• 한국수소및신에너지학회논문집
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• 제33권5호
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• pp.515-524
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• 2022

In this study, the on-site hydrogen production process for refueling stations that were not energy-optimized was improved through exergy analysis and heat exchange network synthesis. Furthermore, the process was scaled up from 30 Nm3/h to 150 Nm3/h to improve hydrogen production capacity. Exergy analysis results show that exergy destruction in the SMR reactor and the heat exchanger accounts for 58.1 and 19.8%, respectively. Thus, the process is improved by modifying the heat exchange network to reduce the exergy loss in these units. As a result of the process simulation analysis, thermal and exergy efficiency is improved from 75.7 to 78.6% and 68.1 to 70.4%, respectively. In conclusion, it is expected to improve the process efficiency when installing on-site hydrogen refueling stations.

• 한국지열·수열에너지학회논문집
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• 제18권3호
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• pp.7-18
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• 2022

Secondary batteries used in electric vehicles have a potential risk of ignition and explosion. Various safety measures are being taken to prevent these risks. A numerical study was performed using a computational fluid dynamics code on the cases where pressure relief vents that can reduce the blast overpressures of batteries were installed in the through-compression test room, short-circuit drop test room, combustion test room, and immersion test room in facilities rleated to battery used in electric vehicles. This study was conducted using the weight of TNT equivalent to the energy release from the battery, where the the thermal runaway energy was set to 324,000 kJ for the capacity of the lithium-ion battery was 90 kWh and the state of charge (SOC) of the battery of 100%. The explosion energy of TNT (△H_TNT) generally has a range of 4,437 to 4,765 kJ/kg, and a value of 4,500 kJ/kg was thus used in this study. The dimensionless explosion efficiency coefficient was defined as 15% assuming the most unfavorable condition, and the TNT equivalent mass was calculated to be 11 kg. The internal explosion generated in a test room shows the very complex propagation behavior of blast waves. The shock wave generated after the explosion creates reflected shock waves on all inner surfaces. If the internally reflected shock waves are not effectively released to the outside, the overpressures inside are increased or maintained due to the continuous reflection and superposition from the inside for a long time. Blast simulations for internal explosion targeting four test rooms with pressure relief vents installed were herein conducted. It was found that that the maximum blast overpressure of 34.69 bar occurred on the rear wall of the immersion test room, and the smallest blast overpressure was calculated to be 3.58 bar on the side wall of the short-circuit drop test room.

• KEPCO Journal on Electric Power and Energy
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• 제8권2호
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• pp.69-72
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• 2022

This paper actually investigates the load on major large-scale buildings in the downtown area, examines the economic feasibility of installing PV and ESS in a microgrid target building, and evaluates whether an electric vehicle capable of V2G through two buildings is effective as an economical analysis program (HOMER) was analyzed using. It is economical to install a mixture of ESS rather than using the whole PV, and it is shown that if there is an electric vehicle using the V2G function of EV, there is an economic effect to replace the PV. So that Incentives and policies are needed to replace a large area of PV and utilize the existing parking lot to lead EV as a resource of the microgrid. Currently, P2X technology that stores power as ESS or converts it to other energy to control when surplus renewable energy occurs in large-capacity solar power plants and wind farms, etc. This is being applied, and efforts are being made to maintain the stability of the system through the management of surplus power, such as replacing thermal energy through a heat pump. Due to the increase in electric vehicles, which were recognized only as a means of transportation, technologies for using electric vehicles are developing. Accordingly, existing gas stations do not only supply traditional chemical fuels, but electricity, and super stations that also produce electricity have appeared. Super Station is a new concept power plant that can produce and store electricity using solar power, ESS, V2G, and P2G. To take advantage of this, research on an urban microgrid that forms an independent system by tying a large building and several buildings together and supplies power through a super station around the microgrid is in full swing.

