• Title/Summary/Keyword: Thermal Runaway

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Numerical Comparative Study on the Thermal Runaway of NCM/LFP Batteries of the Same Geometry (동일 형태의 NCM/LFP 배터리의 열폭주 현상에 대한 수치해석적 비교 연구)

  • Myung-Bo Gang;Woo-Young Kim;Nam-Jin Kim
    • Journal of the Korean Society for Geothermal and Hydrothermal Energy
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    • v.18 no.4
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    • pp.1-11
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    • 2022
  • In this study, the thermal runaway of NCM and LFP batteries were compared and analyzed through numerical analysis under various conditions. Comparing the thermal runaway of the NCM622 (18650) battery cell and the LFP (18650) battery cell through oven test simulation, the LFP battery did not show thermal runaway, whereas the NCM622 battery temperature increased to 710℃ in 12 minutes. To observe the thermal runaway and propagation of the prismatic LFP battery cell, the internal temperature was set at 200℃ and the oven test simulation was conducted. It was found that thermal runaway occurred at 391℃ after 47 minutes. As a result of observing thermal runaway propagation by placing five NCM622 and LFP battery cells, the thermal runaway propagation was clearly observed in the case of the NCM622 battery, but in the case of the LFP battery, thermal runaway was not observed after the first cell. From the third battery cell, it was confirmed that the temperature change was very insignificant, and through this, it is considered that the LFP battery is relatively safe compared to the NCM battery in terms of the thermal runaway propagation of the battery.

Battery thermal runaway cell detection using DBSCAN and statistical validation algorithms (DBSCAN과 통계적 검증 알고리즘을 사용한 배터리 열폭주 셀 탐지)

  • Jingeun Kim;Yourim Yoon
    • The Journal of the Convergence on Culture Technology
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    • v.9 no.5
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    • pp.569-582
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    • 2023
  • Lead-acid Battery is the oldest rechargeable battery system and has maintained its position in the rechargeable battery field. The battery causes thermal runaway for various reasons, which can lead to major accidents. Therefore, preventing thermal runaway is a key part of the battery management system. Recently, research is underway to categorize thermal runaway battery cells into machine learning. In this paper, we present a thermal runaway hazard cell detection and verification algorithm using DBSCAN and statistical method. An experiment was conducted to classify thermal runaway hazard cells using only the resistance values as measured by the Battery Management System (BMS). The results demonstrated the efficacy of the proposed algorithms in accurately classifying thermal runaway cells. Furthermore, the proposed algorithm was able to classify thermal runaway cells between thermal runaway hazard cells and cells containing noise. Additionally, the thermal runaway hazard cells were early detected through the optimization of DBSCAN parameters using a grid search approach.

Numerical analysis on thermal runaway by cathode active materials in lithium-ion batteries (리튬이온전지 열폭주에 대해 양극활물질이 미치는 영향에 대한 수치해석적 연구)

  • Gang, Myung-Bo;Kim, Nam-Jin
    • Journal of the Korean Society for Geothermal and Hydrothermal Energy
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    • v.17 no.2
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    • pp.1-10
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    • 2021
  • Lithium-ion batteries with high energy density, long cycle life and other advantages, have been widely used to energy storage systems(ESS). But as ESS fires frequently occur, the safety concern has become the main obstacle that hinders the large-scale applications of lithium-ion batteries. Especially, thermal runaway is the key scientific problem in battery safety research. Therefore, in this study, we performed a numerical analysis on the thermal runaway phenomenon of NCM111, NCM523 and NCM622 batteries using a two-dimensional analysis model. The results show that the two-dimensional simulation results are generally matched with three-dimensional simulation. Also, In the case of NCM111 with a low Ni content in the temperature range used in this study, thermal runaway phenomenon does occurred very slowly, but as the Ni content is increased, the thermal runaway phenomenon occurs rapidly and the thermal stability tends to be decreased. And, in NCM523 and NCM622 batteries, chain reactions occur almost simultaneously, but in the case of NCM111 battery, it is found that after the SEI(Solid Electrolyte Interface) layer decomposition reaction, the cathode-electrolyte reaction is appeared sequentially. After that, the anodic decomposition reaction is increased and leads to the thermal runaway reaction.

