• 제목/요약/키워드: Thermal Transformation

검색결과 391건 처리시간 0.024초

Cu-Zr이원계 합금에서 화학조성 및 열싸이클링에 따른 마르텐사이트변태 특성의 열분석학적 연구 (A Calorimetric Study on the Martensitic Transformation Characteristics with Chemical Composition and Thermal Cycling in Cu-Zr Binary Alloys)

  • 장우양;;조민성;이재현;이영수;강조원;곽사호
    • 열처리공학회지
    • /
    • 제11권2호
    • /
    • pp.111-120
    • /
    • 1998
  • The effects of chemical composition and thermal cycling on the martensitic transformation characteristics in Cu-rich, equiatomic and Zr-rich CuZr binary alloys have been studied by calorimetry. Only martensite could be indentified in equiatomic $Cu_{49.9}Zr_{50.1}$ alloy, while $Cu_{10}Zr_7$ and $CuZr_2$ intermetallic compounds as well as martensite were formed by rapid cooling from the melts in Cu-rich $Cu_{52.2}Zr_{47.5}$ alloy and Zr-rich $Cu_{48.4}Zr_{51.6}$ alloy, respectively. The $M_s$ temperature of $Cu_{49.9}Zr_{50.1}$ was $156^{\circ}C$ but those of $Cu_{52.5}Zr_{47.5}$ and $Cu_{48.4}Zr_{51.6}$ alloys, being $109^{\circ}C$ and $138^{\circ}C$, were lower than that of equiatomic $Cu_{49.9}Zr_{50.1}$ alloy. In all the alloys, the $M_s$ temperature has fallen but the $A_s$ temperature has risen, resulting in widening of the transformation hysteresis with thermal cycling. The anomalous characteristics in the transformation temperature are due to the presence of the intermetallic compounds i.e. $Cu_{10}Zr_7$ and $CuZr_2$ formed by an eutectoid reaction during thermal cycling in the temperature range between $-100^{\circ}C$ < $T_c$ < $400^{\circ}C$.

  • PDF

퀜칭과정에서 상변태를 고려한 탄소성 열응력의 유한요소해석(I) -오스테나이트에서 퍼얼라이트로의 변태- (An Analysis Finite Element for Elasto-Plastic Stresses Considerating Phase Transformation at the Quenching Process(I) - From Austenite to Pearlite -)

  • 김옥삼;구본권
    • 열처리공학회지
    • /
    • 제7권4호
    • /
    • pp.233-243
    • /
    • 1994
  • Constitutive relation of thermoelasto-plastic material undergoing phase transformation during quenching process were developed on the basic of continuum thermodynamics. The metallic structure, temperature and residual stresses distributions were numerically calculated by the finite element technique. The metallic structure were defined by transformation from austenite to pearlite and characterized as a fuction of thermal history and mixture rule of phase. On the distribution of thermal stress along the radial direction, axial and tangential stresses are compressive in the surface, and tential in the inner part. Radial stress is tensile in the whole body. The reversion of residual stress takes plase at 11.5~15.5mm from the center.

  • PDF

9% Ni강의 GMA 및 SA 용접부 변형 예측 (A Study on the Prediction of the Welding Distortion for GMA and SA weldment of 9% Ni Steel)

  • 이희태;김하근;김경규
    • 대한용접접합학회:학술대회논문집
    • /
    • 대한용접접합학회 2005년도 추계학술발표대회 개요집
    • /
    • pp.26-28
    • /
    • 2005
  • The purpose of this study is to evaluate the behavior of the welding distortion of the 9% Ni steel weldment involving the martensitic phase transformation. In order to do it, an uncoupled thermal-mechanical finite element (FE) model was developed to evaluate the effect of the phase transformation on the distortion for the weldment. High speed quenching dilatometer tests were employed to define the variations of the coefficient of thermal expansion (CTE) with the fraction of the martensitic phase transformation, which strongly depends on the cooling speed after welding. Comprehensive experiments for the welding distortion of the weldment with reference to welding heat input were employed to verify the FE model.

  • PDF

Xonotlite의 가열변화 -규산칼슘 수화물의 가열성상에 관한 연구 (I)- (The Thermal Transformation of Xonotlite -Studies on the Thermal Transformation of Calcium Silicate Hydrates (I)-)

  • 이종근;한상목
    • 한국세라믹학회지
    • /
    • 제11권4호
    • /
    • pp.19-24
    • /
    • 1974
  • The study was investigated to confirm the morphology of crystal from xonotlite to wollastonite at elevated temperature by electron microscopy. Mixtures of slaked lime and powdered quartz with plenty water were oscillated continuously in an autoclave under the pressure of 25kg/$\textrm{cm}^2$ for 8 hours to obtain well crystallized xonotlite. This milky slurry consisting of xonotlite was gained and dried in oven at 11$0^{\circ}C$. Examination of the electron micrograhs showed the xonotlite to be developed thin lath-like crystals and to be formed aggregate as chestnut bur. Details of the morphology suggest that the heat-treated xonotlite up to 100$0^{\circ}C$ splited and deformed slightly in agreement with the topotaxial transformation theory of xonotlite to wollastonite. The molded material endured in good shape under 120$0^{\circ}C$ except a little shrinkage.

