• Title/Summary/Keyword: Thermal Aging

Search Result 620, Processing Time 0.025 seconds

The Effect of Additive Catalyst according to Thermal Aging of Vanadia SCR (Vanadia SCR의 열적 열화에 따른 조촉매의 영향)

  • Seo, Choong-Kil
    • Journal of Power System Engineering
    • /
    • v.18 no.3
    • /
    • pp.14-19
    • /
    • 2014
  • The purpose of the study is to investigate the effect of additive catalyst according to the thermal aging of vanadia SCR catalysts. At a fresh condition, the $3V_2O_5-5WO_5-92TiO_2$ SCR showed the highest NOx conversion rate of about 30%, the performance of 5 kinds of SCR to which additive catalysts were added was not improved due to the insignificant effect of acid site control. For catalysts aged for 12h at $700^{\circ}C$, the SCR to which 3wt% Zeolite was added decreased in NOx conversion rate by 2.5% on average compared to the fresh SCR, it showed higher thermal durability than other additive catalyst. For 3Zeolite with high performance of NOx conversion rate during thermal aging, the Zeolite with stronger durability at a high temperature than other 5 kinds of SCR catalysts decreased the sintering of catalysts.

EFFECTS OF AGING AND THERMAL CYCLING ON THE BIAXIAL FLEXURE STRENGTH OF VENEERING RESIN COMPOSITES FOR CROWN (시효처리와 thermal cycling이 치관전장용 복합레진의 2축굽힘강도에 미치는 영향)

  • Jeong, Gwan-Ho;Ha, Il-Soo;Song, Kwang-Yeob
    • The Journal of Korean Academy of Prosthodontics
    • /
    • v.37 no.5
    • /
    • pp.597-606
    • /
    • 1999
  • This study was performed to evaluate the effect of aging and thermal cycling on the biaxial flexure strength of low commercially available veneering resin composites for crown(Dentacolor : DC, Artglass : AG, Esternia : ET and Targis : TG). Disc specimens were fabricated in a teflon mold giving 12mm in diameter and 1mm in thickness. All samples were divided into 4 groups. Group 1 was dried in a dessicator at $25^{\circ}C$ for 30 days. Group 2 was immersed in distilled water at $37^{\circ}C$ for 30 days. Group 3 was immersed in distilled water at $65^{\circ}C$ for 30 days. Group 4 was subjected to 10,000 thermal cycles between $5^{\circ}C\;and\;55^{\circ}C$, and the immersion time in each bath was 15 seconds per cycle. Biaxial flexure test was conducted using the ball-on-three-ball method at the cross head speed of 0.5mm/min and fracture surfaces were observed with scanning electoron microscope. The results obtained were summarized as follows; 1. Weibull modulus values, except for the AG group, decreased after thermal cycling treatment. 2. Biaxial flexure strength values of aging group at $37^{\circ}C$ were the lowest in all sample groups. Except for the DC group, strength values were significantly decreased for the drying group. 3. After thermal cycling test, the highest value of biaxial flexure strength of 188.8 MPa was observed in the ET group and the lowest value of 73.2 MPa was observed in the DC group. The strength values showed the significant differences in each group (p<0.05). 4. Observation of surfaces after thermal cycling test revealed the ditching in the part of surrounding large fillers.

  • PDF

Study on the thermal Property and Aging Prediction for Pressable Plastic Bonded Explosives through ARC(Heat-Wait-Search method) & isothermal conditions (ARC(Heat-Wait-Search method)와 isothermal 조건을 이용한 압축형 복합화약의 열적 특성 및 노화 예측 연구)

  • Lee, Sojung;Kim, Jinseuk;Kim, Seunghee;Kwon, Kuktae;Chu, Chorong;Jeon, Yeongjin
    • Proceedings of the Korean Society of Propulsion Engineers Conference
    • /
    • 2017.05a
    • /
    • pp.172-178
    • /
    • 2017
  • Thermal property is one of the important characteristic in the field of energetic materials. As the energy material is released during decomposition, DSC(Differential Scanning Calorimetry) is frequently used for the thermal analysis. In case of the dynamic DSC measurements, thermal dynamic change like melting is prevented from the thermal property measurements. And due to the predicting kg scale, the conditions of the heat exchange with the environment significantly is changed. In this study, As the method to resolve the problem, we predict the thermal aging property using the AKTS thermokinetic program from DSC measurements which performed isothermal method. Predicting the thermal aging properties from ARC(Accelerating Rate Calorimetry) measurement, we compare two results.

