• 제목/요약/키워드: Thermal Conductivity at High Temperature

검색결과 341건 처리시간 0.029초

고온작동 수퍼커패시터용 이온성 액체 전해질에서의 흄드 실리카의 효과 (Useful Effects of Fumed Silica Nanoparticles in an Ionic Liquid Electrolyte for High Temperature Supercapacitor)

  • 김동원;정현영
    • 한국재료학회지
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    • 제28권1호
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    • pp.43-49
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    • 2018
  • The demand for energy storage devices capable of operating at high temperatures is increasing. In order to operate at high temperatures, a device must have excellent thermal stability and no risk of explosion. Ionic liquids are electrolytes that satisfy the above conditions, and studies on improving their performance have attracted great interest. Here, we report the results of a study on the fabrication of a supercapacitor that has a composite electrolyte prepared by dispersing fumed silica in an ionic liquid. The fumed silica filler exhibits improved ionic conductivity and lower interfacial resistance. In particular, the silica nanoparticles with diameters of 10 nm exhibit better electrochemical properties than fillers of other diameters and have excellent device performance of 33 times higher than the pristine ionic liquid at high temperatures. This study can be used to improve the electrolytes of electrochemical devices, such as the next generation battery or lithium ion battery.

PDP 투명전극의 응용을 위한 ITO 박막의 제작평가 (Fabrication and Characterizations of ITO Film as a Transparent Conducting Electrode for PDP Application)

  • 박강일;임동건;곽동주
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2002년도 하계학술대회 논문집 Vol.3 No.2
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    • pp.788-791
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    • 2002
  • Tin doped indium oxide(ITO) films are highly conductive and transparent in the visible region whose property leads to the applications in solar cell, liquid crystal display, thermal heater, and other sensors. This paper investigated ITO films as a transparent conducting films for application of PDP. ITO films were grown on glass substrate by RF magnetron sputtering method. To achieve high transmittance and low resistivity, we examined the various film deposition such as substrate temperature, gas pressure, annealing temperature, and deposition time. We recommend the substrate temperature of $500^{\circ}C$ and post annealing of $200^{\circ}C$ in $O_2$ atmosphere for good conductivity and transmittance. From XRD examination, ITO films showed a preferred(222) orientation. As substrate temperature increased from RT to $500^{\circ}C$, the intensity of the (222) peak increased. The highest peak intensity was observed at a substrate temperature of $500^{\circ}C$. with the optimum growth conditions, ITO films showed resistivity of $1.04{\times}10^{-4}{\Omega}-cm$ and transmittance of 81.2% for a film 300nm thick in the wavelength range of the visible spectrum.

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질화분위기에 따른 반응결합 질화규소의 미세구조변화 (The Microstructure of the Reaction -Bonded $Si_3N_4$ Formed in the Various Atmosphere)

  • 박지연;김종희
    • 한국세라믹학회지
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    • 제23권5호
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    • pp.61-66
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    • 1986
  • The gas mixtures ($H_2$/$N_2$, He/$N_2$) having a high thermal conductivity allow the heat generated by the nitriding exotherm to be dissipated from the compact in to the nitriding atmosphere permitting a more accurate control of temperature and produces a more uniform microstructure. In order to observe the effect of the mixed gas atmosphere on the microsturcture of RBSN. the specimen was nitrided in the mixed gas atmosphere which was containe up to 50vol% $H_2$ or He for 0-12 hrs at 135$0^{\circ}C$. The addition of hydrogen to nitrogen gas resulted in the growth of a-needle at the early stage of nitrding increase of the reaction rate and a finer and more uniform microstructure. in case of the addition of helium the behaviour of reaction was similar to the one with pure nitrogen. As the amount of helium was increased a coarse microstructure was formed.

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Carbon Nitride 박막을 이용한 액정배향 효과 (Liquid Crystal Alignment Effects Using a Carbon Nitride Thin Film)

  • 박창준;황정연;강형구;서대식;안한진;김경찬;김종복;백홍구
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2004년도 제6회 학술대회 논문집 일렉트렛트 및 응용기술연구회
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    • pp.23-26
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    • 2004
  • We studied the nematic liquid crystal (NLC) aligning capabilities using the new alignment material of a Carbon Nitride (NDLC) thin film. NDLC thin film exhibits high electrical resistivity and thermal conductivity that are similar to the properties shown by diamond-like carbon (DLC) thin films. The diamond-like properties and nondiamond-like bonding make NDLC an attractive candidate for applications. A high pretilt angle of about $9.9^{\circ}$ by ion beam (IB) exposure on the NDLC thin film surface was measured. A good LC alignment is achieved by the IB alignment method on the NDLC thin film surface at annealing temperature of $200^{\circ}C$. The alignment defect of the NLC was observed above annealing temperature of $250^{\circ}C$. Consequently, the high pretilt angle and the good LC alignment by the IB alignment method on the NDLC thin film surface can be achieved.

