• Title/Summary/Keyword: Thermal analysis characteristics

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Efficiency and Lifetime Improvement of Organic Light- Emitting Diodes with a Use of Lithium-Carbonate- Incorportated Cathode Structure

  • Mok, Rang-Kyun;Kim, Tae-Wan
    • Transactions on Electrical and Electronic Materials
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    • v.13 no.2
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    • pp.60-63
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    • 2012
  • Enhancement of efficiency and luminance of organic light-emitting diodes was investigated by the introduction of a lithium carbonate ($Li_2CO_3$) electron-injection layer. Electron-injection layer is used in organic light-emitting diodes to inject electrons efficiently between a cathode and an organic layer. A device structure of ITO/TPD (40 nm)/$Alq_3$ (60 nm)/$Li_2CO_3$ (x nm)/Al (100 nm) was manufactured by thermal evaporation, where the thickness of $Li_2CO_3$ layer was varied from 0 to 3.3 nm. Current density-luminance-voltage characteristics of the device were measured and analyzed. When the thickness of $Li_2CO_3$ layer is 0.7 nm, the current efficiency and luminance of the device at 8.0 V are improved by a factor of about 18 and 3,000 compared to the ones without the $Li_2CO_3$ layer, respectively. The enhancement of efficiency and luminance of the device with an insertion of $Li_2CO_3$ electron-injection layer is thought to be due to the lowering of an electron barrier height at the interface region between the cathode and the emissive layer. This is judged from an analysis of current density-voltage characteristics with a Fowler-Nordheim tunneling conduction mechanism model. In a study of lifetime of the device that depends on the thickness of $Li_2CO_3$ layer, the optimum thickness of $Li_2CO_3$ layer was obtained to be 1.1 nm. It is thought that an improvement in the lifetime is due to the prevention of moisture and oxygen by $Li_2CO_3$ layer. Thus, from the efficiency and lifetime of the device, we have obtained the optimum thickness of $Li_2CO_3$ layer to be about 1.0 nm.

Analysis of Prediction Results and Grid Size Dependence According to Changes in Fire Area (화원면적 변화에 따른 격자 크기 의존도 및 예측결과 분석)

  • Yun, Hong-Seok;Hwang, Cheol-Hong
    • Fire Science and Engineering
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    • v.33 no.6
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    • pp.9-19
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    • 2019
  • In fire simulations for building fire safety evaluation, changes in the fire area and grid size can significantly influence the prediction results. Therefore, the effects of area changes of the fire source with identical maximum heat release rates on the prediction results of a compartment fire were investigated. The dependence of the prediction results on the grid size using the identical fire area was also examined. No significant changes were observed in the thermal and chemical characteristics of the fires with variable grid sizes, even though the fire area was changed when six or more grids were set based on the fire diameter. In addition, changes in the fire area caused significant differences in the prediction of major physical quantities associated with available safety egress time (ASET) within a compartment. However, the fire area changes did not considerably influence the overall fire characteristics outside the compartment after reaching a certain distance from the opening.

The Performance Characteristics of Anti-Surge Devices for High Head Cooling Water Systems in 1,000 MW Thermal Power plants (고수두 1,000 MW 석탄화력발전소 냉각수계통 수격방지장치의 성능특성)

  • Kim, Keun-Pil;Yoo, Hoseon
    • Plant Journal
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    • v.15 no.4
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    • pp.36-42
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    • 2019
  • In recent, according to the tightening of environment regulation policy, the height of the site of the power plant is increased and the length of the cooling water pipe is increased. This has a serious impact on the stability of the plant. This study analyzes the transient phenomenon using LIQT 7.2, an unsteady state one-dimensional analysis software, to secure the stability of 1,000 MW high-capacity coal-fired power plant cooling water system with high head. To prevent water hammer, The effects on performance characteristics were predicted by individual and combination application. The surge pressure of the cooling water which occurs when the pump was stopped without installing the anti-surge devices was the largest at the pump outlet side. The most effective and simple way to reduce surge pressure in these cooling water systems is to combine a vacuum breaker with a hydraulic non-return valve, which is an essential device for pump protection.

Floral Nectary-specific Gene NTR1 Encodes a Jasmonic Acid Carboxyl Methyltransferase

