• Title/Summary/Keyword: Thermal Diffusivity Ratio

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Thermal Properties of 0.9CaMgSi2O6-0.1MgSiO3 Glass-Ceramics

  • Jeon, Chang-Jun;Sun, Gui-Nam;Lee, Jong-Kyu;Ju, Han-Sae;Kim, Eung-Soo
    • Journal of the Korean Ceramic Society
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    • v.49 no.1
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    • pp.111-117
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    • 2012
  • Dependencies of thermal properties on the crystallization behavior of $0.9CaMgSi_2O_6-0.1MgSiO_3$ glass-ceramics were investigated as a function of heat-treatment temperature from $750^{\circ}C$ to $950^{\circ}C$. The crystallization behavior of the specimens depended on the heat-treatment temperature, which could be evaluated by differential thermal analysis (DTA), Fourier transform infrared spectroscopy (FT-IR), and X-ray diffraction (XRD) analysis by the Rietveld-reference intensity ratio (RIR) combined procedure. With an increase of the heat-treatment temperature, the thermal conductivity and thermal diffusivity of the heat-treated specimens increased. These results could be attributed to the increase of crystallization with heat-treatment temperature. However, the specific heat capacity of the heat-treated specimens was not affected by the heat-treatment temperature. The thermal conductivities measured from $25^{\circ}C$ to $100^{\circ}C$ were also discussed for application to lighting-emitting diode (LED) packages and substrate materials.

Application of Bulk Talc to Molding Material (주형재료로서 덩어리 활석의 이용)

  • Ha, Man-Jin;Lee, Zin-Hyoung;Lee, Sang-Soo;Eun, Hee-Joon
    • Journal of Korea Foundry Society
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    • v.14 no.1
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    • pp.45-51
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    • 1994
  • The possibility of using bulk talc as molding material was reviewed and tested with the measurement of thermal properties and computer simulations. The measured thermal conductivity and heat diffusivity($k{\rho}c$) of talc were $2.4W/m^{\circ}C$ and $6.6{\times}10^6J^2/m^4^{\circ}C^2s$, respectively. Thermal properties of talc could be ranked between those of sand mold and iron mold. Talc transforms into cristobalite and enstatite at $910^{\circ}C$, During the transformation volume and structure change, cracks appear on the surface and distortion occurs. Therefore talc can be used for molding material below $910^{\circ}C$ if carefully treated. Computer simulation was carried out to test whether talc insert could promote directional solidification in sand mold and iron mold. In sand mold, it was possible to achieve directional solidification of thin plate casting with the length to thickness ratio of 15, if both iron insert and talc insert were used. In iron mold, it was possible to achieve directional solidification only with talc insert.

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Characteristics of Turbulent Lifted Flames in Coflow Jet with Initial Temperature Variations (동축류 제트에서 초기 온도 변화에 따른 난류 부상화염 특성)

  • Kim, K.N.;Won, S.H.;Chung, S.H.
    • 한국연소학회:학술대회논문집
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    • 2004.06a
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    • pp.15-20
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    • 2004
  • Characteristics of turbulent lifted flames in coflow jet have been investigated by varying initial temperature through the heating of coflow air. In the turbulent regime, liftoff height increases linearly with fuel jet velocity and decreases nonlinearly as the coflow temperature increases. This can be attributed to the increase of turbulent propagation speed, which is strongly related to laminar burning velocity. Dimensionless liftoff heights are correlated well with dimensionless jet velocity, which are scaled with parameters determining local flow velocity and turbulent propagation speed. This implies that the turbulent lifted flames are stabilized by balance mechanism between local turbulent burning velocity and flow velocity. Blowout velocity can be obtained from the ratio of mixing time to chemical time. Comparing to previous researches, thermal diffusivity should be evaluated from the initial temperature instead of adiabatic flame temperature.

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Characteristics of Turbulent Lifted Flames in Coflow Jet with Initial Temperature Variations (동축류 제트에서 초기 온도 변화에 따른 난류 부상화염 특성)

  • Kim, K.N.;Won, S.H.;Chung, S.H.
    • Journal of the Korean Society of Combustion
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    • v.9 no.1
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    • pp.32-38
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    • 2004
  • Characteristics of turbulent lifted flames in coflow jet have been investigated by varying initial temperature through the heating coflow air. In the turbulent regime, liftoff height increases linearly with fuel jet velocity and decreases nonlinearly as the coflow temperature increases. This can be attributed to the increase of turbulent propagation speed, which is strongly related to laminar burning velocity. Dimensionless liftoff heights are correlated well with dimensionless jet velocity, which are scaled with parameters determining local flow velocity and turbulent propagation speed. This implies that the turbulent lifted flames are stabilized by balance mechanism between local turbulent burning velocity and flow velocity. Blowout velocity can be obtained from the ratio of mixing time to chemical time. Comparing to previous researches, thermal diffusivity should be evaluated from the initial temperature instead of adiabatic flame temperature.

