• Title/Summary/Keyword: Thermal Changes

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Heat Processing and Dyeing Properties of Fabrics by Using Composite Fancy Yarn Containing Low Melting PET Yarn (저온융착 폴리에스테르사 함유 팬시사 직물의 열처리 특성 및 염색성)

  • Sung, Woo Kyung
    • Fashion & Textile Research Journal
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    • v.14 no.6
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    • pp.1024-1031
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    • 2012
  • The thermal bonding PET fabrics were produced through high temperature steaming (HTS) of low melting PET yarn as warp and composite fancy yarn containing low melting PET yarn as weft. The low melting PET yarn of sheath-core structure consisted of a regular PET in core portion and low melting PET in sheath portion. The composite fancy yarn consisted of regular PET yarn as inner part and effect part and low melting PET yarn as binding part. This study was carried out to investigate the melting behavior of thermal bonded PET fabric, the effect of HTS on the thermal bonding, mechanical properties, and dyeing properties. The melting peak of low melting PET yarn showed two melting peaks caused by sheath-core structure. Almost the entire thermal bonding of the fancy PET fabrics containing low melting PET yarn has formed at $200^{\circ}C{\times}3min$ of HTS. The tensile strength in warp and weft direction of the fancy PET fabrics slightly decreased as temperature of HTS increased. The total K/S value of the fancy PET fabrics decreased slightly to $180^{\circ}C{\times}3min$ of HTS, while increased slightly above $200^{\circ}C{\times}3min$ of HTS. The changes in the hue angle ($H^{\circ}$) of the thermal bonded fancy PET fabrics dyed with disperse dyes hardly ever happened.

The Correlation of Sweating of Oil/wax Structure and Thermal Property (오일/왁스 구조의 열적 특성과 Sweating과의 상관관계)

  • Yun, Seiyoung;Kim, Jungil
    • Applied Chemistry for Engineering
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    • v.24 no.2
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    • pp.144-147
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    • 2013
  • Sweating, which is the excretion of oil on the surface of a solid product containing several kinds of pigments in oil and is also solidified with wax, is a unique phenomenon often observed on the surface of cover make-up or lipstick. The cause of sweating is an imbalanced formula. Many studies have been conducted to decrease the symptoms of sweating in the field of cosmetics. Differential scanning calorimetry (DSC) is a thermo-analytical technique that measures the amount of heat required to increase the temperature of a sample as a function of temperature or time under certain conditions. DSC has been used to determine the thermal properties of oil/wax structures. This study investigates how the thermal characteristics correlate with the sweating symptoms. An oil/wax formulation with an optimal melting point was studied in an attempt to make a stable product by considering the thermal properties that represent minimal structural changes with temperature variation. In addition, the sweating of the oil/wax formulation was observed over a various temperature range. As a result, it was found that sweating was minimized when the structure remained static or little bit changed over a variety of temperatures.

THE FORMATION MECHANISM OF GROWN-IN DEFECTS IN CZ SILICON CRYSTALS BASED ON THERMAL GRADIENTS MEASURED BY THERMOCOUPLES NEAR GROWTH INTERFACES

  • Abe, Takao
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 1999.06a
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    • pp.187-207
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    • 1999
  • The thermal distributions near the growth interface of 150mm CZ crystals were measured by three thermocouples installed at the center, middle (half radius) and edge (10m from surface) of the crystals. The results show that larger growth rates produced smaller thermal gradients. This contradicts the widely used heat flux balance equation. Using this fact, it si confirmed in CZ crystals that the type of point defects created is determined by the value of the thermal gradient (G) near the interface during growth, as already reported for FZ crystals. Although depending on the growth systems the effective lengths of the thermal gradient for defect generation are varied, were defined the effective length as 10mm from the interface in this experiment. If the G is roughly smaller than 20C/cm, vacancy rich CZ crystals are produced. If G is larger than 25C/cm, the species of point defects changes dramatically from vacancies to interstitial. The experimental results which FZ and CZ crystals are detached from the melt show that growth interfaces are filled with vacancy. We propose that large G produces shrunk lattice spacing and in order to relax such lattice excess interstitial are necessary. Such interstitial recombine with vacancies which were generated at the growth interface, next occupy interstitial sites and residuals aggregate themselves to make stacking faults and dislocation loops during cooling. The shape of the growth interface is also determined by the distributions of G across the interface. That is, the small G and the large G in the center induce concave and convex interfaces to the melt, respectively.