  • Seo, Hak Soo;Song, Jong Tae;Koo, Yeon Jong;Jung, Choonkyun;Yeu, Song Yion;Kim, Minkyun;Song, Sang Ik;Lee, Jong Seob;Hwang, Ingyu;Cheong, Jong-Joo;Choi, Yang Do
    • Journal of Applied Biological Chemistry
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    • v.44 no.3
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    • pp.119-124
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    • 2001
  • NTR1 gene of Brassica campestris L. ssp. perkinensis encodes a floral nectary-specific methyltransferase. In this study, the NTR1 cDNA was expressed in E. coli to examine the enzymatic characteristics of the protein product. The GST-NTR1 fusion protein was purified to near homogeneity, showing that the size of NTR1 was 44 kDa. The protein reacted specifically with jasmonic acid (JA), consuming methyl group from S-adenosyl-L-methionine (SAM). GC-MS analysis revealed that the compound produced was authentic methyl jasmonate (MeJA), suggesting that NTR1 is an S-adenosyl-L-methionine: jasmonic acid carboxyl methyltransferase. Km values of NTR1 for JA and SAM were 38.0 and $6.4{\mu}M$, respectively. Optimal activity of the NTR1 was observed at $20^{\circ}C$, pH 7.5, in the presence of 100-150 mM KCl. Thus, kinetic properties, thermal characteristics, optimal pH, and ion-dependency of the NTR1 activity were almost identical to those of Arabidopsis JA methyltransferase JMT, indicating that these two proteins are orthologues of each other.

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Pyrolysis Characteristics of Compressed Municipal Solid Wastes (압축한 도시고형폐기물의 열분해 특성)

  • Kim, Jin-Ho;Shon, Byung-Hyun;Cho, Sang-Won;Lee, Hyup-Hee;Oh, Kwang-Joong
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.5
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    • pp.907-918
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    • 2000
  • The pyrolysis characteristics of celluloses and plastics, which are the principal materials contributing to the municipal solid wastes(MSWs), was investigated with a thermal gravimetric analysis reaction system. The experiments were carried out in a nitrogen atmosphere in the temperature range of 400~900K at various experimental conditions. Also, a modified pyrolysis model for compressed MSWs has been proposed. Varing the heating rate to 20, 30, 40K/min, reaction orders of MSWs' main component were around 1.1~1.9, activation energies were 117~166kJ/mol for celluloses and 187~239kJ/mol for plastics. Char yield was proportional to the heating rate, particle size, and compressed ratio. The model proposed in this study, which is applying Arrhenius equation and thermodynamics, is closer to the experimental results than the conventional model.

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GaN Film Growth Characteristics Comparison in according to the Type of Buffer Layers on PSS (PSS 상 버퍼층 종류에 따른 GaN 박막 성장 특성 비교)

  • Lee, Chang-Min;Kang, Byung Hoon;Kim, Dae-Sik;Byun, Dongjin
    • Korean Journal of Materials Research
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    • v.24 no.12
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    • pp.645-651
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    • 2014
  • GaN is most commonly used to make LED elements. But, due to differences of the thermal expansion coefficient and lattice mismatch with sapphire, dislocations have occurred at about $109{\sim}1010/cm^2$. Generally, a low temperature GaN buffer layer is used between the GaN layer and the sapphire substrate in order to reduce the dislocation density and improve the characteristics of the thin film, and thus to increase the efficiency of the LED. Further, patterned sapphire substrate (PSS) are applied to improve the light extraction efficiency. In this experiment, using an AlN buffer layer on PSS in place of the GaN buffer layer that is used mainly to improve the properties of the GaN film, light extraction efficiency and overall properties of the thin film are improved at the same time. The AlN buffer layer was deposited by using a sputter and the AlN buffer layer thickness was determined to be 25 nm through XRD analysis after growing the GaN film at $1070^{\circ}C$ on the AlN buffer CPSS (C-plane Patterned Sapphire Substrate, AlN buffer 25 nm, 100 nm, 200 nm, 300 nm). The GaN film layer formed by applying a 2 step epitaxial lateral overgrowth (ELOG) process, and by changing temperatures ($1020{\sim}1070^{\circ}C$) and pressures (85~300 Torr). To confirm the surface morphology, we used SEM, AFM, and optical microscopy. To analyze the properties (dislocation density and crystallinity) of a thin film, we used HR-XRD and Cathodoluminescence.

Analysis of Radiative Characteristics at Urban Area by Observation in Summer Season (하절기 도시의 지역별 장.단파복사 특성 분석과 해석)

  • Jung, Im-Soo;Choi, Dong-Ho;Lee, Bu-Yong
    • Journal of the Korean Solar Energy Society
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    • v.31 no.3
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    • pp.133-144
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    • 2011
  • The objective of this study is to analyze the characteristic of radiation environment in the urban and rural through the field observation in the summer. The radiation balance was compared through the measurement of the shortwave radiation and long-wave radiation in the urban, sub-urban, and rural. The following conclusion could be obtained from this research. (1)In the results of observation including the rain-day, it was found that the short wave radiance in the urban is lower about 10% than the rural. (2)The upper part of atmosphere layers in the urban are aabsorb much short wave radiation energies compared with the rural relatively. It can increase the temperature of the upper part of atmosphere layers and the emittance of long wave radiation. (3)The ratio of the downward short wave radiation to the downward long wave radiation was 1.24 for the urban, 1.28 for sub-urban and 1.35 for rural. It can be estimated that the atmosphere condition of the rural is better than that of other areas. (4)The net radiation of the rural was lower that of the urban. It was found that the energy in and outflow of the rural is easier than that of the urban. (5)The temperature variation for the long-wave radiation change of the rural showed more sensitive than that of the urban. It was came from the radiation characteristics of the surrounding environment and can be used as the important index to evaluate the thermal environment characteristic of urban.