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Coupled Nonlinear Finite Element-Boundary Element Analysis of Nuclear Waste Storage Structures Considering Infinite Boundaries (비선형 유한요소-경계요소 조합에 의한 핵폐기구조체의 무한영역해석)

  • 김문겸;허택녕
    • Computational Structural Engineering
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    • v.6 no.4
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    • pp.89-98
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    • 1993
  • As the construction of nuclear power plants are increased, nuclear wastes disposal has been faced as a serious problem. If nuclear wastes are to be buried in the underground stratum, thermo-mechanical behavior of stratum must be analyzed, because high temperature distribution has a significant effect on tunnel and surrounding stratum. In this study, in order to analyze the structural behavior of the underground which is subject to concentrated heat sources, a coupling method of nonlinear finite elements and linear boundary elements is proposed. The nonlinear finite elements (NFE) are applied in the vicinity of nuclear depository where thermo-mechanical stress is concentrated. The boundary elements are also used in infinite domain where linear behavior is expected. Using the similar method as for the problem in mechanical field, the coupled nonlinear finite element-boundary element (NFEBE) is developed. It is found that NFEBE method is more efficient than NFE which considers nonlinearity in the whole domain for the nuclear wastes depository that is expected to exhibit local nonlinearity behavior. The effect of coefficients of the rock mass such as Poisson's ratio, elastic modulus, thermal diffusivity and thermal expansion coefficient is investigated through the developed method. As a result, it is revealed that the displacements around tunnel are largely dependent on the thermal expansion coefficients.

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Studies on the Heat Penetration and Pasteurization Conditions of Retort Pouch Kimchi (Retort Pouch 김치의 전열특성(專熱特性)과 살균조건(殺菌條件)에 관한 연구(硏究))

  • Pyun, Yu-Ryang;Shin, Seung-Kyoo;Kim, Ju-Bong;Cho, Eun-Kyung
    • Korean Journal of Food Science and Technology
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    • v.15 no.4
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    • pp.414-420
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    • 1983
  • Heating characteristics for retort pouches of Kimchi heated in hot water were determined as a function of various parameters for processing. Processing conditions in laboratory and commercial retort were also evaluated on the basis of storage test. D values for Lactobacillus plantarum isolated from test sample ranged from $D^{1.08}\;to\;D^{0.18}$ and z value was $10.5^{\circ}C$. Thermal diffusivity of Kimchi increased from 1.15 to $1.44{\times}10^{-3}cm/s$ by blanching for 15 min at $80^{\circ}C$. The rate of heat penetration was significantly decreased with increasing the thickness of the pouch although the decreases was less significant below 1.0cm thickness. Increasing in the ratio of solid to syrup up to 90:10 proportionately decreased $f_h$ value, but above the ratio $f_h$ values were nearly constant.

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Burning Characteristics of Nitramine Propellant Embedded with Metal Wires (금속선을 삽입한 니트라민계 추진제의 연소특성)

  • 유지창
    • Journal of the Korean Society of Propulsion Engineers
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    • v.4 no.4
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    • pp.50-58
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    • 2000
  • Burning rate of the matrix propellant($r_{sb}$) and burning rate along the metal wire($r_w$) were measured and analyzed for the HTPB/AP/Al propellant embedded with Ag wire($\phi$0.15mm) according to weight % of RDX(0~20%). Variation of burning rate increment ratio($r_w$/$r_{sb}$) and pressure exponent(n) was studied for the nitramine propellant having 10% RDX embedded with three kinds of metal(Ag, Cu, and Ni-Cr) of which diameter range is between 0.1~0.6mm. Maximum burning rate increment ratio of the nitramine propellant embedded with Ag wire($\phi$0.1mm) was 5.94 at $20^{\cire}C$, 1000 psia, 16.4% faster than that of HTPB/AP propellant, it is because that autoignition temperature of the nitramine propellant was higher than that of HTPB/AP propellant. Standard deviation of absolute ($r_{wc}$/$r_{we}$)/$r_{we}$ calculated by using new empiracal equation composed of four dimensionless groups, is 6.11% less than that calculated by using original empirical equation composed of three dimensionless group. The new empiracal equation is derived from Buckingham pi theorem using the parameters such as thermal diffusivity, melting temperature. wire diameter, propellant sample diameter, frame temperature, autoignition temperature and matrix burning rate which influence on $r_w$.