• 멤브레인
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• 제32권2호
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• pp.91-99
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• 2022

모든 인구 계층에 저렴한 비용으로 깨끗한 물의 수요를 충족시키는 것은 해결해야 할 세계적인 문제이다. 막 분리 공정을 통한 해수 및 기수의 탈염은 효율이 높고 확립된 방법이다. 그러나 막 분리 공정은 막 오염, 제거된 오염물의 처리, 그리고 자본집약적 공정이라는 본질적인 문제가 있다. 전기투석은 전위차가 구동력인 막 기반 분리 공정이다. 전기투석막의 장점은 뛰어난 효율과 저렴한 운영 비용이다. 전기투석공정에서 사용되는 이온교환막은 장기간 효율을 잃지 않기 위해 내화학성과 내열성, 그리고 기계적 안정성이 필요하다. 이 때, 전기투석막의 이온교환용량은 이온교환막의 전도도에 따라 크게 달라진다. 본 리뷰에서는 이온 전도도과 안정성을 향상시키기 위한 양이온 교환막과 음이온 교환막의 개조를 중점적으로 논의하였다.

• 공업화학
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• 제33권4호
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• pp.343-351
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• 2022

리튬이온 전지(lithium-ion batteries, LIBs)는 높은 에너지 밀도, 느린 자가방전율, 고율 충전 능력 및 긴 배터리 수명 등의 좋은 성능으로 촉망받는 에너지 저장 장치로 꼽힌다. 그러나 고에너지 밀도의 전기자동차 및 대형 디바이스 산업에서 이러한 LIBs의 적용은 큰 안전 문제를 일으키고 있다. 이러한 문제를 해결하기 위하여 열적 안정성 및 내재적 안전성이 높은 재료를 개발하는 것이 LIBs의 안정성 및 전기화학적 성능을 향상시키는 궁극적인 해결방법이다. 본 총설에서는 상용 분리막의 안정성 문제 극복을 위한 분리막의 표면 개질 기술을 소개하였으며 이를 이용하여 개질된 리튬이온 전지용 분리막을 활용한 연구 동향을 요약, 정리하였다. 또한 이를 기반으로 표면 개질에 따른 분리막에 대한 향후 전망을 논의하였다.

• 한국전기전자재료학회논문지
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• 제36권1호
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• pp.10-15
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• 2023

The carbonaceous materials have attracted much attention for utilization of anode materials for lithium-ion batteries. Among them, hollow carbon spheres have great advantages (high specific capacity and good rate capability) to replace currently used graphite anode materials, due to their unique features such as high surface areas, high electrical conductivities, and outstanding chemical and thermal stability. Herein, we have synthesized various sizes of hollow carbon spheres by a facile hardtemplate method and investigated the anode properties for lithium-ion batteries. The obtained hollow carbon spheres have uniform diameters of 350 ~ 600 nm by varying the template condition, and they do not have any cracks after the optimization of the process. Increasing the diameter of hollow carbon spheres decreases their specific capacities, since the larger hollow carbon spheres have more useless spaces inside that could have a disadvantage for lithium storage. The hollow carbon spheres have outstanding rate and cyclic performance, which is originated from the high surface area and high electrical properties of the hollow carbon spheres. Therefore, hollow carbon spheres with smaller diameters are expected to have higher specific capacities, and the noble channel structures through various doping approaches can give the great possibility of high lithium storage properties.

• 한국안전학회지
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• 제38권3호
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• pp.35-42
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• 2023

This study analyzed the current and temperature characteristics of major components of an induction motor during normal and abnormal operations as functions of the difference in the rated capacities of medium and large-sized motors widely used in industrial settings. The temperature rise equation of the induction motor winding was derived through locked-rotor operation experiments and linear regression analysis. When the ambient temperature is 40 ℃, the time to reach 155 ℃, the temperature limit of the insulation class (F class) of the winding of the induction motor, was confirmed to be 48 seconds for the 2.2 kW induction motor and 39 seconds for the 3.7 kW induction motor. This means that when the rated capacity is large or the installation environment is high temperature, the time to reach the temperature limit of the insulation class during locked-rotor operation is short, and the risk of insulation deterioration and fire is high. In addition, even if the EOCR (Electronic Over Current Relay) is installed, if the setting time is excessively set, the EOCR does not operate even if the normal and locked-rotor operation of the induction motor is repeated, and the temperature limit of the insulation grade of the winding of the induction motor is exceeded. The results of this study can be used for preventive measures such as the promotion of electrical and mechanical measures for the failure of induction motors and fire prevention in industrial sites, or the installation of fire alarm systems.