Dynamic Characteristics Analysis of the Cryogenic Nitrogen Injection of Swirl Injector using POD and DMD (POD와 DMD를 이용한 와류형 분사기의 극저온 질소 분무 동적 특성 분석)

  • Kang, Jeongseok;Sung, Hong-Gye;Sohn, Chae Hoon
    • Journal of the Korean Society of Propulsion Engineers
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    • v.21 no.5
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    • pp.1-9
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    • 2017
  • The cryogenic nitrogen spray of a swirl injector has been numerically investigated using three dimensional LES turbulence model to analyze the dynamic characteristics under supercritical condition. To predict the precise nitrogen properties under supercritical condition, SRK equation of state, Chung's method for viscosity and thermal conductivity and Takahashi's correlation based on Fuller's theory for diffusion coefficient are implemented. The complex flow structures due to interaction between flow field and acoustic field are observed inside and outside the injector under supercritical condition. FFT, POD, and DMD techniques are employed to understand the coherent structures. By implementing the FFT, the dominant frequencies are identified inside and outside the injector. The coherent flow structures related to the dominant frequencies are visualized using the POD and DMD techniques. In addition, the DMD provides the damping coefficient which is related with the instability prediction.

A Study on the Effect of Optical Characteristics in 2 inch LCD-BLU by Aspect Ratio of Optical Pattern : I. Optical Analysis and Design (휴대폰용 2인치 LCD-BLU의 광특성에 미치는 광학패턴 세장비의 영향 연구 : I. 광학 해석 및 설계)

  • Hwang, C.J.;Ko, Y.B.;Kim, J.S.;Yoon, K.H.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2006.05a
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    • pp.239-242
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    • 2006
  • LCD-BLU (Liquid Crystal Display - Back Light Unit) is one of kernel parts of LCD unit and it consists of several optical sheets(such as prism, diffuser and protector sheets), LGP (Light Guiding Plate), light source (CCFL or LED) and mold frame. The LGP of LCD-BLU is usually manufactured by forming numerous dots with $50{\sim}200$ um in diameter on it by etching process. But the surface of the etched dots of LGP is very rough due to the characteristics of the etching process during the mold fabrication, so that its light loss is high along with the dispersion of light into the surface. Accordingly, there is a limit in raising the luminance of LCD-BLU. In order to overcome the limit of current etched dot patterned LGP, optical pattern design with 50um micro-lens was applied in the present study. The micro-lens pattern fabricated by modified LiGA with thermal reflow process was applied to the optical design of LGP. The attention was paid to the effects of different aspect ratio (i.e. $0.2{\sim}0.5$) of optical pattern conditions to the brightness distribution of BLU with micro-lens patterned LGP. Finally, high aspect ratio micro-lens patterned LGP showed superior results to the one made by low aspect ratio in average luminance.

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Characteristics of Atmospheric Concentrations of Volatile Organic Compounds and Aldehydes for Near a Shipyard (조선소 주변지역에서 휘발성유기화합물 및 알데히드류의 농도분포 특성)

  • Park, Jeong-Ho;Suh, Jeong-Min;Han, Seong-Jong
    • Journal of Environmental Science International
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    • v.17 no.7
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    • pp.767-774
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    • 2008
  • This study was carried out to evaluate the characteristics of atmospheric concentrations of volatile organic compounds(VOCs) and aldehydes for near a large shipyard. Most of the painting work in marine coating is performed indoor and outdoor. Most of the VOCs are emitted to the atmosphere as the paint is applied and cures. The massive scale of a ship makes it difficult to capture the emissions from outdoor painting. The VOCs are an important health and contributors to photochemical smog. The VOCs and aldehydes samples were collected using adsorbent tube and 2,4-DNPH cartridge, and were determined by an automatic thermal desorption coupled with GC/MS and HPLC-UV analysis, respectively. A total of 16 aromatic VOCs and 12 aldehydes of environmental concern were determined. At indoor coating facilities, the most abundant compound among 16 target VOCs appeared to be m,p-xylene, being followed by o-xylene. But most of the aldehydes were extremely lower concentrations. The atmospheric concentration of VOCs, m,p-xylene concentrations were the highest and the mean value were outdoor workshop 11.323 ppb, residental area 5.134 ppb, and green area 2.137 ppb, respectively. However, the most aldehydes were extremely lower concentrations such as formaldehyde, acetaldehyde and non-detection such as iso-valeraldehyde, n-valeraldehyde and o-tolualdehyde.