• Title/Summary/Keyword: Thermal NO$_{}$ x/

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The Effects of Exhaust Gas Recirculation on Premixed Combustion System (배기가스 재순환 방식이 예혼합 연소시스템에 미치는 영향)

  • Yu, Byeonghun;Lee, Seungro;Kum, Sung-Min;Lee, Chang-Eon
    • 한국연소학회:학술대회논문집
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    • 2013.06a
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    • pp.1-3
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    • 2013
  • The premixed combustion system applying exhaust gas recirculation was investigated to achieve the low pollutant emission and the high thermal efficiency. In this study, it was studied the effects of EGR on the thermal efficiency, $NO_x$ and CO emissions with various EGR ratios and equivalence ratios. As results, when equivalence ratio was increased, thermal efficiency increased and $NO_x$ and CO concentration increased. When EGR was applied, $NO_x$ and CO concentration decreased and thermal efficiency increased. Especially, in the case of 15% of EGR ratio at 0.85 of equivalence ratio, $NO_x$ and CO concentration will be a smaller than these of a current operating condition of the boiler and thermal efficiency was about 1.7% higher.

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NOx Reduction with Secondary Air and Fuel in a Catalytic Combustor (촉매연소기에서 2단 공급공기와 연료가 NOx 저감에 미치는 연구)

  • 정진도;이보영
    • Journal of Korean Society for Atmospheric Environment
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    • v.19 no.5
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    • pp.541-549
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    • 2003
  • A basic experimental study was conducted in order to find the optimum combustion control technology to decrease the thermal NO$_{x}$, by applying the catalytic combustion method with natural gas. NO$_{x}$ emission increased with increasing space velocity due to temperature rising in the furnace. In order to overcome the low resistance to high temperature, secondary air was supplied to the CST combustor. The following secondary fuel formed combustible mixture in part, which resulted in steep increase of the exiting temperature of the 2nd catalyst bed. It led to the more generator of NO$_{x}$, 30∼60% of the 1 st catalyst bed. It might be due to the potential increase of thermal NO$_{x}$.

The removing characteristic of harmful exhaust from a motorcycle using non-thermal plasma (플라즈마를 이용한 이륜자동차 배출가스저감 특성)

  • Kim, Young-Ju;Park, Hong-Jae;Jung, Jang-Gun;Lee, Jae-Dong;Park, Jae-Yoon;Koh, Hee-Seog
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.07b
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    • pp.1127-1130
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    • 2003
  • In the last several centuries, humankind have been experienced the material abundance with a development of technical civilization and being industrialized quickly. During the process of this, environmental pollutant have occurred naturally so that humankind have more interests for environment pollutant. Air pollution caused by exhaust from a car is very harmful for human. Most of exhaust from a gasoline engine are $CO_x(CO+CO_2),\;NO_x(NO+NO_2)$, and THC(Total Hydrocarbon). The method to remove these kinds of noxious gases are so many thing such as the three catalysts, $NO_x$ catalysts, Filter and so on. However, although air pollution caused by exhaust from motorcycle have also occurred very much, there is no regulation for motorcycle. In this paper, we studied to remove $CO_x(CO+CO_2),\;NO_x(NO+NO_2)$, THC exhaust from a motorcycle using non-thermal plasma In the result, $NO_x(NO+NO_2)$ concentration was decreased approximately 70% and THC(Total Hydrocarbon) was removed about 40%.

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Effect of Fe Addition on Hydrogen Rich NSR Kinetics over Pt/Co/Ba/Al2O3 Catalyst (Pt/Co/Ba/Al2O3에 Fe 첨가가 수소 풍부 NSR 반응성에 미치는 영향)

  • Kim, Jingul;Jeon, Jiyong;Kim, Seongsoo
    • Journal of Hydrogen and New Energy
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    • v.23 no.6
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    • pp.581-587
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    • 2012
  • Thermal aging effect on NSR kinetics was studied over Pt/Co/Fe/Ba/$Al_2O_3$ catalyst. The amount of $NO_x$ uptake over Pt/Co/Fe/Ba/$Al_2O_3$ calcined at $400^{\circ}C$ increased with increasing NSR temperature from $200^{\circ}C$ to $400^{\circ}C$, where amount of $NO_x$ uptake is the highest at $400^{\circ}C$ with mol ratio of $NO_x$/Ba = 0.5. Thereafter, the amount of $NO_x$ uptake at $400^{\circ}C$ decreased with the higher calcination temperature, where Pt/Co/Fe/Ba/$Al_2O_3$ catalyst calcined at $700^{\circ}C$ showed an amount of $NO_x$ uptake with the mol ratio of $NO_x$/Ba=0.062. Result of XRD and NSR showed that Fe addition into Pt/Co/Fe/Ba/$Al_2O_3$ suppressed sintering of Pt crystallites and make $NO_x$ uptake larger, compared to no addition of Fe into Pt/Co/Fe/Ba/$Al_2O_3$ catalyst. From BET result, it was found that the change of specific surface area was relatively small by the thermal aging process. Therefore, it was found that the sintering of Pt crystallites caused the decrease of $NO_x$ uptake during NSR reaction and Fe played a role to suppress the sintering process of Pt crystallites caused by thermal aging.

