• Title/Summary/Keyword: Thermal air treatment

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Development of a Sustainable Waste Paint Treatment Process for Waste Resource Recovery Improvement (폐기물 자원회수 향상을 위한 친환경 폐페인트 처리프로세스 개발)

  • Moon, Jongwook;Hwang, Suckho;Kim, Daeyoung
    • Korean Journal of Construction Engineering and Management
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    • v.23 no.1
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    • pp.73-82
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    • 2022
  • Waste paint, one of the specified wastes in Korea, is currently treated entirely by incineration treatment method, and is hardly recycled compared to other wastes. Incineration treatment method also causes environmental problems such as air pollution. Thus, this study breaks away from the existing incineration treatment method of waste paint and switch to a method of pretreatment operation through evaporation, condensation, and thermal decomposition by temperature control. and then proposes a sustainable waste paint treatment process that can be recycled as an alternative energy heat source. If a new method of disposing of waste paint and technology for recycling are developed and disseminated, it is expected that the effect will be large from an economic and environmental point of view.

Heat and mass transfer analysis in air gap membrane distillation process for desalination

  • Pangarkar, Bhausaheb L.;Sane, Mukund G.
    • Membrane and Water Treatment
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    • v.2 no.3
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    • pp.159-173
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    • 2011
  • The air gap membrane distillation (AGMD) process was applied for water desalination. The main objective of the present work was to study the heat and mass transfer mechanism of the process. The experiments were performed on a flat sheet module using aqueous NaCl solutions as a feed. The membrane employed was hydrophobic PTFE of pore size 0.22 ${\mu}m$. A mathematical model is proposed to evaluate the membrane mass transfer coefficient, thermal boundary layers' heat transfer coefficients, membrane / liquid interface temperatures and the temperature polarization coefficients. The mass transfer model was validated by the experimentally and fitted well with the combined Knudsen and molecular diffusion mechanism. The mass transfer coefficient increased with an increase in feed bulk temperature. The experimental parameters such as, feed temperature, 313 to 333 K, feed velocity, 0.8 to 1.8 m/s (turbulent flow region) were analyzed. The permeation fluxes increased with feed temperature and velocity. The effect of feed bulk temperature on the boundary layers' heat transfer coefficients was shown and fairly discussed. The temperature polarization coefficient increased with feed velocity and decreased with temperature. The values obtained were 0.56 to 0.82, indicating the effective heat transfer of the system. The fouling was observed during the 90 h experimental run in the application of natural ground water and seawater. The time dependent fouling resistance can be added in the total transport resistance.

Influence of Thermal Treatment on Surface Morphology of Tin Dioxide Thin Films (열처리에 따른 SnO2 박막의 표면형상)

  • Park, Kyung-Hee;Ryu, Hyun-Wook;Seo, Yong-Jin;Lee, Woo-Sun;Hong, Kwang-Jun;Park, Jin-Seong
    • Korean Journal of Materials Research
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    • v.13 no.7
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    • pp.442-446
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    • 2003
  • Tin dioxide ($SnO _2$) thin films were deposited at $375^{\circ}C$ on alumina substrate by metal-organic chemical vapor deposition. A few hillocks like a cauliflower were observed and the number of hillock on thin film surface increased with annealing temperature in air atmosphere. The oxygen content and the binding energy during air annealing at$ 500^{\circ}C$ came to close the stoichiometric $SnO_2$. The cauliflower hillocks seem to be the result of the continuous migration of the tiny grains to release the stress of an expanded grain. Sensitivity of CO gas depended on annealing temperature and increased with increasing annealing temperature.

Prediction of Heat-Up Time of the Glass Plate by IR Heaters in an LCD-Panel Cleaning Process (LCD 패널 세척공정에서 원적외선 히터에 의한 유리기판 승온시간 예측)

  • Kim, Yun-Ho;Ji, Tae-Ho;Kim, Seo-Young;Rhee, Gwang-Hoon
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.18 no.6
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    • pp.526-533
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    • 2006
  • The prediction of heat-up time of an LCD glass plate in LCD glass pre-treatment process has been implemented in the present study. Firstly, the analytical solution for one-dimensional radiation heat transfer from IR heaters to a LCD glass plate is obtained. When the surface temperature of the IR heaters is set at 473 K, the heat-up time of LCD glass to averaged temperature of 383K is 28 seconds. In addition, a three dimensional full CFD analysis using STAR-CD is implemented in an effort to consider the effect of 3-D heat loss through the furnace walls. From the results of the 3-D CFB analysis, the heat-up time increases up to 32.5 seconds under the same conditions. When the IR heater temperature in creases up to 573 K, the heat-up time decreases to 12 seconds for the one-dimensional analytical solution and to 13.5 seconds for the 3-D CFD analysis, respectively.

