• Journal of Korean Society for Atmospheric Environment
• /
• v.15 no.3
• /
• pp.249-255
• /
• 1999

We sdudied effect of additives on catalytic activity in thermal catalytic de-NOx process which was composed of thermal reduction, catalytic reduction and catalytic oxidation stage. Pd-Pt/${\gamma}$-$Al_2O_3$ catalysts with the addition of transition metals(Co, Cu, Fe, Ni, W, Zn, Zr) and rare earth metals(Ce, Sr) were prepared by the conventional washcoating method. Those catalysts were characterized by CO pulse chemisorption, ICP, $N_2$ adsorption, SEM and XRD. The effect of catalyst additives on NOx removal for diesel emission was studied in thermal catalytic de-NOx process at reduction temperature(350~50$0^{\circ}C$), space velocity(5,000~20,000 $hr^{-1}$) and the engine load(0~120kW). The concentraton of CO, $CO_2$, NO and $NO_2$ in the exhaust gas increased with the engine load. On the other hand the concentration of $O_2$ decreased. The de-NOx activityof all prepared catalysts increased with respect to high CO and low $O_2$ level in the thermal reduction stage of the process. Insertion of Ce to Pt-Pd/${\gamma}$-$Al_2O_3$ catalyst showed the best activity of all the catalysts under these experimental conditions. De-NOx catalysts are effective to remove CO in addition to NOx in the catalytic reduction stage.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.10 no.7
• /
• pp.1465-1472
• /
• 2009

The effect of heat loss rate on NOx formation of $CH_4/air$premixed flame were examined numerically in a perfectly stirred reactor. The following conclusions were drawn. Under the adiabatic wall condition, an increase in the residence time causes a remarkable increases in NOx emission. Under the heat loss conditions, however, NOx decreases significantly as the heat transfer coefficient and residence time increase. As the heat loss rate increases, Thermal NO mechanism and Re-burning NO mechanism play an important role in the NOx reduction, but Prompt NO mechanism and $N_2O$-intermediate NO mechanism lead to the increase in NOx production. Although the NOx formation is actually related to complex NOx mechanism with the changes in the heat transfer coefficient and residence time, it was found that NOx concentration can be represented by independent Thermal NO mechanism. From these results, new NOx correlation combined with the heat loss rate and residence time was suggested for predicting the NOx concentration in a practical $CH_4/air$premixed combustor.

• Journal of Advanced Marine Engineering and Technology
• /
• v.27 no.5
• /
• pp.657-665
• /
• 2003

Combined De-NOx Process in which $NH_3$ SCR (Selective Catalytic Reduction) and non-thermal Plasma Process are simultaneously used, has been investigated with a pilot test facility. The pilot test facility treats the combustion flue gases exhausted from a diesel engine that generates 240 kW of electrical power. Test results show that up to 80 % of NOx (NO and NO2) can be removed at 100 - $200^{\circ}C$. None of conventional De-NOx techniques works under such low temperature range. In addition to NOx. the Pilot test results show that soot can be simultaneously treated with the present non-thermal plasma technique. The present pilot test shows that the electrical power consumption to operate the non-thermal plasma reactor is equivalent to 3 - 4 % of the electrical power generated by the diesel engine.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.40 no.8
• /
• pp.503-510
• /
• 2016

Incinerators generally emit pollutants such as NOx and CO during the combustion process. In this paper, pollutant emissions and temperature distributions were studied in a simulated incinerator with a reversed (relative to the flue gas flow) secondary air injection system. The experiments were performed by using a lab-scale furnace in order to evaluate the effects of the injection location, direction and flow rate of secondary air jets. The emission of NOx was lower in the case of reversed secondary air injection than in the case of cross injection, due to the recirculation and mixing of the exhaust gas. In the reversed air injection cases, thermal NOx emissions decreased as secondary air ratio increased from 30 to 60 and slightly increased at secondary air ratios higher than 60. In most cases, CO emissions were not detected except for a few reversed secondary air injection cases, in which cases CO concentrations below 2ppm were observed.

• 한국연소학회:학술대회논문집
• /
• 2000.05a
• /
• pp.35-44
• /
• 2000

It was numerically studied that NOx emission characteristics of confined $CH_{4}$ jet flames with the variation of the diameter of inner fuel nozzle, the flow rate of $CH_{4}$ and equivalence ratio. Parabolic type equations were adopted in the calculation and GRI-2.1I mechanism was used for the chemical reaction. NOx emission index (EINOx) was introduced to evaluate NOx emission quantitatively in parametrically varied flames and the contribution of Thermal and Prompt NO mechanism was discussed. The results showed that Total EINOx varied sensitively with the variation of the flow rate of$CH_{4}$ but it was not sensitive to the variation of the diameter of inner fuel nozzle. Thermal EINOx showed the similar tendency to total EINOx and Prompt EINOx showed insensitivity to the variation of the diameter of inner fuel nozzle and the flow rate of $CH_{4}$.