An Experimental Study on Flame and $NO_x$ Emission Characteristics of Front Mixing Premix Combustor ($NO_x$ 선단 예혼합 연소기의 화염 및 $NO_x$ 배출 특성 연구)

  • Shin, Myung-Chul;Kim, Se-Won;Mun, Min-Uk
    • Journal of the Korean Society of Combustion
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    • v.11 no.2
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    • pp.22-27
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    • 2006
  • This experimental study has been mainly motivated to obtain generally applicable design correlation for the front mixing premix combustor. The design concept of the front mixing premix combustor is to minimize thermal $NO_x$ and prompt $NO_x$ formation by maintaining low peak flame temperature, and nearly uniform flame temperature through rapid mixing process near the ignition point. The present experimental results clearly indicate that the front mixing premix combustor yields the $NO_x$ level lower than 43 ppm $NO_x$ emissions and the nearly uniform temperature distribution.

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A Numerical Study on the $NO_{x}$ Reduction in 500MW Pulverized Coal Tangential Firing Boiler (500MW급 접선분사형 미분탄보일러의 $NO_{x}$ 저감에 관한 수치해석적 연구)

  • Choi, Choeng-Ryul;Kang, Dae-Woong;Kim, Chang-Nyung;Park,, Man-Heung;Kim, Kwang-Chu;Kim, Jong-Kill
    • Proceedings of the KSME Conference
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    • 2001.06d
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    • pp.967-972
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    • 2001
  • The emission of $NO_{x}$ during coal combustion is a major reason of environment impact. $NO_{x}$ is an acid rain precursor and participates in the generation of smog through ozone production. $NO_{x}$ can be divided into thermal $NO_{x}$, fuel $NO_{x}$ and prompt $NO_{x}$. Thermal $NO_{x}$ is formed in a highly temperature condition dependent. Fuel $NO_{x}$ is dependent on the local combustion characteristics and initial concentration of nitrogen bound compound, while prompt $NO_{x}$ is formed in a significant quantity in some combustion environments, such as low temperature and short residence times. This paper presents numerical simulation of the flow and combustion characteristics in the furnace of a tangential firing boiler of 500MW with burners installed at the every comer of the furnace. The purpose of this paper is to investigate the reduction of $NO_{x}$ emission in a 500MW pulverized coal tangential firing boiler with different OFA's and burner angles. Calculations with different air flow rates of over fired air(OFA) and burner angles are performed.

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NOx and CO Emission Characteristics of Porous Inert Medium Burner (다공물질 연소기의 NOx 및 CO 배출 특성)

  • 임인권
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.19 no.2
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    • pp.559-567
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    • 1995
  • The combustion process within a porous inert medium (PIM) burner is numerical studied. A detailed chemical reaction scheme including thermal and prompt NO$_{x}$ reactions is used to predict the formation and destruction of pollutants such as NO$_{x}$ and CO. The reaction paths for NO$_{x}$ formation are divided to quantify the amount of NO$_{x}$ formed through thermal NO$_{x}$ reaction or through prompt NO$_{x}$ reaction. Emission index is calculated to compare the actual mass of NO$_{x}$ or CO produced through the combustion of unit mass of fuel. It is found NO formation in PIM burner is confined in flame zone and formation is suppressed due to heat loss at down-stream of the flame. Higher production of NO through prompt NO reaction path is observed due to the higher concentration of fuel derivative species and its higher diffusion at flame front. For all equivalence ratios, CO emission within PIM burner is lower than that from the one-dimensional freely-propagating flame. PIM burner flame has better NO$_{x}$ emission index from .psi. = 0.75 to .psi. = 1.1. to .psi. = 1.1.