  • PDF

ACCELERATED AGING USING $FOCAS^{(R)}$-A BURNER BASED SYSTEM SIMULATING AN ENGINE

  • Bykowski, B.B.;Bartley, G.J.J.;Webb, C.C.;Zhan, R.;Burrahm, R.W.
    • International Journal of Automotive Technology
    • /
    • v.7 no.3
    • /
    • pp.245-249
    • /
    • 2006
  • Accelerated aging of engine exhaust system components such as catalytic converters are traditionally performed using an engine/dynamometer test stand. $SwRI^{(R)}'s\;FOCAS^{(R)}$ system reduces or eliminates many of the engine based aging limitations. This paper will describe several studies. These include: 1) replication of engine based catalyst aging cycles with added precision and dependability; 2) catalyst aging with and without lubricating oil effects; 3) effects of lubricant phosphorus on catalyst performance; and 4) the potential to thermally age components beyond the capabilities of engine based systems. The first study includes the development of the SwRI FOCAS system to run programmed aging conditions with or without lubricating oil. A description of the subsystems is given. The second two studies used the SwRI FOCAS system to age catalysts. One study compared thermal-only aging using of the SwRI FOCAS system with equivalent aging on a traditional engine/dynamometer test stand. The other study examined the effect on catalyst performance of two lubricating oils containing different levels of phosphorus, and compared the results to field data generated using the same oils in a fleet of vehicles.

Effects of thermal aging on variations in paper color (강제열화에 따른 종이의 색상변화)

  • Kim, Sun-Kyung;Choi, Eun-Yeon;Lee, Yong-Kyu;Cho, Byoung-Uk
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
    • /
    • 2011.04a
    • /
    • pp.235-241
    • /
    • 2011
  • Effects of thermal aging on color variations of various papers were evaluated. With thermal aging, most of papers showed a special trend in $a^*$-$b^*$ plane: $a^*$ (red-green) values of the samples were reduced at beginning and after a turning point it was increased while $b^*$ (blue-yellow) was kept increased (yellowing of paper). In case of filter paper which consists of chemical pulps, the changes in $a^*$ value was occurred late compared with other samples. In case of the copy paper with optical brightening agent, the turning point in $a^*$ was not observed while a constant increase in $b^*$ was observed. In case of color paper, no specific trends in $a^*$-$b^*$ were found.

  • PDF

Influence of Thermal Aging on the Properties of Polyurethane Coating of Waterproof. (우레탄 도막 방수재의 열열화 특성)

  • Kim, Sung-Rae;Shin, Hong-Chol;Shin, Ju-Jae;Kim, Young-Geun
    • Proceedings of the Korea Concrete Institute Conference
    • /
    • 2008.11a
    • /
    • pp.931-934
    • /
    • 2008
  • Polyurethane apply to the waterproof widely. Polyurethane rubbers are prepared that the influences of a thermal aging on the properties are investigated. Polyol and Polyisocyanate were varied ratio in the range mixed by using individual product that was vulcanized by a hot. The waterproofs of Polyurethane were investigated about tensile strength, tear strength and elongation after the thermal Aging for 168, 336, 504 hrs at 70$^{\circ}$C and 80$^{\circ}$C in the air oven. As the increase of the thermal aging time, tensile strength, tear strength and elongation were reduced.

  • PDF

Strengthening Treatment of Aged Hanji with Solvent Soluble Polymers (용제 용해형 고분자를 이용한 열화한지의 보강처리)

  • Kim, Kang-Jae;Lee, Min-Hyung;Eom, Tae-Jin
    • Journal of Korea Technical Association of The Pulp and Paper Industry
    • /
    • v.44 no.1
    • /
    • pp.1-9
    • /
    • 2012
  • In this study, 5 solvent soluble polymers were treated on Hanji. Mechanical properties, morphology and oxidation index with thermal aging were measured on the aged Hanji, dewaxed Hanji and polymer treated Hanji. Synthetic polymers(such as polylactic acid, polybutylene succinate, polystyrene) treated Hanji had higher strength and thermal stability than cellulose derivatives(such as cellulose nitrate and cellulose acetate) treated Hanji. Polymer treated Hanji showed a little bit of color change. The oxidation index of PS treated Hanji did not increase with thermal aging because it did not have a carboxyl group in chemical structure. Finally, polystyrene was found to be the most efficient method for strengthening the dewaxed Hanji. The best aging safety and thermal stability were obtained at the polystyrene 3% solution.

Thermal Properties of DGEBHA/MDA/SN/zeolite System Degraded by Moisture Absorption

  • Kim, You-Jeong;Lee, Hong-Ki;Kim, Sang-Wook
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 1999.11a
    • /
    • pp.479-482
    • /
    • 1999
  • Cured epoxy resins are extensively used for the electrical insulation in high-voltage equipments. The bisphenol A-based epoxy resins lured with azine show, especially, good thermal properties and mechanical resistances. For the technical and economic reasons, varing amount of inorganic fillers are added to endow the required special properties. In the large generators and motors of power plants, epoxy insulation is disclosed to the harsh conditions like the superheated steam and abrupt temperature variation. Hygrothermal aging at elevated temperatures tends to induce degradation in epoxy resins. To predict the effect of this degradation in DGEBA/MDA/SN/zeolite system, we proceeded the forced moisture absorption experiment using the autoclave. The thermal properties of the untreated and treated specimens were analyzed by DSC and TGA under the nitrogen flowing condition. The moisture absorption results showed a weight increase during hygrothermal aging at 1207. At the initial aging period, the system leaded to more or less postcuring but more prolonged environmental aging leaded the discoloration of specimen and lowering the T$_{g}$./.

  • PDF