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Characteristics of MOCVD Cobalt on ALD Tantalum Nitride Layer Using $H_2/NH_3$ Gas as a Reactant

  • Park, Jae-Hyeong;Han, Dong-Seok;Mun, Dae-Yong;Yun, Don-Gyu;Park, Jong-Wan
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.377-377
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    • 2012
  • Microprocessor technology now relies on copper for most of its electrical interconnections. Because of the high diffusivity of copper, Atomic layer deposition (ALD) $TaN_x$ is used as a diffusion barrier to prevent copper diffusion into the Si or $SiO_2$. Another problem with copper is that it has weak adhesion to most materials. Strong adhesion to copper is an essential characteristic for the new barrier layer because copper films prepared by electroplating peel off easily in the damascene process. Thus adhesion-enhancing layer of cobalt is placed between the $TaN_x$ and the copper. Because, cobalt has strong adhesion to the copper layer and possible seedless electro-plating of copper. Until now, metal film has generally been deposited by physical vapor deposition. However, one draw-back of this method is poor step coverage in applications of ultralarge-scale integration metallization technology. Metal organic chemical vapor deposition (MOCVD) is a good approach to address this problem. In addition, the MOCVD method has several advantages, such as conformal coverage, uniform deposition over large substrate areas and less substrate damage. For this reasons, cobalt films have been studied using MOCVD and various metal-organic precursors. In this study, we used $C_{12}H_{10}O_6(Co)_2$ (dicobalt hexacarbonyl tert-butylacetylene, CCTBA) as a cobalt precursor because of its high vapor pressure and volatility, a liquid state and its excellent thermal stability under normal conditions. Furthermore, the cobalt film was also deposited at various $H_2/NH_3$ gas ratio(1, 1:1,2,6,8) producing pure cobalt thin films with excellent conformality. Compared to MOCVD cobalt using $H_2$ gas as a reactant, the cobalt thin film deposited by MOCVD using $H_2$ with $NH_3$ showed a low roughness, a low resistivity, and a low carbon impurity. It was found that Co/$TaN_x$ film can achieve a low resistivity of $90{\mu}{\Omega}-cm$, a low root-mean-square roughness of 0.97 nm at a growth temperature of $150^{\circ}C$ and a low carbon impurity of 4~6% carbon concentration.

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Studies on the Physical Properties of Major Tree Barks Grown in Korea -Genus Pinus, Populus and Quercus- (한국산(韓國産) 주요(主要) 수종(樹種) 수피(樹皮)의 이학적(理學的) 성질(性質)에 관(關)한 연구(硏究) -소나무속(屬), 사시나무속(屬), 참나무속(屬)을 중심(中心)으로-)

  • Lee, Hwa Hyoung
    • Journal of Korean Society of Forest Science
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    • v.33 no.1
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    • pp.33-58
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    • 1977
  • A bark comprises about 10 to 20 percents of a typical log by volume, and is generally considered as an unwanted residue rather than a potentially valuable resourses. As the world has been confronted with decreasing forest resources, natural resources pressure dictate that a bark should be a raw material instead of a waste. The utilization of the largely wasted bark of genus Pinus, Quercus, and Populus grown in Korea can be enhanced by learning its physical and mechanical properties. However, the study of tree bark grown in Korea have never been undertaken. In the present paper, an investigative study is carried out on the bark of three genus, eleven species representing not only the major bark trees but major species currently grown in Korea. For each species 20 trees were selected, at Suweon and Kwang-neung areas, on the same basis of the diameter class at the proper harvesting age. One $200cm^2$ segment of bark was obtained from each tree at brest height. Physical properties of bark studied are: bark density, moisture content of green bark (inner-, outer-, and total-bark), fiber saturation point, hysteresis loop, shrinkage, water absorption, specific heat, heat of wetting, thermal conductivity, thermal diffusivity, heat of combustion, and differential thermal analysis. The mechanical properties are studied on bending and compression strength (radial, longitudinal, and tangential). The results may be summarized as follows: 1. The oven-dry specific gravities differ between wood and bark, further more even for a given bark sample, the difference is obersved between inner and outer bark. 2. The oven-dry specific gravity of bark is higher than that of wood. This fact is attributed to the anatomical structure whose characters are manifested by higher content of sieve fiber and sclereids. 3. Except Pinus koraiensis, the oven-dry specific gravity of inner bark is higher than that of outer bark, which results from higher shrinkage of inner bark. 4. The moisture content of bark increases with direct proportion to the composition ratio of sieve components and decreases with higher percent of sclerenchyma and periderm tissues. 5. The possibility of determining fiber saturation point is suggested by the measuring the heat of wetting. With the proposed method, the fiber saturation point of Pinus densiflora lies between 26 and 28%, that of Quercus accutissima ranges from 24 to 28%. These results need be further examined by other methods. 6. Contrary to the behavior of wood, the bark shrinkage is the highest in radial direction and the lowest in longitudinal direction. Quercus serrata and Q. variabilis do not fall in this category. 7. Bark shows the same specific heat as wood, but the heat of wetting of bark is higher than that of wood. In heat conductivity, bark is lower than wood. From the measures of oven-dry specific gravity (${\rho}d$) and moisture fraction specific gravity (${\rho}m$) is devised the following regression equation upon which heat conductivity can be calculated. The calculated heat conductivity of bark is between $0.8{\times}10^{-4}$ and $1.6{\times}10^{-4}cal/cm-sec-deg$. $$K=4.631+11.408{\rho}d+7.628{\rho}m$$ 8. The bark heat diffusivity varies from $8.03{\times}10^{-4}$ to $4.46{\times}10^{-4}cm^2/sec$. From differential thermal analysis, wood shows a higher thermogram than bark under ignition point, but the tendency is reversed above ignition point. 9. The modulus of rupture for static bending strength of bark is proportional to the density of bark which in turn gives the following regression equation. M=243.78X-12.02 The compressive strength of bark is the highest in radial direction, contrary to the behavior of wood, and the compressive strength of longitudinal direction follows the tangential one in decreasing order.