  • PDF

Tobermorite의 가열변화 -규산칼슘 수화물의 가열성상에 관한 연구(II)- (The Thermal Transformation of Tobermorite-Studies on The Thermal Transformation of Calcium Silicate Hydrates(II)-)

  • 이종근;최상흘;한상목
    • 한국세라믹학회지
    • /
    • 제11권4호
    • /
    • pp.25-30
    • /
    • 1974
  • The mixture of quartz powder and slaked lime with plenty water was oscillated in an autoclave and treated hydrothermally under the pressure of 10 kg/$\textrm{cm}^2$ for 8 hours. The main mineral synthesized was confirmed 11$\AA$ tobermorite by the method of X-ray diffraction and selected area electron diffraction. Tobermorite was heat-treated at 40$0^{\circ}C$, 80$0^{\circ}C$ and 100$0^{\circ}C$ for investigation of transformation of morphology and structure. Electron micrographs showed the thin platy structure of synthetic tobermorite with a little of crumpled foil or fibrous semi-crystalline calcium silicate hydrates. No difference in structure was appeared under the temperature of 80$0^{\circ}C$ but tobermorite converted gradually into wollastonite at 800$^{\circ}$~85$0^{\circ}C$. On heating, moulded material from tobermorite hardly shrinks under 80$0^{\circ}C$.

  • PDF

Ti-42.5at.%Ni-10at.%Cu합금의 형상기억특성에 관한 연구 (A Study on the Shape Memory Characteristic Behaviors of Ti-42.5at%Ni-10at.% Cu Alloys)

  • 우흥식;박용규
    • 한국안전학회지
    • /
    • 제24권1호
    • /
    • pp.26-30
    • /
    • 2009
  • Shape memory recoverable stress and strain of Ti-42.5at%Ni-10at%Cu alloys were measured by means of constant temperature tensile tests. The alloys' transformation behavior is B2 - B19 by DSC result. The strain by tensile stress were perfectly recovered by heating at any testing conditions but shape memory recoverable stress increased to 66MPa and then slightly decreased. Transformation temperatures from thermal cycling under constant uniaxial applied tensile loads linearly increased by increasing tensile load and their thermal hysteresis are about 110K and their maximum recoverable strain is 6.5% at 100MPa condition.

탄소강의 펄라이트 변태에 대한 유한요소 해석 (Finite Element Analysis for Pearlite Transformation of Carbon Steel)

  • 탄소강
    • 한국생산제조학회지
    • /
    • 제9권3호
    • /
    • pp.69-75
    • /
    • 2000
  • The object of the research is to estimate for pearlite structure of quenched carbon steels. The effects of temperature on physical properties metallic structures and the latent heat by phase transformation were considered. In this study a set of constitutive equations relevant to the analysis of thermo-elasto plastic materials with pearlite phase transformation during quenching process way presented on the basis of continuum thermo-dynamics. The iso-thermal transformation curve of the SM50C was formlated by cubic spline curve. The formulated equations of evolution in pearlite transformation was used for structure analysis. The volume fraction of pearlite was obtained from the results of calculated metallic structure by Finite element equation.

  • PDF

상변태를 고려한 베어링의 열처리 변형 해석 (Heat Treatment Deformation Analysis of Bearing Considering Phase Transformation)

  • 이승표;이석재;김태범;조균택
    • 열처리공학회지
    • /
    • 제36권6호
    • /
    • pp.351-358
    • /
    • 2023
  • Bearings are mechanical components that support loads and transmit rotation. The inner and outer rings come into contact with the rotating mechanism, requiring a very high level of hardness. To meet this requirement, heat treatment is commonly performed. The heat treatment process inherently involves thermal deformation. Particularly in the case of large bearings, significant deformation relative to the bearing's shape can occur, making accurate deformation prediction during heat treatment essential. However, predicting deformation in heat treatment is challenging due to the simultaneous consideration of phase transformation, heat transfer, and bearing deformation. In this study, an analysis of heat treatment-induced deformation in bearings was conducted, taking phase transformation into account. The thermal and mechanical properties were calculated based on the chemical composition of the bearing material. This information was then used to perform a deformation-heat transfer-phase transformation analysis. To validate the reliability of the analysis, experiments were conducted under the same conditions. When comparing the analysis and experimental results, differences in deformation were observed. These differences were attributed to variations in phase transformation conditions between the analysis and experiments. Consequently, it is anticipated that supplementing these results will enable the prediction of deformation while considering phase transformation conditions in bearings.