Characteristics Analysis of Measurement Variables for Detecting Anomaly Signs of Thermal Runaway in Lithium-Ion Batteries (리튬이온 배터리의 열폭주 이상징후 감지를 위한 측정 변수 특성 분석)

  • LIM, BYUNG-JU;CHO, SUNG-HOON;LEE, GA-RAM;CHOI, SEOK-MIN;PARK, CHANG-DAE
    • Transactions of the Korean hydrogen and new energy society
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    • v.33 no.1
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    • pp.85-94
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    • 2022
  • To detect anomaly signs of thermal runaway in advance, this study analyzed the signals from various sensors installed in lithium-ion batteries. The thermal runaway mechanism was analyzed, and measurement variables for anomalies of a battery cell were surface temperature, strain, and gas concentration. The changes and characteristics of three variables during the thermal runaway process were analyzed under the abuse environment: the overheat and the overcharge. In experiment, the thermal runaway of the battery proceeded in the initial developing stage, the outgassing stage, and the ignition stage. Analysis from the measured data indicated that the suitable variable to detect all stages of thermal runaway is the surface temperature of the battery, and surface strain is alternative.

A Study on the Effectively Improvement of Thermal Runaway Phenomenon by Optimal Resistor without RF Input Signal of SSPA (고출력 SSPA의 입력신호 차단시 최적화 게이트 저항 값에 따른 열폭주 현상의 개선에 관한 연구)

  • 황규일;이용민;나극환;신철재
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.10 no.6
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    • pp.910-916
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    • 1999
  • This paper presents the effective improvement of the thermal runaway phenomenon in high power SSPA when the RF input signal is not provided. The total gate resistors are optimized by the experiments and deducing the variation of velocity and currents of thermal runaway, which is based on manufacturer's recommendation. Especially, it is solved the complex thermal runaway that related gate resistors with the gate voltage variable circuit. The result of this paper is able to apply for improving the thermal runaway in existence of high power SSPA for WLL, cellular system and PCS repeater.

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Analysis of Effect of Surface Temperature Rise Rate of 72.5 Ah NCM Pouch-type Lithium-ion Battery on Thermal Runaway Trigger Time (72.5 Ah NCM계 파우치형 리튬이온배터리의 표면온도 상승률이 열폭주 발생시간에 미치는 영향 분석)

  • Lee, Heung-Su;Hong, Sung-Ho;Lee, Joon-Hyuk;Park, Moon Woo
    • Journal of the Korean Society of Safety
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    • v.36 no.5
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    • pp.1-9
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    • 2021
  • With the convergence of the information and communication technologies, a new age of technological civilization has arrived. This is the age of intelligent revolution, known as the 4th industrial revolution. The 4th industrial revolution is based on technological innovations, such as robots, big data analysis, artificial intelligence, and unmanned transportation facilities. This revolution would interconnect all the people, things, and economy, and hence will lead to the expansion of the industry. A high-density, high-capacity energy technology is required to maintain this interconnection. As a next-generation energy source, lithium-ion batteries are in the spotlight today. However, lithium-ion batteries can cause thermal runaway and fire because of electrical, thermal, and mechanical abuse. In this study, thermal runaway was induced in 72.5 Ah NCM pouch-type lithium-ion batteries because of thermal abuse. The surface of the pouch-type lithium-ion batteries was heated by the hot plate heating method, and the effect of the rate of increase in the surface temperature on the thermal runaway trigger time was analyzed using Minitab 19, a statistical analysis program. The correlation analysis results confirmed that there existed a strong negative relationship between each variable, while the regression analysis demonstrated that the thermal runaway trigger time of lithium-ion batteries can be predicted from the rate of increase in their surface temperature.