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고온선박엔진용 MoSi$_2$금속간화합물의 경도와 방전가공특성 (Hardness and EDM Processing of MoSi$_2$Intermetallics for High Temperature Ship Engine)

  • 윤한기;이상필
    • 한국해양공학회지
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    • 제16권6호
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    • pp.60-64
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    • 2002
  • This paper describes the machining characteristics of the MoSi$_2$--based composites through the process of electric discharge drilling with various tubular electrodes. In addition to hardness characteristics, microstructures of Nb/MoSi$_2$laminate composites were evaluated from the variation of fabricating conditions, such as preparation temperature, applied pressure, and pressure holding time. MoSi$_2$-based composites have been developed in new materials for jet engines of supersonic-speed airplanes and gas turbines for high-temperature generators. These high performance engines may require new hard materials with high strength and high temperature-resistance. Also, with the exception of grinding, traditional machining methods are not applicable to these new materials. Electric discharge machining (EDM) is a thermal process that utilizes a spark discharge to melt a conductive material. The tool electrode is almost -unloaded, because there is n direct contact between the tool electrode and the work piece. By combining a non-conducting ceramic with more conducting ceramic, it was possible to raise the electrical conductivity. From experimental results, it was found that the lamination from Nb sheet and MoSi$_2$ powder was an excellent strategy to improve hardness characteristics of monolithic MoSi$_2$. However, interfacial reaction products, like (Nb, Mo)SiO$_2$and Nb$_2$Si$_3$formed at the interface of Nb/MoSi$_2$, and increased with fabricating temperature. MoSi$_2$composites, with which a hole drilling was not possible through the conventional machining process, enhanced the capacity of ED-drilling by adding MbSi$_2$, relative to that of SiC or ZrO$_2$reinforcements.

Axisymmetric vibration analysis of a sandwich porous plate in thermal environment rested on Kerr foundation

  • Zhang, Zhe;Yang, Qijian;Jin, Cong
    • Steel and Composite Structures
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    • 제43권5호
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    • pp.581-601
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    • 2022
  • The main objective of this research work is to investigate the free vibration behavior of annular sandwich plates resting on the Kerr foundation at thermal conditions. This sandwich configuration is composed of two FGM face sheets as coating layer and a porous GPLRC (GPL reinforced composite) core. It is supposed that the GPL nanofillers and the porosity coefficient vary continuously along the core thickness direction. To model closed-cell FG porous material reinforced with GPLs, Halpin-Tsai micromechanical modeling in conjunction with Gaussian-Random field scheme is used, while the Poisson's ratio and density are computed by the rule of mixtures. Besides, the material properties of two FGM face sheets change continuously through the thickness according to the power-law distribution. To capture fundamental frequencies of the annular sandwich plate resting on the Kerr foundation in a thermal environment, the analysis procedure is with the aid of Reddy's shear-deformation plate theory based high-order shear deformation plate theory (HSDT) to derive and solve the equations of motion and boundary conditions. The governing equations together with related boundary conditions are discretized using the generalized differential quadrature (GDQ) method in the spatial domain. Numerical results are compared with those published in the literature to examine the accuracy and validity of the present approach. A parametric solution for temperature variation across the thickness of the sandwich plate is employed taking into account the thermal conductivity, the inhomogeneity parameter, and the sandwich schemes. The numerical results indicate the influence of volume fraction index, GPLs volume fraction, porosity coefficient, three independent coefficients of Kerr elastic foundation, and temperature difference on the free vibration behavior of annular sandwich plate. This study provides essential information to engineers seeking innovative ways to promote composite structures in a practical way.

개방형 체적식 흡수기를 위한 SiC 허니컴 모듈의 성능 평가 (Performance Evaluation of SiC Honeycomb Modules Used for Open Volumetric Solar Receivers)

  • 채관교;이현진;김종규;윤환기;이상남;한인섭;서두원
    • 한국태양에너지학회:학술대회논문집
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    • 한국태양에너지학회 2012년도 춘계학술발표대회 논문집
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    • pp.120-125
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    • 2012
  • Daegu Solar Power Tower Plant of a 200 kW thermal capacity uses an open air receiver. An air receiver is generally based on the volumetric receiver concept with porous ceramic absorbers. Because absorber material is important in the volumetric receiver, ceramic materials with excellent thermal conductivity, high solar absorptivity and good thermal stability have been researched. KIER also developed SiC honeycomb absorber modules and evaluated performance of the modules at the KIER solar furnace. For performance evaluation, we made an open volumetric receiver containing the modules and measured the outlet temperature and the efficiency. It is demonstrated that performance of the KIER absorber is comparable to that of a reference absorber developed by DLR.

