• 대한기계학회논문집B
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• 제26권3호
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• pp.439-447
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• 2002

The microchannel flow in miniature TCDs (thermal conductivity detectors) is investigated numerically. The solutions based on the boundary layer approximation are not very accurate in the region of the duct inlet for low Reynolds numbers. In this study, two-dimensional Navier-Stokes equations are considered to analyze the gas flow in a miniature TCD. Effects of channel size, inlet and boundary conditions on the heat transfer rate are examined. When the gas stream is not preheated, the distances for a miniature TCD to reach the conduction-dominant region for duct flow are found to be approximately two and three times the thermal entry length for duct flow with constant properties, respectively, leer constant wall temperature and constant wall heat flux boundary conditions. If the gas temperature at the channel inlet is close to the mean gas temperature in the conduction-dominant region, the entrance region is much shorter compared to other cases considered in this study.

• 한국지반공학회:학술대회논문집
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• 한국지반공학회 2010년도 추계 학술발표회 2차
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• pp.45-52
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• 2010

Thermal properties of geomaterial are overlooked with other geomechanical properties. The transient line-source (TLS) method is one of the most used testing methods for measuring the thermal conductivity (K) and thermal diffusivity ($\alpha$) of materials. But more recently, Transient Plane-Source method was developed to measure these. It has several advantage of comparing with TSL method, but there has not been documented application in geomaterial. A Resistance Temperature Detector is used to construct sensor. For durability of Probe, Adopt a new technique that two probes are bonded in exact matching. For standard materials, such as glycerin, and ice the measured K and a values of these materials were generally within 2-5% from the standard values in the literature. This document present to evaluate the thermal properties of geomaterials and its application was tested for varying degree of saturation using the Transient Plane Source method. The result of this study suggests that it is an comparatively accurate method for simultaneously measuring thermal conductivity and thermal diffusivity and can identify the feasibility to geomaterial.

• 한국초전도ㆍ저온공학회논문지
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• 제4권2호
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• pp.68-72
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• 2002

This work investigates the transient cooling characteristics of an Infrared (IR) detector cryochamber, which has a critical effect on the cooling load. The current thermal modeling considers the conduction heat transfer through a cold well. the gaseous conduction due to outgassing. and the radiation heat transfer. The transient cooling Performance. i.e. the penetration depth and cooling load, is determined using a finite difference method. It is found that the penetration depth increases as the bore conductivity increases. Gaseous conduction and radiation hardly affect the penetration depth. The transient cooling load increases as the bore conductivity increases. The effects of gaseous conduction and radiation on transient heat transfer are weak at initial stages of cooling. However, their effects become significant as the cooling Process Proceeds.

• 전기학회논문지
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• 제60권12호
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• pp.2311-2317
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• 2011

In this paper, we study the temperature change of a ${\mu}$-bolometer focal plane array with a capacitive transimpedance amplifier bias cancellation circuit. Thermal analysis is essential to understand the performance of a ${\mu}$-bolometer focal plane array, and to improve the temperature stability of a focal plane array characteristics. In this study, the thermal analyses of a ${\mu}$-bolometer and its two reference detectors are carried out as a function of time. The analyses are done with the $30{\mu}m$ pitch $320{\times}240$ focal plane array operating of 60 Hz frame rate and having a columnwise readout. From the results, the temperature increase of a ${\mu}$-bolometer in FPA by an incident IR is estimated as $0.689^{\circ}C$, while the temperature increase by a pulsed bias as $7.1^{\circ}C$, which is about 10 times larger than by IR. The temperature increase of a reference detector by a train of bias pulses may be increased much higher than that of an active ${\mu}$-bolometer. The suppression of temperature increase in a reference bolometer can be done by increasing the thermal conductivity of the reference bolometer, in which the selection of thermal conductivity also determines the range of CTIA output voltage.

