pp.736-738
    • /
    • 2001
  • Induction heating is utilized in a large and ever-increasing number of application. The most prominent of these are billet heating, heat treating, metals joining, and metal melting. In these day, heating roll, a kind of induction heating, is widely used in curing of coatings and fiber industry. In this paper, we analyzed thermal characteristic analysis of induction heating roll according to primary material. Using this analysis results, efficiency of induction heating roll could be improved.

  • PDF

Preparation of New Polyenaminonitriles Containing Cyclic and Methylene Units and Their Thermal Properties

  • Cho, Jeong-Hyun;Gong, Myoung-Seon
    • Macromolecular Research
    • /
    • 제8권5호
    • /
    • pp.209-214
    • /
    • 2000
  • Polyenaminonitriles containing cycloaliphatic and aliphatic units were prepared by interfacial or solution polymerization reaction of p-bis(1-chloro-2,2-dicyanovinyl) benzene (1) with 4-aminobenzyl-amine, 1-(2-aminoethyl)piperazine, 2-(aminomethyl)pyrrolidine and 4-(aminomethyl)piperidine. The chemical structure of the polymers was confirmed through a syntheses of the model compound. The resulting polymers possessed inherent viscosities of 0.29∼0.62 dL/g and they were easily soluble in polar aprotic solvents and common organic solvents. Thermal properties of the polymers such as curability and stability were studied by differential scanning calorimetry (DSC), thermogravimetric analysis (TGA) and infrared spectroscopy. The polymers exhibited a large exotherm in DSC analyses and underwent a curing reaction around 340-370$\^{C}$ to form insoluble materials. The polymers showed 70-80% residual weight at 600 $\^{C}$ under nitrogen.

  • PDF

Hexamethylenetetramine의 함량에 따른 마찰재의 마찰.마모 특성 (Friction and Wear Characteristics of Friction Material with the Content of Hexamethylenetetramine)

  • 김대균;장호;윤호규
    • Tribology and Lubricants
    • /
    • 제16권4호
    • /
    • pp.266-273
    • /
    • 2000
  • The friction characteristics of phenolic resin and model friction materials were investigated with the content of hexamethylenetetamine (HEXA). At 10 wt.% of HEXA, the phenolic resin and model friction materials showed the most stable friction coeffcient in constant temperature test at various test conditions because of its good thermal stability and proper curing reaction. It was found from constant interval test in mild condition that the friction coeffcients of friction materials cured with 10 wt.% of HEXA was the highest and stable values in the whole range of braking operations. However, at the severe condition in constant interval test, the friction coefficient of friction materials cured with 10 wt.% to of HEXA was lowered and as the number of braking operation increased, the values became stable. In order to obtain the thormal stable friction materials, the content of HEXA from 5 to 10 wt.% could be recommended.

기계기초 매스콘크리트의 균열제어를 위한 온도관리 (A Temperature Management of Mass Concrete for Crack Control in Machine Foundation)

  • 허택녕;이제방;손영현
    • 한국콘크리트학회:학술대회논문집
    • /
    • 한국콘크리트학회 1996년도 봄 학술발표회 논문집
    • /
    • pp.394-401
    • /
    • 1996
  • This paper persents the crack control of mass concrete in massive machine foundation. The dimension of the machine foundation is 52.6m$\times$14.4m$\times$8.5m. The one distinctive characteristic of mass concrete is thermal behavior. Since the cement-water reaction is exothermic by nature, the temperature rises inside the massive concrete structure. When the heat is not quickly dissipated, it can be quite high. Significant tensile stresses may develop from the volume change associated with the increase of decrease of temperature within the mass concrete structure. To avoid occurrence of harmful cracks due to hydration heat, special attention shall be given to the construction of mass cnocrete structures. The temperature control system of mass concrete is proposed in this paper. This system contains a discussion of materials and concrete mix proportioning, thermal analysis, curing method, temperature control, and measurement of hydration heat. As will be seen throughout the paper, the proposed temperature control system have a great effect on the temperature-related cracks on mass concrete structures.

  • PDF

Epoxidized soybean oil(ESO)의 합성 및 4 관능성 에폭시 수지/ESO 블렌드 시스템의 물성 (Synthesis of Epoxidized Soybean Oil (ESO) and its Blends with Tetrafunctional Epoxy Resins)

  • Lee, Jae-Rock;Jin, Fan-Long;Park, Soo-Jin
    • 한국복합재료학회:학술대회논문집
    • /
    • 한국복합재료학회 2003년도 춘계학술발표대회 논문집
    • /
    • pp.180-183
    • /
    • 2003
  • In this work. a potential inexpensive epoxy resin. epoxidized soybean oil (ESO) was synthesized and applied as a toughening agent for 4.4'-tetradiglycidyl diaminodiphenyl methane (TGDDM). The chemical structure of ESO was characterized by FT-IR, $^1H NMR, and ^{13}C NMR$ spectroscopy. The curing behaviors. thermal stabilities. fracture toughness. and flexural strength of TGDDM/ESO blend systems were investigated by using the dynamic DSC. thermogravimetric analysis (TGA). and flexural tests. The thermal stabilities of TGDDM/ESO blend systems were decreased with increasing ESO contents. whereas the critical stress intensity factor ($K_{IC}$) and flexural strength ($\sigma_f$) were increased with ESO contents up to 10 wt% ESO.