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Influence of Aging of Lead Rubber Bearing on Seismic Performance of Bridges (납고무받침의 노화가 교량의 내진성능에 미치는 영향)

  • Park, Seong-Kyu;Oh, Ju
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.32 no.2A
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    • pp.109-116
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    • 2012
  • The dynamic properties of lead rubber bearings, which are used as isolator, are dependent on the main rubber's dynamic behaviors and nonlinear qualities. Rubber materials tend to undergo an aging process under the influence of mechanical or environmental factors, so they can end up inevitably facing damage. A main cause of such aging is known to be oxidization, which occurs through the heat of reaction at high temperatures. Accordingly, in this study an accelerated thermal aging test was carried out in order to compare the characteristic values of the bearings with each other before and after thermal aging occurs. As a result of this experiment, it was found that a thermal aging phenomenon could have an effect on shear stiffness, energy absorption, and equivalent damping coefficients. Furthermore, a decline in the dynamic properties of the lead rubber bearings by means of the thermal aging process was applied to an actual bridge and the effects of such thermal aging on the seismic performance of the bridge were also compared and analyzed based on numerical analysis. As a result of this analysis, it was found that the changes in the basic properties of the lead rubber bearings have a minor effect on the seismic performance of bridges.

An Experimental Analysis of Effective Thermal Conductivity of Porous Materials Using Structural Models (구조모델을 이용한 다공성 매질의 유효열전도도 분석)

  • Cha, Jang-Hwan;Koo, Min-Ho;Keehm, Young-Seuk
    • Journal of Soil and Groundwater Environment
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    • v.15 no.6
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    • pp.91-98
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    • 2010
  • The effective thermal conductivity of porous materials is usually determined by porosity, water content, and the conductivity of the matrix. In addition, it is also affected by the internal structure of the materials such as the size, arrangement, and connectivity of the matrix-forming grains. Based on the structural models for multi-phase materials, thermal conductivities of soils and sands measured with varying the water content were analyzed. Thermal conductivities of dry samples were likely to fall in the region between the Maxwell-Eucken model with air as the continuous phase and the matrix as the dispersed phase ($ME_{air}$) and the co-continuous (CC) model. However, water-saturated samples moved down to the region between the $ME_{wat}$ model and the series model. The predictive inconsistency of the structural models for dry and water-saturated samples may be caused by the increase of porosity for water-saturated samples, which leads to decrease of connectivity among the grains of matrix. In cases of variably saturated samples with a uniform grain size, the thermal conductivity showed progressive changes of the structural models from the $ME_{air}$ model to the $ME_{wat}$ model depending on the water content. Especially, an abrupt increase found in 0-20% of the water content, showing transition from the $ME_{air}$ model to the CC model, can be attributed to change of water from the dispersed to continuous phase. On the contrary, the undisturbed soil samples with various sizes of grains showed a gradual increase of conductivity during the transition from the $ME_{air}$ model to the CC model.

Thermal Emissivity Changes as a Function of Degree of Flakes Alignment on the Graphite Surface (흑연표면의 열방사율 측정시 결정립 배향성의 영향)

  • Roh, Jae-Seung;Ahn, Jai-Sang;Kim, Beom-Jun;Jeon, Ho-Yeon;Seo, Seung-Kuk;Kim, Suk-Hwan;Lee, Sang-Woo
    • Journal of the Korean institute of surface engineering
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    • v.42 no.2
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    • pp.95-101
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    • 2009
  • This study is the research on the thermal emissivity depending on the bulk graphite's alignment degree. Bulk graphites were manufactured by uni-axial pressing and subsequent heat treatment of natural graphite flakes with organic binder. The samples were prepared to be $0^{\circ}$ (relative to the 002 c-face), $45^{\circ}$, and $90^{\circ}$ (relative to the 100 a-face) for measuring alignment degree. The alignment degree of the sample was measured by XRD. The thermal emissivity was measured by infrared thermal image camera at $100^{\circ}C$ and compared with the value obtained by Infrared spectroscopy. The alignment degree and thermal emissivity of $0^{\circ}$ sample were measured to be 0 and 0.70 respectively. And those of $90^{\circ}$ sample were 0.73 and 0.80 respectively. The emissivity value was correlated with obtained by IR spectroscopy. Therefore it was considered that the thermal emissivity of the bulk graphite is correlated with the alignment degree.

