• 한국조명전기설비학회지:조명전기설비
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• 제11권1호
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• pp.24-33
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• 1997

본 논문에서는 주상변압기 절연유의 가속열화반응을 수행하였다. 유중가스를 air bubbling법으로 추출하여 가스크로마토그라프로 성분을 분석하였으며 가스농도는 각 가스의 추출율을 감안하여 보정하였다. 절연재료의 열화는 열분해반응과 산화반응에 의하여 진행되었으며 두종류의 반응은 모두 0차반응의 특성을 보였고 탄화수소류, $CO+CO_2$ 및 수소가스의 생성속도식을 얻었다. 유중가스 분석과 UV-Visible 분광광도법에 의하여 변압기내의 철심과 동코일이 열화과정에서 촉매역활을 함에 확인하였다.

• Elastomers and Composites
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• 제47권2호
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• pp.148-155
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• 2012

EPDM, IIR, 그리고 BIIR 복합체를 열노화시켜 가교밀도 변화를 조사하였다. 노화 시간이 증가하거나 노화온도가 올라갈수록 EPDM 복합체의 가교밀도는 증가하였으나, 고온에서 장기간 노화된 IIR과 BIIR 복합체의 가교밀도는 감소하는 경향을 보였다. EPDM 복합체의 가교밀도 변화에 대한 활성화 에너지는 BIIR 복합체보다 높았다. 실험결과는 알릴 수소의 수, 아연 복합체의 활성화, 입체 가리움 효과, 그리고 고무 사슬의 산화로 설명하였다.

• 펄프종이기술
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• 제43권5호
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• pp.1-10
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• 2011

In this study, 13 water soluble polymers(6 natural polymer, 7 synthetic polymer) were treated on Hanji. Mechanical properties, morphology and oxidation index with thermal aging were measured on the aged Hanji, dewaxed Hanji and polymer treated Hanji. 3 natural polymer(such as CMC, EC, MC) and 3 synthetic polymers(such as PVA 1500, 2000, PEG 1500) treated Hanji had higher strength than other polymer treated Hanji. The oxidation index of 3% methyl cellulose solution treated Hanji did a little increase with thermal aging. Finally, methyl cellulose was found to be the most efficient method for strengthening the dewaxed Hanji. The best aging safety and thermal stability were obtained at the methyl cellulose 3% water solution.

• 한국원자력학회:학술대회논문집
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• 한국원자력학회 1996년도 춘계학술발표회논문집(3)
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• pp.79-84
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• 1996

Small punch test was performed on CF8 duplex stainless steel aged at 370 and 400$^{\circ}C$ up to 5,000 h to evaluate the degree of the thermal aging embrittlement. At room temperature, the SP load-displacement curve was in a similar shape to those of ferritic steels and had a good reproducibility in spite of two-phase structure. The aging heat treatment resulted in a slight increase of the yield strength. As test temperature was lowered, the SP load showed a sudden drop followed by serrations before the SP specimen was fractured, resulting from the cracking of ferrite phase. The extent of thermal embrittlement was assessed in terms of the SP energy. Aging treatment at higher temperature led to a larger shift in the transition temperature and the corresponding change in the fracture mode. The main cause of the degradation was the embrittlement of ferrite phase. Additionally the phase boundary separation profoundly contributed to the degradation of the specimen aged at 400$^{\circ}C$.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2004년도 추계학술대회 논문집 전기설비전문위원
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• pp.77-79
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• 2004

It is caused that insulation paper, which had got a lot of thermal stress by over-load after installation, should have been deteriorated in electrical and mechanical characteristics. Beside, insulation material is decreased the insulating property and accelerated aging of them in case of dielectric loss when transformers are manufactured with some moisture or transformers would have been them because of moisture-permeation. Therefore, in this study we experienced the influence of moisture content in case of the thermal aged insulation paper. we have measured tan 6 and breakdown voltage in the ratio of paper' moisture content before the aging and then taken the same tests again after insulation paper thermally accelerating-aged. There is a purpose to gain data for a life-design and to establish aging mechanism in order to continuously study life expectancy of the insulation paper

• Nuclear Engineering and Technology
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• 제53권8호
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• pp.2591-2599
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• 2021

The effect of thermal aging at 475 ℃ and 750 ℃ of Z3CN20.09M cast duplex stainless steel (CDSS) on microstructure, mechanical and intergranular corrosion properties were investigated by transmission electron microscope (TEM), nano indenter, scanning electron microscope (SEM) and corrosion fatigue test system. The result indicated that the spinodal decomposition and G precipitated were occurred after aged at 475 ℃, as well as sigma precipitated at 750 ℃. The microstructure degeneration of ferrite was saturated after aged for 2000h and 200 h at 475 ℃ and 750 ℃ respectively. The mechanical properties, intergranular corrosion resistance and corrosion fatigue lives were continuing deteriorated with increasing the aging time at both temperatures. The difference of the degeneration mechanisms of Z3CN20.09M CDSS aged at 475 ℃ and 750 ℃ was analyzed.