• 플랜트 저널
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• 제18권4호
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• pp.66-72
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• 2023

신재생에너지 비중 증가에 따른 전력계통 불안정성과 탈원전, 노후 석탄화력 폐쇄로 인한 안정적인 발전자원 감소에 대한 대응 방안으로 터빈제어밸브 4개중 2~3개를 교축하여 발전기 출력 증·감발과 주파수를 추종하는 복합 변압 운전 방식을 터빈제어밸브를 전개하여 교축손실을 줄임으로서 발전 효율을 극대화하는 순 변압운전 방식으로 대체하고, 계통 주파수 변동에 신속하게 대응하기 위해 ESS를 연계하여 주파수 추종 및 자동발전운전을 하는 제어로직을 500MW 석탄화력인 태안 5호기를 대상으로 개발하였다. ESS 운전(신속한 응답, 용량 한계)과 발전소 터빈제어밸브 교축 운전(느린 응답, 지속적인 운전)의 장·단점을 보완하는 협조제어 알고리즘이 실제 발전소에 적용시 발전 효율 향상은 물론 전력 수요에 신속하고 유연하여 대응하여 계통 안정성에 기여할 것으로 확신한다.

• 한국수소및신에너지학회논문집
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• 제34권2호
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• pp.91-99
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• 2023

Participation in power trading using surplus power is considered a business model active in the domestic energy trade market, but it is limited only if the legal requirements according to the type, capacity, and use of the facilities to be applied for are satisfied. The hydrogen residential demonstration model presented in this paper includes solar power, energy storage system (ESS), fuel cell, and water electrolysis facilities in electrical facilities for private use with low-voltage power receiving system. The concept of operations strategy for this model focuses on securing the energy self-sufficiency ratio of the entire system, securing economic feasibility through the optimal operation module installed in the energy management system (EMS), and securing the stability of the internal power balancing issue during the stand-alone mode. An electric facility configuration method of a hydrogen residential complex demonstrated to achieve this operational goal has a structure in which individual energy sources are electrically connected to the main bus, and ESS is also directly connected to the main bus instead of a renewable connection type to perform charging/discharging operation for energy balancing management in the complex. If surplus power exists after scheduling, participation in power trading through reverse transmission parallel operation can be considered to solve the energy balancing problem and ensure profitability. Consequentially, this paper reviews the legal regulations on participation in electric power trading using surplus power from hydrogen residential models that can produce and consume power, gas, and thermal energy including hybrid distributed power sources, and suggests action plans.

• 한국수소및신에너지학회논문집
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• 제33권1호
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• pp.19-27
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• 2022

A series of QPAE/TiO₂-x (x = 1, 4, 7 and 10 wt%) organic/inorganic composite membranes were prepared as electrolyte membranes for alkaline anion exchange membrane fuel cells by controlling the content of inorganic filler with quaternized poly(arylene ether) (QPAE) random copolymer. Among the prepared QPAE/TiO₂-x organic/inorganic composite membranes, the highest ionic conductivity was 26.6 mS cm^-1 at 30℃ in QPAE/TiO₂-7 composite membrane, which was improvement over the ionic conductivity value of 6.4 mS cm^-1 (at 30℃) of the pristine QPAE membrane. Furthermore, the water uptake, swelling ratio, ionic exchange capacity, and thermal property of QPAE/TiO₂-x composite membranes were improved compared to the pristine QPAE membrane. The results of these studies suggest that the fabricated QPAE/TiO₂-x composite membranes have good prospects for alkaline anion exchange membrane fuel cell applications.