• 공업화학
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• 제18권3호
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• pp.245-250
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• 2007

실리카겔의 열처리 온도에 따른 1,2-dichlorobenzene의 흡착 특성을 모멘트 법으로 고찰하였다. 실리카겔의 열처리 온도는 150, 500, $800^{\circ}C$로 변화시켰으며 고정층 반응기를 사용하여 TCD (Thermal Conductivity Detector)가 장착된 기체크로마토 그래프에서 1,2-dichlorobenzene의 펄스 응답곡선을 측정하였다. 1,2-dichlorobenzene의 평형흡착상수와 표면 흡착열은 열처리 온도 $500^{\circ}C$에서 가장 높은 값을 나타내었다. 열처리 온도가 증가함에 따라 실리카겔 표면의 수분과 OH 작용기가 제거되어 1,2-dichlorobenzene과의 상호작용이 증가한 것으로 판단된다. 고온인 $800^{\circ}C$에서 열처리한 실리카겔은 비표면적이 감소하여 평형흡착상수와 흡착열, 모두 감소한 것으로 사료된다. 모멘트 해석으로 계산된 축분산 계수는 $0.046{\times}10^{-4}{\sim}1.033{\times}10^{-4}m^2/sec$였으며 기공 내의 확산계수는 $500^{\circ}C$ 열처리 실리카겔에서 가장 낮은 것으로 나타났다.

• 한국펄프종이공학회:학술대회논문집
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• 한국펄프종이공학회 2006년도 PAN PACIFIC CONFERENCE vol.2
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• pp.265-270
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• 2006

This paper reports an improved headspace gas chromatographic method for the determination of carboxyl group content in wood fibers. Pretreatment of wood fibers was applied using dilute HCl to convert carboxyl groups to carboxylic acid groups and then using deionized water to wash fiber samples thoroughly. The samples were finally air dried. Sodium bicarbonate solution was used to react with carboxylic acid groups of the pretreated fibers in a closed testing vial to release carbon dioxide. The content of carboxyl groups in fibers was accurately quantified by determining the amount of carbon dioxide released by a headspace gas chromatograph equipped with a thermal conductivity detector. The modified process for fiber sample pretreatment increased the reliability and accuracy in measuring carboxylic acid groups. The present method is simple, accurate.

• KEPCO Journal on Electric Power and Energy
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• 제3권1호
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• pp.41-47
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• 2017

After $SF_6$, which is being used in power equipment as an insulating material, is classified as one of the 6 major greenhouse gases, the maintenance and the refinement of used $SF_6$ started to get attention. In regard to this, KEPCO Research Institute (KEPRI) is developing $SF_6$ recovery and refinement technology starting with establishing a comprehensive $SF_6$ analysis system. With the analysis system, qualitative and quantitative analyses of the purity and the impurities of $SF_6$ before and after recovery, and before and after refinement have been carried out. The analysis system is comprised of GC-DID (Gas Chromatograph -Discharge Ionization Detector) for trace impurities analysis, GC-TCD (Thermal Conductivity Detector) for analyses of $SF_6$ purity and major impurities concentration from several hundred ppm up to percent range, GC-MSD (Mass Selective Detector) for analyses of impurities not included in standard gas, FT-IR (Fourier Transform-Infrared) Spectrometer for analysis of HF and $SO_2$, and moisture analyzer for analysis of moisture below 100 ppm. With this analysis system, complete analysis method of $SF_6$ has been established. This analysis system is being used in the maintenance of power equipment and the development of $SF_6$ recovery and refinement technologies. In this paper, the analysis results of four samples - gas and liquid phase $SF_6$ samples from a $SF_6$ refinement system before and after refinement are presented.