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Highly Doped Nano-crystal Embedded Polymorphous Silicon Thin Film Deposited by Using Neutral Beam Assisted CVD at Room Temperature

  • Jang, Jin-Nyeong;Lee, Dong-Hyeok;So, Hyeon-Uk;Hong, Mun-Pyo
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.154-155
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    • 2012
  • The promise of nano-crystalites (nc) as a technological material, for applications including display backplane, and solar cells, may ultimately depend on tailoring their behavior through doping and crystallinity. Impurities can strongly modify electronic and optical properties of bulk and nc semiconductors. Highly doped dopant also effect structural properties (both grain size, crystal fraction) of nc-Si thin film. As discussed in several literatures, P atoms or radicals have the tendency to reside on the surface of nc. The P-radical segregation on the nano-grain surfaces that called self-purification may reduce the possibility of new nucleation because of the five-coordination of P. In addition, the P doping levels of ${\sim}2{\times}10^{21}\;at/cm^3$ is the solubility limitation of P in Si; the solubility of nc thin film should be smaller. Therefore, the non-activated P tends to segregate on the grain boundaries and the surface of nc. These mechanisms could prevent new nucleation on the existing grain surface. Therefore, most researches shown that highly doped nc-thin film by using conventional PECVD deposition system tended to have low crystallinity, where the formation energy of nucleation should be higher than the nc surface in the intrinsic materials. If the deposition technology that can make highly doped and simultaneously highly crystallized nc at low temperature, it can lead processes of next generation flexible devices. Recently, we are developing a novel CVD technology with a neutral particle beam (NPB) source, named as neutral beam assisted CVD (NBaCVD), which controls the energy of incident neutral particles in the range of 1~300eV in order to enhance the atomic activation and crystalline of thin films at low temperatures. During the formation of the nc-/pm-Si thin films by the NBaCVD with various process conditions, NPB energy directly controlled by the reflector bias and effectively increased crystal fraction (~80%) by uniformly distributed nc grains with 3~10 nm size. In the case of phosphorous doped Si thin films, the doping efficiency also increased as increasing the reflector bias (i.e. increasing NPB energy). At 330V of reflector bias, activation energy of the doped nc-Si thin film reduced as low as 0.001 eV. This means dopants are fully occupied as substitutional site, even though the Si thin film has nano-sized grain structure. And activated dopant concentration is recorded as high as up to 1020 #/$cm^3$ at very low process temperature (< $80^{\circ}C$) process without any post annealing. Theoretical solubility for the higher dopant concentration in Si thin film for order of 1020 #/$cm^3$ can be done only high temperature process or post annealing over $650^{\circ}C$. In general, as decreasing the grain size, the dopant binding energy increases as ratio of 1 of diameter of grain and the dopant hardly be activated. The highly doped nc-Si thin film by low-temperature NBaCVD process had smaller average grain size under 10 nm (measured by GIWAXS, GISAXS and TEM analysis), but achieved very higher activation of phosphorous dopant; NB energy sufficiently transports its energy to doping and crystallization even though without supplying additional thermal energy. TEM image shows that incubation layer does not formed between nc-Si film and SiO2 under later and highly crystallized nc-Si film is constructed with uniformly distributed nano-grains in polymorphous tissues. The nucleation should be start at the first layer on the SiO2 later, but it hardly growth to be cone-shaped micro-size grains. The nc-grain evenly embedded pm-Si thin film can be formatted by competition of the nucleation and the crystal growing, which depend on the NPB energies. In the evaluation of the light soaking degradation of photoconductivity, while conventional intrinsic and n-type doped a-Si thin films appeared typical degradation of photoconductivity, all of the nc-Si thin films processed by the NBaCVD show only a few % of degradation of it. From FTIR and RAMAN spectra, the energetic hydrogen NB atoms passivate nano-grain boundaries during the NBaCVD process because of the high diffusivity and chemical potential of hydrogen atoms.

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