• Applied Chemistry for Engineering
• /
• v.20 no.4
• /
• pp.437-442
• /
• 2009

In this work, thermal shock and simultaneous removal reaction for NOx, soot over Pt catalysts using $TiO_2$, $Al_2O_3$ as support were studied. The catalytic reaction test for NOx and soot were also performed independently and simultaneously, as a result, it showed different NOx removal efficiency and soot oxidation rate according to support and phase, and the onset temperature of soot oxidation has correlation to NOx removal efficiency for the catalyst. The onset temperature of soot oxidation shifted to lower temperature by generated $NO_2$ at the simultaneous reaction for NOx and soot. Also Pt/$TiO_2$ catalyst is more affected than Pt/$Al_2O_3$ on NOx removal efficiency caused by thermal shock while Pt sintering effect induced to reduce the performance on soot oxidation rate for all catalysts.

• 한국연소학회:학술대회논문집
• /
• 2001.06a
• /
• pp.147-155
• /
• 2001

The NOx emission characteristics of jet flames fueled with $H_2$ and $CH_4$ were studied. Experimental and numerical investigations were carried out for various flames with varying equivalence ratio, fuel flow rate and nozzle diameter. The Emission indices of NOx(EINOx) were measured by chemiluminescent method and calculated by simulation using detailed chemistry. The results show that EINOx of $CH_4$ and $H_2$ flames have different trends in terms of equivalence ratio and fuel flow rate but have the same trends in terms of nozzle diameter. These differences can be explained by the following Thermal and Prompt trends in both flames. Thermal EINOx trends can be describe in function of residence time in the high-temperature region weighted by the maximum flame temperature and Prompt EINOx trends can be described in function of flame surface area of each combustion conditions.

• Journal of the Korean Society of Combustion
• /
• v.6 no.1
• /
• pp.36-43
• /
• 2001

The NOx emission characteristics of jet flames fueled with $H_2\;and\;CH_4$ were studied. Experimental and numerical investigations were carried out for various flames with varying equivalence ratio, fuel flow rate and nozzle diameter. The Emission indices of NOx(EINOx) were measured by chemiluminescent method and calculated by numerical model based on detailed chemistry. The results show that EINOx of $CH_4\;and\;H_2$ flames have different trends in terms of equivalence ratio and fuel flow rate but have the same trends in terms of nozzle diameter. These differences can be explained by the following Thermal and Prompt trends in both flames. Thermal EINOx is quite sensitive to the residence time in the high-temperature region weighted by the maximum flame temperature. Prompt EINOx is mainly influenced by flame surface area of each combustion conditions.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
• /
• 1999.05a
• /
• pp.89-93
• /
• 1999

Experimental studies are conducted to investigate the flame stability and the thermal/fuel NOx formation characteristics of the low calorific value(LCV) gas fuel. Synthetic LCV fuel gas is produced through mixing carbon monoxide, hydrogen, nitrogen and ammonia on the basis that the thermal input of the syngas fuel into a burner is identical to that of natural gas, and then the syngas mixture is fed to and burnt with air on flat flame burner. Flame behaviors are observed to identify flame instability due to blow-off or flash-back when burning the LCV fuel gas at various equivalence ratio conditions. Measurements of NOx in combustion gas are made for comparing thermal and fuel NOx emissions from the LCV syngas combustion with those of the natural gas one, and for analyzing ammonia to NOx conversion mechanism. In addition, the nitrogen dilution of the LCV syngas is preliminarily attempted as a NOx reduction technique.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
• /
• 1999.11a
• /
• pp.23-29
• /
• 1999

Experimental studies are conducted to investigate the flame stability and the thermal/fuel NOx formation characteristics of the low calorific value (LCV) coal derived gas fuel. Synthetic LCV fuel gas is produced by mixing carbon monoxide, hydrogen, nitrogen and ammonia on the basis that the thermal input of the syngas fuel into a burner is identical to that of natural gas. The syngas mixture is fed to and burnt with air on flat flame burner. With the variation of the equivalence ratio for specific syngas fuel, flame behaviors are observed to identify the flame instability due to blow-off or flashback and to define stable combustion range. Measurements of NOx content in combustion gas are made for comparing thermal and fuel NOx from the LCV syngas combustion with those of the natural gas one. In addition, the nitrogen dilution of the LCV syngas is preliminarily attempted as a NOx reduction technique, and its effects on thermal and fuel NOx production are discussed.