  • PDF

유기실리카와 나노기공형성 수지의 상용성 변화에 의한 나노기공의 구조 변화

  • 차국헌;최연승;김상율;진문영
    • 한국결정학회:학술대회논문집
    • /
    • 한국결정학회 2002년도 정기총회 및 추계학술연구발표회
    • /
    • pp.52-52
    • /
    • 2002
  • Recently, nanoporous low-k materials using porogen (pore generating material) template method have gained much attraction due to the feasible advantage of dielectric constant decrease with the increase of porogen content, which is burning out and making air void by thermal curing. In nanoporous thin films, further, control of pore size and its distribution is very important to retain suitable thermal, mechanical and electrical properties. In this study, nanoporous low-k films were prepared with MTMS-BTMSE copolymer and porogen. The effect of interaction of copolymer matrix and porogen on pore size and distribution was comparatively to investigate with molecular structure and end functional group. The characterization of nanoporous thin film prepared was also performed using various techniques including NMR, GPC, Ellipsometer, FE-SEM, TGA, and FT-IR.

  • PDF

동절기 단열갱폼의 발열량 변화 측정에 관한 연구 (A Study on the Calorific Value of Insulated Gang-form in Winter)

  • 강인선;원준연;김태희;김성덕;최석;남경용
    • 한국건축시공학회:학술대회논문집
    • /
    • 한국건축시공학회 2017년도 추계 학술논문 발표대회
    • /
    • pp.135-136
    • /
    • 2017
  • This paper examines the efficiency of the application of conventional and insulated gang forms for curing and protection of concrete by comparing the amount of electric energy required therefor. In addition, a thermal vision camera was used to identify heat loss from surfaces of the gang forms after each placement of concrete. Experimental results, show that the heat loss at the submerged temperature was large at the submerged surface due to the large calorific value at the surface of the mold. The insulated gang form had some heat loss in the horizontal bars. In the case of adiabatic reforming, the pattern shows a constant calorific value over time. In conclusion, the insulation performance is better than that of general gang form.

  • PDF

Physical properties of mungbean starch/PVA bionanocomposites added nano-ZnS particles and its photocatalytic activity

  • Yun, Yeon-Hum;Kim, Eun-Sik;Shim, Wang-Geun;Yoon, Soon-Do
    • Journal of Industrial and Engineering Chemistry
    • /
    • 제68권
    • /
    • pp.57-68
    • /
    • 2018
  • The main objective of this study is to prepare the bionanocomposite films using mungbean starch (MBS), PVA, ZnS, and plasticizers, and to evaluate the physical properties, thermal stability, and photocatalytic activity. The bionanocomposite films were cross-linked by heat-curing process. The ZnS and bionanocomposite films were characterized by FT-IR, XRD, and SEM. The results indicated that the mechanical properties and water resistance enhanced up to 1.2-1.5 times by the addition of nano-ZnS particles, and the thermal stability was improved by the addition of nano-ZnS particles. The photocatalytic activity of the bionanocomposite films added nano-ZnS particles was examined using bisphenol A (BPA) and methyl orange (MO). In addition, the photodegradation efficiency of BPA and MO was evaluated using the pseudo-first order kinetic model (PFOK).

Preparation of Polyesters Containing Enaryloxynitrile Moiety and Their Thermal Properties

  • Moon Sung-Hee;Lee Seung-Jae;Kim Jin-Bong;Gong Myoung-Seon
    • Bulletin of the Korean Chemical Society
    • /
    • 제15권12호
    • /
    • pp.1089-1093
    • /
    • 1994
  • Polyesters containing enaryloxynitriles moiety have been newly prepared from p-bis[1-[4-(3-hydroxypropyl)phenoxy]-2,2-dicyano vinyl]benzene (3) and common diols with terephthaloyl chloride. The copolyesters have a good solubility in common organic solvents as well as polar aprotic solvents. They undergo a curing reaction at around 350 $^{circ}C$ and show a 50-60${\%}$ of residual weight at 500 $^{circ}C$. The enhanced thermal stabilities were due to the intramolecular cyclization or intermolecular cross-linking reaction of the dicyanovinyl group incorporated into polyester by copolymerization.

The Coating Performance of UV Curable Urethane Acrylate Coatings for Fancy Veneer Overlayed Plywood Flooring

  • Lee, Byoung-Hoo;Kim, Hyun-Joong;Lee, Young-Kyu
    • Journal of the Korean Wood Science and Technology
    • /
    • 제32권6호
    • /
    • pp.23-35
    • /
    • 2004
  • The goal of study was to investigate the influence of the acrylated urethane oligomer on mechanical properties, the chemical resistance and thermal resistance of the UV curable urethane acrylate coatings for fancy veneer overlayed plywood flooring. The pencil hardness and abrasion resistance of the coated fancy veneer overlayed plywood floorings increased with increasing the acrylate functionality of the acrylated urethane oligomer. In the case of the UV cured film containing hexa-functional acrylated aliphatic urethane oligomer, high discoloration of the coated fancy veneer overlayed plywood flooring was observed near the cracks at the beginning of the chemical treatment. In this study, it was found that the degradation of the UV cured film caused by an alkaline reagent was higher than that of the UV cured film caused by an acidic treatment.