• Journal of Electrical Engineering and Technology
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• 제13권2호
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• pp.918-927
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• 2018

Based on the actual operating environment of transformer, the aging tests of nitrile butadiene rubber (NBR) were conducted systematically under four conditions: in air, in transform oil, under compression in air and under compression in transform oil to studythe effect of high temperature, transform oil and compression stress simultaneously on the thermal aging behaviors of nitrile butadiene rubber and predict the lifetime. The effects of liquid media and compression stress simultaneously on the thermal aging behaviors of nitrile butadiene rubber were studied by using characterization methods such as IR spectrosc-opy, thermogravimetric measurements, Differential Scanning Calorimetry (DSC) measurements and mechanical property measurements. The changes in physical properties during the aging process were analyzed and compared. Different aging conditions yielded materials with different properties. Aging at $70^{\circ}C$ under compression stress in oil, the change in elongation at break was lower than that aging in oil, but larger than that aging under compression in air. The compression set or elongation at break as evaluation indexes, 50% as critical value, the lifetime of NBR at $25^{\circ}C$ was predicted and compared. When aging under compression in oil, the prediction lifetime was lower than in air and under compression in air, and in oil. It was clear that when predicting the service lifetime of NBR in oil sealing application, compression and media liquid should be involved simultaneously. Under compression in oil, compression set as the evaluation index, the prediction lifetime of NBR was shorter than that of elongation at break as the evaluation index. For the life prediction of NBR, we should take into account of the performance trends of NBR under actual operating conditions to select the appropriate evaluation index.

• 한국자동차공학회논문집
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• 제15권3호
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• pp.147-152
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• 2007

This study investigates the aging characteristics of NOx storage and reduction(NSR) catalyst on the emission conditions of lean burn natural gas vehicles. We designed various NSR catalysts using by the double-layer washcoat technology to increase of a surface area and a thermal durability performance of the catalysts. The experiments were conducted with 3 kinds of the NSR catalysts, which were manufactured using by a honeycomb cordierite substrate. It was found that Ba is weak in the thermal aging because it has lower melting temperature than that of precious metals (PMs). The suitable loading amount of Ba in this study should be about 42 g/L from the results of the NOx adsorption and the NOx reduction efficiency. The major reason in deactivation of the NSR catalyst is the decrease of the adsorption site owing to the agglomeration and sintering of Ba rather than PM aging by hydrothermal aging. It was confirmed by results of BET, SEM and TEM.

• 펄프종이기술
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• 제43권1호
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• pp.11-16
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• 2011

This study was carried out in order to elucidate the effect of latex dosage and properties on aging behavior of coated paper. The coated paper with five different coating formulations were prepared and also four different latices were used. The coated paper were thermally aged at $105^{\circ}C$ for 14 days and the optical properties were measured. Increasing latex content increased the magnitude of reduction in brightness and whiteness. In addition, the variations in CIE a$^*b^*$ were larger with increasing latex dosage. Latex which has the lower gel content and the higher Tg showed the higher reduction in brightness and whiteness and much variation in CIE a$^*b^*$. However the particle size of latex didn't affect to thermal behavior of coated paper. These results indicate that latex which has higher Tg and lower gel content is the one of the main factors affecting aging behavior of coated paper.

• 한국항공우주학회지
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• 제31권10호
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• pp.21-26
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• 2003

본 논문에서는 광섬유 센서를 사용하여 우주환경하에 노출된 그래파이트/에폭시 복합재 적층판의 열팽창계수의 변화를 측정하였다. 열변형률과 온도를 동시에 측정하기 위해서 두개의 FBG 센서를 사용하였다. 또한 열-진공 챔버를 사용하여 고진공, 자외선, 열적 사이클 등의 인자를 가지는 저궤도(LEO) 우주환경을 모사하였다. 예비실험으로써, 본 실험에서 사용되는 온도범위에 대해 FBG 온도센서를 기준온도계로부터 보정하였고 알루미늄 시편에 부착된 FBG 변형률 센서와 변형률 게이지(ESG)의 비교실험을 통해 FBG 변형률 센서의 사용가능성을 검증하였다. 검증된 FBG센서가 삽입된 그래파이트/에폭시 복합재 평판을 모사된 우주환경에 노출하여 일정한 노화간격마다 열팽창계수 변화를 실시간으로 측정하였다. 실험결과 1000 사이클 노화후의 열팽창계수는 노화전에 비해 대체적으로 큰 변화는 없었지만 전 온도구간에서 약간 감소하는 경향을 보였다. 이러한 현상은 가스방출(outgassing), 수분방출, 모재균열 등에 기인한다.