Protection of MOV Thermal Runaway and Safety Improvement of SPD using Built-in Instantaneous Trip Device (내장 순시 트립장치를 이용한 MOV의 열폭주 보호와 SPD의 안전성 개선)

  • Kim, Ju-Chul;Jeon, Joo-Sool;Ki, Che-Ouk;Choi, Gyung-Ray;Lee, Sang-Joong
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.25 no.2
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    • pp.120-125
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    • 2011
  • SPDs are increasingly being used against lightning and switching surge according to the applicable revised standard and equipotential grounding system. SPDs are equipped usually with a MOV voltage regulating element. The MOV, however, always is exposed to the danger of thermal runaway resulting from inrushing temporary overvoltage and deterioration. In this paper, the authors made two prototype SPDs built-in Instantaneous trip device and analyzed their limiting voltage through test of the MOV breakdown. As the result of the analysis, the SPDs built-in Instantaneous trip device was proven to be effective for protecting MOV against thermal runaway and Instantaneous trip device react for limiting voltage is considered that is applicable to SPD.

Hazard Evaluation of Runaway Reaction in the Vinyl Acetate Polymerization Process (비닐아세테이트 중합공정에서 폭주반응 위험성 평가)

  • Lee, Keun-Won;Han, In-Soo
    • Journal of the Korean Society of Safety
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    • v.26 no.5
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    • pp.46-53
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    • 2011
  • The risk assessment of thermal behavior and runaway reaction cased by an exothermic batch process in manufacture of the vinyl acetate resin are described in the present paper. The aim of the study was to evaluate the risk of runaway reaction with operating parameters such as a reaction inhibitor, reaction temperature and a mount of methanol charged in the vinyl acetate polymerization process. The experiments were performed by a sort of calorimetry with the Multimax reactor system as a screening tool to investigate runaway reaction. From the experimental results, it was found that we could occur the auto acceleration for reaction of raw materials with operating parameters over $65^{\circ}C$ of reaction temperature in the vinyl acetate polymerization process.

Numerical Study on Thermal Runaway by Temperatures and Appearance Sizes in NCM622 and LFP Cylindrical Lithium-ion Batteries (NCM622과 LFP 리튬이온 배터리의 주변 온도와 셀 크기에 따른 열폭주 현상에 대한 수치해석적 연구)

  • Kim, Woo-Young;Kim, Nam-Jin
    • Journal of the Korean Society for Geothermal and Hydrothermal Energy
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    • v.17 no.4
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    • pp.46-58
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    • 2021
  • As accidents with thermal runaway (TR) of lithium-ion batteries occur sporadically, the safety concern is the main obstacle that hinders the large-scale applications of lithium ion batteries. In most accidents, the TR of a single cell occurred first, and then dissipated the heat to the surroundings and triggered the TR of adjacent cells, resulting in TR propagation. Therefore, it is important to understand the mechanism of TR propagation and determine the key parameters during TR propagation in a battery pack. In this study, we performed a numerical analysis on the thermal runaway phenomenon by cathode active materials and appearance sizes in cylindrical lithium-ion batteries using a two-dimensional analysis model. The model results showed that the TR propagation of 21700 type cells (21 mm diameter, 70 mm height) occurs more rapidly than 46800 type cells (46 mm diameter, 80 mm height) and the LFP cell has higher thermal safety than the NCM cell. Especially, we found that the effect of the separator on the occurrence of TR is negligible.

A study on analysis of thermal and electrical parameters of the ZnO arrester block (배전용 ZnO 피뢰기 소자의 열적/전기적 파라미터 분석에 관한 연구)

  • Lee, Bok-Hee;Lee, Su-Bong;Lee, Seung-Ju;Jeon, Byung-Wook;Kim, Dong-Sung
    • Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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    • 2007.05a
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    • pp.353-356
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    • 2007
  • This paper presents the thermal and electrical characteristics of ZnO arrester blocks under the AC voltages. The leakage currents of ZnO arrester blocks were measured as a function of time. The temperature distributions of ZnO arrester blocks were observed by the forward looking infrared camera The degradation and thermal runaway of ZnO arrester blocks were closely related with the temperature limit of ZnO arrester blocks which decided heat generation and dissipation As a result, the degradation and thermal runaway of ZnO arrester blocks depend on the temperature and leakage current of ZnO arrester blocks.

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