• 한국전기전자재료학회논문지
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• 제14권12호
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• pp.1008-1015
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• 2001

Thin films of vanadium oxide(VO$\_$x/) have been deposited by r.f. magnetron sputtering from V$_2$O$\_$5/ target in gas mixture of argon and oxygen. The oxygen/(oxygen+argon) partial pressure ratio is changed from 0% to 8%. Crystal structure, chemical composition, bonding, optical and electrical properties of films sputter-deposited under different oxygen gas pressures are characterized through XPS, AES, RBS, FTIR, optical absorption and electrical conductivity measurements. V$_2$O$\_$5/ and lower oxides co-exist in sputter-deposited films and as the oxygen partial pressure is increased the films become more stoichiometric V$_2$O$\_$5/. The increase of O/V ratio with increasing oxygen gas pressure is attributed to the partial filling of oxygen vacancies through diffusion. It is observed that the oxygen atoms located on the V-O plane of V$_2$O$\_$5/ layer participate more readily in the oxidation process. With increasing oxygen gas pressure indirect and direct optical band gaps are increased, but thermal activation energies are decreased.

• 한국전산구조공학회:학술대회논문집
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• 한국전산구조공학회 2011년도 정기 학술대회
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• pp.157-160
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• 2011

본 연구에서는 광섬유 센서 기반 스마트 모니터링 시스템이 지중 열전도도 측정에도 효율적으로 적용될 수 있는지를 분석하였다. 이를 위해 광섬유 온도센서를 이용하여 지반의 열전도도를 측정할 수 있는 열응답 시험기가 개발되었다. 개발된 열응답 시험기는 기존의 RTD(Resistance Temperature Detector) 온도 센서 외에 광섬유 센서의 한 종류인 FBG(Fiber Bragg Grating) 센서도 실시간적으로 측정할 수 있는 시스템으로 구성되어 있다. 개발된 장비의 적용성 검증을 위하여 주문진 표준사를 이용하여 모형토조 내에 일정한 간극비에 맞추어 시료가 조성되었으며 지중열교환기는 U자형 파이프가 사용되었다. 20시간동안 열응답 시험을 통하여 광섬유 센서와 RTD 센서를 동시에 이용하여 온도값을 측정하여 표준사의 열전도도 값을 산출하였다. 그 결과 모형실험을 통한 열전도도 값은 탐침법을 통해 얻어진 열전도도 값과 선형 열원 모델(line source model) 해석해와 거의 유사하게 나타났으며 광섬유 센서와 RTD 센서와의 온도차는 0.1~0.3$^{\circ}$로써 유사한 값을 나타내었다. 따라서 본 연구에서 개발된 광섬유 기반 열응답 시험기는 지반의 열전도도를 측정하는데 효과적으로 사용될 수 있음을 알 수 있었으며 향후 지열시스템 가동에 따른 지중열 교환기의 손상도 평가 및 경보시스템 개발을 위해 지중열교환기의 거동을 실시간으로 모니터링 하는데 있어서도 효과적으로 사용될 수 있을 것으로 생각된다.

• 분석과학
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• 제33권2호
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• pp.68-75
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• 2020

We have developed 10 μmol/mol nitrogen and oxygen certified reference materials (CRMs) in helium, as a SI-traceable gas standard for a quantifying of impurities in pure gases for the first time in Korea. The standard gas mixtures of nitrogen and oxygen were prepared in 5000 μmol/mol and sequentially were diluted to 250 μmol/mol and 10 μmol/mol according to the gravimetric preparation. In each dilution step, two cylinders of CRMs were prepared. The verification of internal consistency among the prepared gas mixtures was performed by using GC-TCD. The amount fractions and those expanded uncertainties (k = 2) of nitrogen and oxygen in the standard gas mixtures were (10.12 ± 0.08) μmol/mol and (10.18 ± 0.08) μmol/mol for nitrogen, and (9.88 ± 0.06) μmol/mol and (9.94 ± 0.06) μmol/mol for oxygen, respectively. We have conducted a purity assessment of two commercial helium gases using developed CRMs. As the results of the purity assessment, nitrogen and oxygen were detected by (1.66 ± 0.03) μmol/mol and (0.31 ± 0.02) μmol/mol, respectively, as the impurities in one of the pure helium.