A Study on Heavy-Duty Diesel Engine Performance with a CR-DPF and Cooled-EGR (CR-DPF와 Cooled-EGR 적용한 대형디젤기관 성능에 관한 연구)

  • Moon, Byung-Chul;Oh, Yong-Suk;Oh, Sang-Ki;Kang, Kum-Won;Ahn, Kyun-Jae
    • Transactions of the Korean Society of Automotive Engineers
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    • v.14 no.3
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    • pp.75-80
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    • 2006
  • Since air pollution has become a globally critical issue and exhaust emissions from automobiles cause a major source of air pollution, many countries including advanced countries have stipulated stringent emission regulations. Particularly in diesel vehicles, NOx and particulate matters exhaust in significant amounts even though diesel vehicles provide merits in aspects of higher thermal efficiency and lower $CO_2$. To reduce Particulate matters and NOx, after-treatment technology such as filter trap, oxidation catalysts and EGR has been applied. This test was conducted on the effect of continuous regeneration diesel particulate filter and cooled-EGR, and 15ppm low sulfur diesel was used as a test fuel. Exhaust emissions, PM, NOx, CO, HC and Soots were measured and compared under D-13 and D-3 modes.

FUNDAMENTAL STUDY ON THE RECOVERY AND REMOVAL OF WHITE PHOSPHORUS FROM PHOSPHORUS SLUDGE

  • Jung, Joon-Oh
    • Environmental Engineering Research
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    • v.10 no.1
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    • pp.38-44
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    • 2005
  • Electro-thermal production of white phosphorus(WP, P4) generates substantial amount of highly toxic phossy water and sludges. Because of their high phosphorus contents and lack of reliable processing technology, large tonnages of these hazardous wastes have accumulated from current and past operations in the United States. In this study, two different methods for treatment of phosphorus sludge were investigated. These were bulk removal of WP by physical separation(froth flotation) and transformation of WP to oxyphosphorus compounds by air oxidation in the sludge medium. Kerosene, among other collectors, resulted in selective flotation of WP from the associated mineral gangue. Solvent action of kerosene occurring on the WP surface(by rendering WP particles hydrophobic) might produce the high selectivity of WP. The WP recovery in the froth was 79.3% from a sludge assaying 34.2% of WP. In the oxidation study, air gas was dispersed in the sludge medium by the rapid rotation of the impeller blades. The high level of sludge agitation intensity caused a fast completion of the oxidation reactions and it resulted in the high percentage conversion of WP to PO4-3 with PO3-3 making up almost all portion of oxyphosphorus compounds. The WP analysis on the treated sludge showed that supernatant solution and solid residue contained an average of 4.2 μg/L and 143 ppm respectively from the sludge containing about 26 g of WP. Further investigation will be required on operational factors to better understand the processes and achieve an optimum condition.

Electrocatalytic Performances of La0.6Ca0.4CoO3 and Pb2Ru2O6 prepared by Amorphous Citrate Precursor Method (Amorphous Citrate Precursor 법으로 제조한 La0.6Ca0.4CoO3와 Pb2Ru2O6의 전기화학적 촉매능)

  • Lee, Churl Kyoung;Sohn, Hun-Joon
    • Applied Chemistry for Engineering
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    • v.10 no.3
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    • pp.331-335
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    • 1999
  • The transition metal oxides have been of interest as bifunctional electrocatalysts for bifunctional air electrodes. The amorphous citrate precursor (ACP) process has been optimized to prepare perovskite (La0.6Ca0.4CoO3) and pyrochlore (Pb2Ru2O6) powders with high surface area, and consequent improvement of The electrocatalytic performance in an air electrode with thermal treatment. PTFE -bonded gas diffusion electrodes loaded with perovskitc and pyrochlore catalysts showed good bifunctional performances. The electrodes were fairly stable up to 100 hour in the galvanostatic mode at ${\pm}25mA/cm^2$, from which these electrodes offer promise as practical bifunctional air electrodes.