Effect of pressure and stochiometric air ratio on flame structure and NOx emission in gas turbine dump combustor with double cone burner (이중원추형 모형연소기에서 압력과 공기비에 따른 화염 구조 및 NOx 배출특성)

  • Nam, Hyun Su;Han, Dong Sik;Kim, Gyu Bo;Jeo, Chung-Hwan
    • 한국연소학회:학술대회논문집
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    • 2012.04a
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    • pp.177-179
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    • 2012
  • This work presents an experimental investigation to study $NO_x$ emissions under stoichiometric air ratio and elevated pressure (2~10bar) in a High Press Combustor(HPC) equiped with double cone burner which was designed by Pusan Clean Coal Center(PC3). Exaust gas temperature and $NO_x$ emissions were measured at the end of the combustion chamber. The $OH^*$ radical concentration and $NO_x$ emission were decreased as a function of increasing ${\lambda}$ generally. On the other hand, $OH^*$ radical concentration and $NO_x$ emission increased with ${\lambda}$ pressure of the combustion chamber. $NO_x$ emissions which were governed by thermal $NO_x$, were highly increased under the elevated pressure, but slightly increased at sufficiently low fuel concentrations (${\lambda}>2.0$).

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A Study on Characteristics of Performance and $NO_x{\cdot}THC$ Emissions in Turbo Intercooler ECU Common-rail Diesel Engines with a Combined Plasma EGR System (플라즈마 EGR 조합시스템 터보 인터쿨러 ECU 커먼레일 디젤기관의 성능 및 $NO_x{\cdot}THC$ 배출물 특성에 관한 연구)

  • Bae, Myung-Whan;Ku, Young-Jin;Lee, Bong-Sub
    • Transactions of the Korean Society of Automotive Engineers
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    • v.14 no.3
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    • pp.10-21
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    • 2006
  • The aim in this study is to develop the combined EGR system with a non-thermal plasma reactor for reducing exhaust emissions and improving fuel economy in turbo intercooler ECU common-rail diesel engines. At the first step, in this paper, the characteristics of performance and $NO_x{\cdot}THC$ emissions under four kinds of engine loads are experimentally investigated by using a four-cycle, four-cylinder, direct injection type, water-cooled turbo intercooler ECU common-rail diesel engine with a combined plasma exhaust gas recirculation(EGR) system operating at three kinds of engine speeds. The EGR system is used to reduce $NO_x$ emissions, and the non-thermal plasma reactor and turbo intercooler system are used to reduce THC emissions. The plasma system is a flat-to-flat type reactor operated by a plasma power supply. The fuel is sprayed by pilot and main injections at the variable injection timing between BTDC $15^{\circ}$ and ATDC $1^{\circ}$ according to experimental conditions. It is found that the specific fuel consumption rate with EGR is increased, but the fuel economy is better than that of mechanical injection type diesel engine as compared with the same output. Results show that $NO_x$ emissions are decreased, but THC emissions are increased, as the EGR rate is elevated. $NO_x$ and THC emissions are also slightly decreased as the applied electrical voltage of the non-thermal plasma reactor is elevated. Thus one can conclude that the influence of EGR in $NO_x$ and THC emissions is larger than that of the non-thermal plasma reactor, but THC emissions are greatly influenced by the non-thermal plasma reactor as the EGR rate is elevated.

Thermal Characteristics Simulation with Detecting Temperature for the Wearable Nylon-Yarn NOx Gas Sensors (웨어러블용 Nylon-Yarn NOx 가스 센서의 검출 온도 변화에 따른 열 특성 시뮬레이션)

  • Jang, Kyung-Uk
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.33 no.4
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    • pp.321-325
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    • 2020
  • Atmospheric environmental problems have a major impact on human health and lifestyle. In humans, inhalation of nitrogen oxides causes respiratory diseases, such as bronchitis. In this paper, thermal analysis of a gas sensor was carried out to design and fabricate a wearable nylon-yarn gas sensor for the detection of NOx gas. In the thermal analysis method, the thermal diffusion process was analyzed while operating the sensors at 40 and 60℃ to secure a temperature range that does not cause thermal runaway due to temperature in the operating environment. Thermal diffusion analysis was performed using the COMSOL software. The thermal analysis results could be useful for analyzing gas adsorption and desorption, as well as the design of gas sensors. The thermal energy diffusion rate increased slightly from 10.05 to 10.1 K/mm as the sensor temperature increased from 40 to 60℃. It was concluded that the sensor could be operated in this temperature range without thermal breakdown.