Material Model and Thermal Response Analysis of Concrete at Elevated Temperatures (고온에서의 콘크리트 재료모델과 열거동해석)

  • 강석원;홍성걸
    • Journal of the Korea Concrete Institute
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    • v.13 no.3
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    • pp.268-276
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    • 2001
  • A numerical model for the thermal response analysis of concrete structures is suggested. The model includes the stress-strain relationship, constitutive relationship, and multiaxial failure criteria at elevated temperature conditions. Modified Saenz's model was used to describe the stress-strain relationship at high temperatures. Concrete subjected to elevated temperatures undergoes rapid strain increase and dimensional instability. In order to explain those changes in mechanical properties, a constitutive model of concrete subjected to elevated temperature is proposed. The model consists of four strain components; free thermal creep strain, stress-induced (mechanical) strain, thermal creep strain, and transient strain due to moisture effects. The failure model employs modified Drucker-Prager model in order to describe the temperature dependent multiaxial failure criteria. Some numerical analyses are performed and compared with the experimental results to verify the proposed model. According to the comparison, the suggested material model gives reliable analytical results.

Changes of Corn Proteins and Lipids induced by Thermal Processing (옥수수 가열가공처리에 의한 단백질 및 지질성분의 변화)

  • Cho, Sung-Hwan;Yoon, Zoo-Lk
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.18 no.3
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    • pp.287-299
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    • 1989
  • This research was conducted in order to investigate thermal stability and nutritional value of corn lipids and proteins during thermal processing. The lipids of raw and popped corn were fractionated and analyzed by column and gas chromatography. The effect of thermal processing on corn proteins was examined by sodium dodecyl sulfate polyacrylamide gel electrophoresis (SDS-PAGE) and amino acid analysis. There was no remarkable change in proximate compositions during thermal processing. The lipid fractions obtained by silicic acid column chromatography were composed of neutral lipid(93.5%), glycolipid(3.8%), and phospholipid(2.7%), Although the thermal processing showed the increase in the ratio of unsaturated/saturated fatty acid, there was no significant differences in the lipid composition between raw and popped corn. Most of each protein fractions had lower molecular weight than 25,000 dalton and albumin fractions were distributed in the molecular weight range 11,500-94,000 daltons. Popped corn proteins did not show marked differences in their electrophoretic migrations when compared with raw corn proteins.

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Thermal Deformation Analysis of L-shaped Composite During Cure Process by Viscoelastic Model (점탄성을 고려한 L-형상 복합재료 성형시 열변형 해석)

  • Seong, Dong-Yun;Kim, Wie-Dae
    • Composites Research
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    • v.33 no.4
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    • pp.220-227
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    • 2020
  • When curing the composite, the fibers have little thermal deformation, but the resin changes its properties with time and temperature, which leads to residual stress in the product. Residual stress is caused by the difference in the coefficient of thermal expansion of the fibers and resin during the curing process and the chemical shrinkage of the resin. This difference causes thermal deformation such as spring-in and warpage. Thermal deformation of composite structure is important issue on quality of product, and it should be considered in manufacturing process. In this study, a subroutine was developed to predict thermal deformation by applying 3-D viscoelastic model. The finite element analysis was verified by comparing the results of the plate analysis of the 2-D viscoelastic model. Spring-in of L-shaped structure was predicted and analyzed by applying the 3-D viscoelastic model.

Analysis on Thermomechanical Response to Tensile Deformation of GaN Nanowires (GaN 나노와이어의 인장 변형에 의한 열기계적 거동 해석)

  • Jung, Kwangsub;Zhou, Min;Cho, Maenghyo
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.25 no.4
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    • pp.301-305
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    • 2012
  • In this work the mechanical behaviors of GaN nanowires are analyzed during tension, compression, and unloading deformations. The thermal conductivity of the nanowires at each deformed state is evaluated using an equilibrium Green-Kubo approach. Under tensile loading, the [0001]-oriented nanowires with hexagonal cross-sections undergo a phase transformation from wurtzite to a tetragonal structure. The phase transformation is not observed under compressive loading. The thermal conductivity decreases on going from compressive strains to tensile strains. The strain dependence of the thermal conductivity results from the relaxation time of phonon. A reverse transformation from the tetragonal structure to the wurtzite structure is observed during unloading. The thermal conductivities in the intermediate states are lower than the conductivity in the wurtzite structure at same strain. Such differences in the thermal conductivity between different atomic structures are mainly due to changes in the group velocity of phonon.