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Physiological Functionalities of Tea Thermally Processed from Ixeris dentata Root (열처리 가공조건에 따른 씀바귀 침출차의 생리활성)

  • Lee, Ka-Soon;Kim, Gwan-Hou;Kim, Hyun-Ho;Kim, Eun-Soo;Park, Hae-Min;Oh, Man-Jin
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.38 no.4
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    • pp.496-501
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    • 2009
  • This study was carried out to investigate physiological functionalities of tea prepared by various thermal processing methods from Ixeris dentata root in order to elevate utilization of Ixeris dentata root as food. These methods included natural drying (ND), hot-air drying (HAD, $75^{\circ}C$), hot-air drying after steam (HADS, steaming at $95^{\circ}C$ for 30 min) and roasting after hot-air drying (RHAD, roasting at $140^{\circ}C$ for $2{\sim}3$ min). Physiological functionalities of tea prepared by ND, HAD, HADS, and RHAD were measured as hot-water extracts and each tea was extracted by 100 mL water on 1 g dried Ixeris dentata root powder. Electron donating abilities were the highest in HADS treatment at 98%. SOD-like activities were the highest in RHAD at 35.61%. Both ACE and tyrosinase inhibitory activities were the highest on ND treatment at 52.34% and 44.60%, respectively. Nitrite scavenging abilities of all treatment were the highest at pH 1.2 and the highest activity among them was on RHAD treatment at 50.5%.

Preparation of Coal Tar Pitch as Carbon Fibers Precursor from Coal Tar (콜타르로부터 탄소섬유 제조를 위한 프리커서용 석탄계 핏치의 제조)

  • Ko, Hyo Joon;Park, Chang Uk;Cho, Hyo Hang;Yoo, Mi Jung;Kim, Myung-Soo;Lim, Yun-Soo
    • Korean Journal of Materials Research
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    • v.23 no.5
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    • pp.276-280
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    • 2013
  • Coal tar is the primary feedstock of premium graphitizable carbon precursor. Coal tars are residues formed as byproducts of thermal treatments of coal. Coal tar pitches were prepared through two different heat treatment schedules and their properties were characterized. One was prepared with argon and oxidation treatment with oxygen; the other was prepared with oxygen treatment at low temperature and then argon treatment at high temperature; both used coal tar to prepare coal tar pitches. To modulate the properties, different heat treatment temperatures ($300{\sim}400^{\circ}C$) were used for the coal tar pitches. The prepared coal tar pitches were investigated to determine several properties, such as softening point, C/H ratio, coke yield, and aromaticity index. The coal tar pitches were subject to considerable changes in chemical composition that arose due to polymerization after heat treatment. Coal tar pitch showed considerable increases in softening point, C/H ratio, coke yields, and aromaticity index compared to those characteristics for coal tar. The contents of gamma resin, which consists of low molecular weight compounds in the pitches and is insoluble in toluene, showed that the degree of polymerization in the pitches was proportional to C/H ratio. Using an oxidizing atmosphere like air to prepare the pitches from coal tar was an effective way to increase the aromaticity index at relatively low temperature.

Surface Modification by Atmospheric Pressure DBDs Plasma: Application to Electroless Ni Plating on ABS Plates

  • Song, Hoshik;Choi, Jin Moon;Kim, Tae Wan
    • Transactions on Electrical and Electronic Materials
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    • v.14 no.3
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    • pp.133-138
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    • 2013
  • Acrylonitrile-butadiene-styrene (ABS) plastic is a polymer material extensively used in electrical and electronic applications. Nickel (Ni) thin film was deposited on ABS by electroless plating, after its surface was treated and modified with atmospheric plasma generated by means of dielectric barrier discharges (DBDs) in air. The method in this study was developed as a pre-treatment for electroless plating using DBDs, and is a dry process featuring fewer processing steps and more environmentally friendliness than the chemical method. After ABS surfaces were modified, surface morphologies were observed using a scanning electron microscope (SEM) to check for any physical changes of the surfaces. Cross-sectional SEM images were taken to observe the binding characteristics between metallic films and ABS after metal plating. According to the SEM images, the depths of ABS by plasma are shallow compared to those modified by chemically treatment. The static contact angles were measured with deionized (DI) water droplets on the modified surfaces in order to observe for any changes in chemical activities and wettability. The surfaces modified by plasma showed smaller contact angles, and their modified states lasted longer than those modified by chemical etching. Adhesion strengths were measured using 3M tape (3M 810D standard) and by 90° peel-off tests. The peel-off test revealed the stronger adhesion of the Ni films on the plasma-modified surfaces than on the chemically modified surfaces. Thermal shock test was performed by changing the temperature drastically to see if any detachment of Ni film from ABS would occur due to the differences in thermal expansion coefficients between them. Only for the plasma-treated samples showed no separation of the Ni films from the ABS surfaces in tests. The adhesion strengths of metallic films on the ABS processed by the method developed in this study are better than those of the chemically processed films.