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순차이송 GMP 공정에서의 비구면 유리렌즈 성형 해석에 관한 연구 (Study on the Aspheric Glass Lens Forming Simulation in the Progressive GMP process)

  • 장성호;강정진;신광호;정우철;허영무;정태성
    • 한국소성가공학회:학술대회논문집
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    • 한국소성가공학회 2008년도 춘계학술대회 논문집
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    • pp.539-542
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    • 2008
  • Recently, GMP(Glass Molding Press) process is mainly used to produce aspheric glass lenses. Because glass lens is heated at high temperature above Ty (yielding point) for forming glass, the quality of aspheric glass lens is deteriorated by residual stresses which are generated in a aspheric glass lens after forming. Before this study, as a fundamental study to develop forming conditions for progressive GMP process, compression, strain relaxation and thermal conductivity tests were carried out to obtain the visco-rigid plastic, the visco-elastic and thermal properties of K-PBK40 which is newly developed and applied for precision molding glass material, In this study, using the experimental results we obtained, a glass lens forming simulation in progressive GMP process was carried out and we could forecast the shape of deformed glass lenses and residual stresses contribution in the structure of deformed glass lenses after forming.

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분말형 견운모를 혼입한 모르타르의 내화성능 연구 (Investigation on Fire Resistance of Mortar Made of Powder Type Sericite)

  • 박지연;김소이;김성하;이재용;정철우
    • 한국건설순환자원학회논문집
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    • 제9권1호
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    • pp.26-32
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    • 2021
  • 분말형 견운모는 폐기물 재활용 차원에서 화학, 광물 분야에서 활발하게 연구가 이루어지고 있고, 비교적 저렴하게 구할 수 있는 재료이며, 일반 운모와 마찬가지로 낮은 열전도율을 가지고 있다. 따라서 본 연구에서는 분말형 견운모를 활용하여 모르타르의 열전도율을 개선하고, 이를 통해 시멘트 복합체용 내화재료로서와 활용가능성을 확인하고자 하였다. 분말형 견운모를 혼입한 시멘트 모르타르를 제작하고, 이의 열전도율 및 고온 노출 전후의 압축강도를 비교 평가하여 내화성능을 규명하고자 하였다. 실험 결과에 따르면, 분말형 견운모를 혼입하는 경우 압축강도가 감소하는 것으로 나타났으며, 혼입량 증가에 따른 압축강도의 감소는 미미하였다. 분말형 견운모를 혼입하면, 열전도율이 감소하며, 600℃, 900℃, 1,200℃에 소성된 모르타르 시험체의 잔존강도가 플레인 모르타르에 비해 높게 나타났다. 실험 결과를 종합적으로 평가해 볼 때, 분말형 견운모는 시멘트 복합체용 내화 재료로서의 활용가능성이 존재한다고 결론지을 수 있다.

질화알루미늄의 소결(I) : 상압소결 (Sintering of Aluminum Nitride (I) : Pressureless Sintering)

  • 최상욱;이희철;이전;이임창
    • 한국세라믹학회지
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    • 제28권6호
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    • pp.457-464
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    • 1991
  • Aluminum nitride (AlN) has excellent properties such as high thermal conductivity and electrical resistivity, whereas it has some disadvantages such as low sinterability and tendency to be hydrolyzed by moisture at room temperature. In the present work, the relative density, modulus of rupture and microhardness were examined for pressure-less-sintered AlN (synthetic and commercial) bodies which were prepared under the conditions of various sintering temperatures, holding times and additions of CaCO3 which showed the best effect on sinterability among the various sintering aids. As a result, the AlN bodies with 1.0 wt% CaCO3 (0.56wt% CaO) which were sintered at 1800$^{\circ}C$ for 20 min showed good densification. In this case, the relative densities were 95.9% and 95.2%, and microhardnesses were 10.3 GPa and 9.8 GPa for synthetic and commercial AlN respectively. And as the holding time at 1800$^{\circ}C$ was increased from 10 min to 60 min, the relative density was increased from 91.9% to 96.5%. It was considered that impurities of metals and oxygen promoted the densification of AlN at low temperature (1600$^{\circ}C$).

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